Chapter 850:              IDENTIFICATION OF HAZARDOUS WASTES

 

TABLE OF CONTENTS

Page

l.    Legal Authority......................................................................................................................... 1

2... Preamble.................................................................................................................................... 1

3... Definitions................................................................................................................................. 1

4.   Identification of Hazardous Wastes.......................................................................................... 2

      A.  General................................................................................................................................. 2

            (3)   Definition of hazardous waste..................................................................................... 2

            (4)   Exclusions.................................................................................................................... 4

            (5)   Special requirements for hazardous waste generated by small quantity generators... 11

            (6)   Special requirements for hazardous waste which is beneficially used or reused....... 14

            (7)   Residues of hazardous waste in empty containers..................................................... 14

            (8)   The use of material which is contaminated or mixed with dioxin or any other

                    hazardous waste identified in Chapter 850, for dust suppression or road

                    treatment is prohibited............................................................................................... 14

            (9)   No fuel which contains any hazardous waste may be burned in any cement

                    kiln unless licensed under Chapter 856...................................................................... 15

            (10) Persons who generate, transport, or collect non‑leaking spent batteries, or who store

                    non‑leaking spent batteries but do not reclaim or intend to reclaim them are not

                    required to obtain a license for such a facility............................................................ 15

            (11) Owners or operators of facilities that store spent batteries before reclaiming

                    them are required to obtain a license for such storage under Chapter 856................ 15

            (12) Delistings.................................................................................................................... 15

            (13) Special requirements for universal wastes.................................................................. 15

            (14) Special requirements for certain batteries................................................................... 17

      B.  Identification of hazardous wastes by characteristics....................................................... 17

            (1)   General....................................................................................................................... 17

            (2)   Characteristic of ignitability....................................................................................... 17

            (3)   Characteristic of corrosivity....................................................................................... 18

            (4)   Characteristic of reactivity......................................................................................... 19

            (5)   Characteristic of toxicity............................................................................................ 19

      C.  Identification of hazardous wastes by particular substance, by chemical class or

            as waste products of specific industrial activities.............................................................. 20

            (1)   General....................................................................................................................... 20

            (2)   Hazardous wastes from non‑specific sources............................................................. 20

            (3)   Hazardous Wastes from specific sources................................................................... 26

            (4)   Discarded commercial chemical products, off‑specification species, container

                    residues, and spill residues thereof............................................................................. 31

      D.  Criteria for designation of a hazardous waste as a universal waste................................... 51

 

Table 1. Maximum Concentration of Contaminants for the Toxicity Characteristic..................... 20

APPENDIX I:   REPRESENTATIVE SAMPLING METHODS............................................... 53

APPENDIX II:. METHOD 1311 TOXICITY CHARACTERISTIC LEACHING PROCEDURE(TCLP)           54

APPENDIX III:...................................................... CHEMICAL ANALYSIS TEST METHODS            54

APPENDIX IV:........................................................................................................... RESERVED            67

APPENDIX V:  RESERVED....................................................................................................... 67

APPENDIX VI:........................................................................................................... RESERVED            67

APPENDIX VII:BASIS FOR LISTING HAZARDOUS WASTES......................................... 67

APPENDIX VIII:HAZARDOUS CONSTITUENTS................................................................. 72

APPENDIX IX:........................................................................................................... RESERVED            88

APPENDIX X:  METHOD OF ANALYSIS FOR CHLORINATED

                           DIBENZO‑p‑DIOXINS AND DIBENZOFURANS l,2,3,4............................ 88

APPENDIX XI:........................................................................................... PAINT FILTER TEST            98

 

 

 


Chapter 850:              IDENTIFICATION OF HAZARDOUS WASTES

 

SUMMARY: This rule identifies hazardous wastes. These hazardous wastes are subject to regulation according to the provisions of 38 M.R.S.A., §1301, et seq. and to this and other rules adopted thereunder.

 

l.    Legal Authority. This rule is authorized and adopted under 38 M.R.S.A. §1319‑O (1) and is intended to be consistent with applicable requirements of The Solid Waste Disposal Act, as amended by the Resource Conservation and Recovery Act of 1976, as amended, 42 U.S.C.A. 6901, et seq. and regulations promulgated by the United States Environmental Protection Agency (EPA) thereunder.

 

2.   Preamble. It is the purpose of the Department of Environmental Protection, consistent with legislative policy, to provide effective controls for the management of hazardous wastes. This rule is promulgated to identify hazardous wastes so that effective management measures can be implemented.

 

3. Definitions. The following terms as used throughout this rule shall have the following meaning unless the context indicates otherwise:

 

  1. Generator. "Generator" means a person whose act or process produces a waste which is or may be hazardous or whose act first causes a hazardous waste to become subject to regulation.

 

B.     Large Quantity Generator. “Large Quantity Generator” means a generator that does any one of the following:

(1)   Generates more than 100 kilograms (approximately 27 gallons) per month of hazardous waste,

(2)   Generates more than 1 kilogram of acute hazardous waste per month,

(3)   Accumulates more than 600 kilograms (approximately 165 gallons) of hazardous waste at any one time,

(4)   Accumulates more than 1 kilogram of acute hazardous waste at any one time, or

(5)   Accumulates acute hazardous waste in a container that is larger than 20 liters in capacity.

 

C.    Small Quantity Generator. “Small Quantity Generator” means a generator that does all of the following:

(1)   Generates less than 100 kilograms (approximately 27 gallons) of hazardous waste per month,

(2)   Accumulates a total of no more than 200 kilograms (or 55 gallons) of hazardous waste at any one time, and

(3)   Accumulates 1 kilogram or less, or 20 liters or less of acute hazardous waste at any one time.

 

D.    Small Quantity Generator Plus. “Small Quantity Generator Plus” means a generator that does all of the following:

(1)   Generates less than 100 kilograms (approximately 27 gallons) of hazardous waste per month,

(2)   Accumulates over 200 kilograms (or 55 gallons), but less than 600 kilograms (or 165 gallons) of hazardous waste at any one time, and

(3)   Accumulates 1 kilogram or less, or 20 liters or less of acute hazardous waste at any one time.

 

4.   Identification of Hazardous Wastes

 

A.    General

 

(1)  This rule identifies those wastes which are subject to regulation as hazardous wastes under 38 M.R.S.A., §1301, et seq.

 

(2)  Portions of this rule refer to federal regulations of the United States Environmental Protection Agency (EPA). Unless otherwise specified, the federal regulations referenced are those interim final or final regulations revised as of July 1, 1988, as they appeared in volume 40 of the Code of Federal Regulations (CFR). Where specifically indicated, the terms of a referenced federal regulation are hereby adopted as terms of this rule, except that in regulations incorporated thereby, "EPA" shall mean "the Maine Department of Environmental Protection (DEP)"; "Administrator", "Regional Administrator" and "Director" shall mean "the Maine Board of Environmental Protection or its designated representative"; and the phrase "treat, store, and/or dispose" shall mean "handle". In addition, where the terms of federal regulations hereby incorporated by reference differ from or are inconsistent with other terms of this Chapter or Chapters 850‑860, the more stringent of the requirements shall apply. Other changes to regulations incorporated hereby are as expressly made in this rule.

 

      Waste. "Waste" means any useless, unwanted or discarded substance or material, whether or not such substance or material has any other or future use and includes any substance or material that is spilled, leaked, pumped, poured, emitted, disposed, emptied, or dumped onto the land or into the water or ambient air. This definition includes, without being limited to, materials which are used in a manner constituting disposal, burned for energy recovery, reclaimed or accumulated speculatively.

 

NOTE: It is intended that the terms "materials which are used in a manner constituting disposal, burned for energy recovery, reclaimed or accumulated speculatively" should include all materials covered by 40 C.F.R. Section 261.2(c)(1)-(4) and any amendments thereto.

 

(3)        Definition of hazardous waste

 

(a)  A waste is a hazardous waste if:

 

(i)   It is not excluded from regulation as a hazardous waste under Section 4A(4) of this rule; and

 

(ii)  It meets any of the following criteria:

 

a.   It is listed in Section 4(C) and has not been excluded by EPA under 40 CFR 260.20 and 260.22 and excluded subsequently by the Maine Board of Environmental Protection;

 

b.   It is a mixture of a non‑hazardous waste and one or more hazardous wastes listed in Section 4(C) and has not been excluded by EPA under 40 CFR 260.20 and 260.22 and excluded subsequently by the Maine Board of Environmental Protection;

 

c.   It exhibits any of the characteristics of hazardous waste identified in Section 4 (B) of this rule.

 

(b)  A waste which is not excluded from regulation under paragraph 4(A)(3)(a)(i) of this section becomes a hazardous waste when any of the following events occur:

 

(i)   In the case of a waste listed in Section 4 (C), when the waste first meets the listing description set forth in Section 4(C).

 

(ii)  In the case of a mixture of a non‑hazardous waste and one or more listed hazardous wastes, when a hazardous waste listed in Section 4(C) is first added to the non‑hazardous waste.

 

(iii) In the case of any other waste (including a waste mixture), when the waste exhibits any of the characteristics identified in Section 4(B) of this rule.

 

(c)  Unless and until it meets the criteria of paragraph (d) below:

 

(i)   A hazardous waste will remain a hazardous waste.

 

(ii)  Any waste generated from the handling of a hazardous waste, including any sludge, spill residue, ash, emission control dust or leachate (but not including precipitation run‑off), is a hazardous waste.

 

(d) Any waste described in paragraph (c) above is not a hazardous waste if it meets the following criteria:

 

(i)   In the case of any waste, it does not exhibit any of the characteristics of hazardous waste identified in Section 4 (B).


 

 

(ii)  In the case of a waste which is a listed waste under Section 4(C), contains a waste listed under Section 4(C) or is derived from a waste listed in Section 4(C), it also has been excluded from paragraph (c) by EPA under 40 CFR 260.20 and 260.22 and excluded subsequently by the Maine Board of Environmental Protection.

 

(4)  Exclusions

 

(a)    Substances which are not hazardous wastes. The following materials are not hazardous wastes for the purpose of this rule:

 

(i)                 Domestic sewage; and

 

(ii)               Any mixture of domestic sewage and other wastes that passes through a sewer system to a publicly‑owned treatment works (POTW) for treatment, provided the mixture is a discharge of a non segregable waste at the site of generation, the mixture is a discharge from a source whose hazardous constituents are subject to categorical, local limits, and prohibitions established in accordance with Section 307(b) of the Clean Water Act, and the source is in compliance with those limits by means other than dilution and the hazardous constituents are sampled and analyzed no less frequently than annually. "Domestic sewage" means untreated sanitary wastes that pass through a sewer system. The unknowing receipt of hazardous waste by a POTW does not cause the POTW to become a hazardous waste facility.

 

NOTE: Unless the discharge is non segregable and is subject to categorical and local limits, persons discharging hazardous waste to POTWs via a sewer system containing domestic sewage or other means are subject to the applicable abbreviated license provisions of Chapter 856, Section 11. Dischargers to POTWs and POTWs are responsible for complying with the applicable provisions of Chapter 856, Section 11. See also Section 12(D) of Chapter 851. A waste is considered non-segregable when it is inherently mixed with wastewater and is not segregated in containers, tanks, pipes and sumps. A segregable waste cannot be introduced to wastewaters unless an abbreviated license is held for the activity.

 

(iii)             Industrial wastewater discharges that are point source discharges subject to regulation under Section 402 of the Clean Water Act, as amended, in so far as any hazardous waste present in the discharge is in fact regulated.

 

NOTE: This exclusion applies only to the actual point source discharge. It does not exclude industrial wastewaters while they are being handled before discharge, or sludges that are generated by industrial wastewater treatment. The exclusion is further limited by the provisions under Chapter 856 for the abbreviated licensing of a POTW for treatment of a hazardous waste.

 

 

(iv)             Irrigation return flows.

 

(v)               Source, special nuclear or by‑product material as defined by the Atomic Energy Act of l954, as amended, 42 U.S.C.. 20ll et seq.

 

(vi)             Materials subjected to in‑situ mining techniques which are not removed from the ground as part of the extraction process.

 

(vii)           Household waste, including household waste that has been collected, transported, stored, treated, disposed, recovered (e.g., refuse‑derived fuel) or reused. "Household waste" means any waste material (including garbage, trash and sanitary wastes in septic tanks) derived from households (including single and multiple residences, hotels and motels, bunkhouses, picnic grounds, and day-use recreation areas.)

 

(viii)         Wastes resulting from agricultural activities which are returned to the soils as fertilizers. "Agricultural activities" means the growing of vegetables, fruit, seeds, nursery crops, poultry, livestock, field crops, cultivated or pasture hay and farm woodlot products, including Christmas trees.

 

(ix)             Mining overburden returned to the mine site.

 

Note: Wastes from the extraction and beneficiation of metallic ores and minerals are regulated under Chapter 200 of the Department's rules, not Chapters 850‑857.

 

(x)               Fly ash waste, bottom ash waste, slag waste, and flue emission control waste generated solely from the combustion of coal, other fossil fuels, or wood or generated primarily from the combustion of coal and/or other fossil fuels and/or wood, providing that the waste does not exhibit any of the characteristics of hazardous waste as defined in Section 4(B)(2), (3), (4), or (5) of this rule.

 

(xi)             Drilling fluids, produced waters. and other wastes associated with the exploration, development, or production of crude oil, natural gas or geothermal energy.

 

(xii)           A sample of waste or sample of water, soil, or air which is collected for the sole purpose of testing to determine its characteristics or composition provided it meets the requirements of 40 CFR 261.4(d)(1)(i)‑(vi) which are hereby adopted and incorporated by reference, and the sample collector shipping samples to a laboratory and a laboratory returning samples to a sample collector comply with 40 CFR 261.4(d)(2) which is hereby adopted and incorporated by reference. This exemption does not apply if the laboratory determines the waste is hazardous but the laboratory is no longer meeting the requirements of this provision.

 

(xiii)         Commercial chemical product that is unused and which is reinserted into the onsite manufacturing process without any alteration, or that is unused and unexpired and is shipped to the original manufacturer or distributor with their approval for use.

 

(xiv)         Waste from the leather tanning and finishing industry including chrome (blue) trimmings, chrome (blue) shavings, and buffing dust; and scrap tanned leather from the leather tanning industry, the shoe manufacturing industry, and other leather product manufacturing industries, provided the generator can demonstrate the waste meets the exemption criteria of 40 CFR 261.4(b)(6)(i) which is hereby adopted and incorporated by reference, the waste is managed in a non oxidizing environment, and if disposed in Maine, is managed in a secure landfill.

 

NOTE: Due to the potential conversion of trivalent chromium to hexavalent chromium in certain situations, the increased leachability of certain types of chrome waste, and the current management of the waste in oxidizing environments, the Department's Hazardous Waste program continues to have concerns with the disposition of this waste stream. These wastes will be managed in secure landfills as special wastes under 06-096 CMR 400-406, 408 & 409 (May 24, 1989) the Department's Solid Waste Management Regulations.

 

(xv)           Pulping liquors (i.e: black liquor) that are reclaimed in a pulping liquor recovery furnace and then reused in the pulping process, provided the storage of such liquor, if any, prior to reuse occurs in a fully enclosed tank and the liquors are not accumulated speculatively as defined in 40 CFR 261.1(c)

 

NOTE: For the purpose of this paragraph, pulping liquor that is spilled or otherwise released into the environment may qualify for this exemption only to the extent the liquor is recovered for subsequent reuse.

 

(xvi)         Scrap metal which is recycled or intended to be recycled, provided it is not accumulated speculatively as defined in 40 CFR 261.1(c). "Scrap metal" means bits and pieces of metal parts (e.g., bars, turnings, rods, sheets, wire) or metal pieces that may be combined together with bolts or soldering (e.g. radiators, scrap automobiles, railroad box cars), which when worn or superfluous can be recycled and which are not otherwise mixed with or contaminated with non metal hazardous wastes.

 

NOTE: It is the generator's responsibility to demonstrate to the Department that the scrap metal is being recycled.


 

 

(xvii)       Materials in unopened containers which are unused, unexpired and which meet the product specifications, provided the materials are not used in a manner constituting disposal (unless the product is normally applied to the land) or burned for energy recovery (unless the product is a fuel).

 

(xviii)     Unused, unexpired materials in an original container which meet the product specifications, provided the Chief Executive Officers or plant managers of the shipping and receiving facilities exchange letters acknowledging the exchange of material, the Department receives copies of these letters prior to shipment, and the materials are not used in a manner constituting disposal (unless the product is originally applied to the land) or burned for energy recovery (unless the product is a fuel.) The letter must contain the following information: (1) the type and quantity of material transferred; (2) the name, address and telephone number of the transferer and transferee; (3) the date of transfer; and (4) the proposed use of the materials by the transferee.

 

(xix)         Isopropyl alcohol is excluded when shown to be recycled by being used or reused as an effective substitute for commercial products provided the isopropyl alcohol is not being reclaimed and the generator and recycling facility is in compliance with the following:

 

The generator and if located in Maine, the recycler, must maintain the following documentation at the facility of the generator and, if located in Maine, at the recycling facility, and be available for the Department’s inspection:

 

(1)   A description of the isopropyl alcohol to be used or reused;

 

(2)   Consistent with the requirements of 40 CFR 261.2(f) a demonstration that a known market or disposition exists for the isopropyl alcohol. This demonstration must include documentation such as a contract that a material is used to substitute for another product; a description of the process by which the isopropyl alcohol is beneficially used or reused; a representative analysis of the isopropyl alcohol including the hazardous constituents found in 40 CFR 261 Appendix VIII; and documentation that the use of the material does not introduce toxic constituents into the product, for which the material is used as a substitute, in concentrations that are higher than those found in analogous products consistent with 40 CFR 261.2(d)(3)(i)(B); and

 

(3)  Consistent with the requirements of 40 CFR 261.2(f), a demonstration by the owners or operators of the receiving facilities that they are actually recycling the materials and documenting that they have the necessary equipment to do so.

 

Isopropyl alcohol is not exempt under this provision and is a hazardous waste, even if the recycling involves use or reuse, consistent with 40 CFR 261.2(c) and (e) if the isopropyl alcohol or associated materials are reclaimed, used in a manner constituting disposal, or used to produce products that are applied to land, or burned for energy recovery, used to produce a fuel, or contained in fuels, or if materials are accumulated speculatively as defined in 40 CFR 261.1(c)(8), or fed to a halogen acid furnace. A respondent in an action to enforce hazardous waste regulations who raises a claim that isopropyl alcohol is used or reused under this provision must demonstrate consistent with 40 CFR 261.2(f), that there is a known market or disposition for the material, and that they meet the terms of the exclusion.

 

(b)   Samples

 

                                                     (i)            Persons who generate or collect samples for the purpose of conducting a treatability study, as defined in 40 CFR 260.10 on July 19, 1988 (53 FR 27301) are not subject to the requirements of this Chapter, Chapter 851, or Chapter 853, nor are such samples included in the quantity determinations of Section 4(A)(5) of this Chapter, under the circumstances specific in paragraph (ii) where the conditions in paragraph (iii) are met.

 

                                                   (ii)            The exclusion of paragraph (b)(i) shall apply when the sample is being collected and prepared for transportation by the generator or sample collector, the sample is being accumulated or stored by the generator or sample collector prior to transportation to a laboratory or testing facility, or the sample is being transported to the laboratory or testing facility for the purpose of conducting a treatability study.

 

                                                 (iii)            The exclusion of paragraph (b)(i) shall apply when the conditions of 40 CFR 261.4(e)(2)(i)‑(vi) as revised on July 19, 1988 (53 FR 27301) are met, provided however, that the generator shall provide the information required in 40 CFR 261.4(e)(2)(vi) in its annual report, and prior approval has been obtained from the Department. The provisions of 40 CFR 261.4(e)(2)(i)‑(vi) as revised on July 19, 1988 are hereby adopted and incorporated by reference, except that the term "biennial" in 40 CFR 261.4(e)(2)(vi) shall mean "annual".

 

(c)  Solvent-Contaminated Wipes

 

(i)    For purposes of this subsection, “solvent-contaminated wipes” means woven or non-woven shop towels, rags, pads, or swabs made of wood pulp, fabric, cotton, polyester blends, or other material, that, after use or after cleaning up a spill, either:


 

 

(1)   Contains one or more of the F001 through F005 solvents listed in section 4(C)(2) or the corresponding P- or U-listed solvents found in section (4)(C)(4);

 

(2)   Contains one or more solvents listed in section 4(C) which exhibit a hazardous waste characteristic found in section (4)(B) when that characteristic results from a listed solvent; and/or,

 

(3)   Contains one or more solvents that are not listed in section 4(C) which exhibit only the hazardous waste characteristic of ignitability found in section (4)(B)(2).

 

(ii)  The following solvent contaminated wipes are not considered hazardous waste from the point of generation, provided that the generator also complies with the provisions of 4(A)(4)(c)(iv) below:

 

(1)  Solvent-contaminated wipes that the generator either launders or dry cleans on-site, or sends off-site to be laundered or dry cleaned, and the on-site or off-site facility: is located in Maine or in a state that has adopted the exclusion at 40 C.F.R. 261.4(a)(26) as amended up to July 1, 2016 or adopted a state equivalent rule which is no less stringent than 40 C.F.R. 261.4(a)(26), and its discharge, if any, is regulated under sections 301 and 402 or section 307 of the Clean Water Act.

 

(2)  Solvent- contaminated wipes that are sent for disposal provided that:

 

(a)    They are not hazardous waste due to the presence of trichloroethylene; and,

 

(b)   The generator sends the solvent-contaminated wipes for disposal to: an authorized out-of-state facility in a state where the exclusion at 40 C.F.R. 261.4(b)(18) as amended up to July 1, 2016 or a state equivalent rule which is no less stringent than 40 C.F.R. 261.4(b)(18) has been adopted; a municipal solid waste landfill regulated under the Department’s Solid Waste Management Rules 09-096 C.M.R. Chapters 400 to 425; a hazardous waste landfill regulated under 06-096 C.M.R. 854 to 856; a municipal waste combustor or other combustion facility regulated under section 06-096 C.M.R. 143; or, to a hazardous waste combustor, boiler, or industrial furnace regulated under 06-096 C.M.R. 854 to 856.

 

(iii)    Solvent-contaminated wipes that also contain listed hazardous waste other than solvents, or exhibit toxicity, corrosivity, or reactivity due to contaminants other than solvents, are not eligible for the exclusions in this section.

 

(iv)    All solvent-contaminated wipes excluded from the point of generation under sections 4(A)(4)(c)(ii) above must also meet the following provisions:

 

(1)   Containers in which solvent-contaminated wipes are stored must be used only for the storage of those wipes, and not for any other wipes or wastes.

 

(2)   No more than 180 days after the date on which a generator begins to accumulate solvent-contaminated wipes in any container, all solvent-contaminated wipes in that container shall be sent for cleaning or disposal;

 

(3)   Solvent-contaminated wipes, when accumulated, stored and transported, must be contained in non-leaking, closed containers. A container is considered closed where there is complete contact between the fitted lid and the rim, except when it is necessary to add or remove solvent-contaminated wipes;

 

(4)   Any container in which solvent-contaminated wipes are accumulated, stored or transported must be able to contain free liquids, should free liquids accumulate;

 

(5)   Containers in which solvent-contaminated wipes are accumulated, stored, or transported must be clearly labeled or marked with the words “Excluded Solvent-Contaminated Wipes”;

 

(6)   When the container is full or the solvent-contaminated wipes are no longer being accumulated and/or when the container is being transported, the container must be sealed with all lids properly and securely affixed to the container and all openings tightly bound or closed sufficiently to prevent leaks and emissions;

 

(7)   At the point of being sent for cleaning on site or of being transported off site for cleaning or disposal, the solvent-contaminated wipes must contain no free liquids, as defined by 40 C.F.R. 260.10 as amended up to July 1, 2016, and as determined by Method 9095B (Paint Filter Liquids Test), included in “Test Methods for Evaluating Solid Waste, Physical/Chemical Methods” (EPA Publication SW-846) (see Appendix XI);

 

(8)   Free liquids removed from the solvent-contaminated wipes or from the container holding the wipes must be managed in accordance with the hazardous waste management rules; and,

 

(9)  Generators must maintain the following documentation on site:

 

(a)    Name and address of the laundry, dry cleaner, landfill or combustor that is receiving the solvent-contaminated wipes;

 

(b)   Documentation that the 180-day accumulation time limit in subsection (iv)(2) above is being met; and

 

(c)    Description of the process the generator is using to ensure the solvent-contaminated wipes contain no free liquids at the point of being laundered or dry cleaned on-site, or being transported off-site for laundering, dry cleaning or disposal.

 

(d) Treatability study

 

                                                     (i)            Samples undergoing a treatability study and the laboratory or testing facility conducting such treatability study (to the extent the facility is not otherwise subject to the requirements of Chapters 850‑860) are not subject to the requirements of Chapters 850‑860 provided the conditions in paragraph (c)(ii) are met. A mobile treatment unit (MTU) may qualify as a testing facility, and where a group of MTUs are located at the same site, the limitations of paragraph (c)(ii) apply to the entire group of MTUs as if the group were one MTU.

 

                                                   (ii)            The exclusion of paragraph (c)(i) shall apply when the conditions of 40 CFR 261.4(f)(1)‑(11), as revised on July 19, 1988 (53 FR 27302), are met (such provisions are hereby adopted and incorporated by reference, provided however, that references to "40 CFR 261.3" shall mean "this Chapter", "Parts 261 through 268 and Part 270 of this Chapter" shall mean "Chapters 850‑860" and "40 CFR 261.4(e)" shall mean "paragraph (b)(i)‑(iii) above") and prior approval has been obtained from the Department.

 

(5)  Special requirements for hazardous waste generated by small quantity generators

 

(a)  Except as otherwise provided in this section, if a person determines whether the waste he generates is hazardous under Chapter 851, Section 5 and generates, in a calendar month, a total of less than 100 kilograms (220.46 lbs.) of hazardous wastes, those wastes are not subject to regulation under 38 M.R.S.A., §1301, et seq. and related rules, provided the generator complies with paragraph (d) below.

 

NOTE: A small quantity generator is required to properly package for shipment, manifest, use a licensed hazardous waste transporter, and ship its hazardous waste to an authorized facility identified in Section 4(A)(5) (d)(v) of this chapter.

 

(b)  If a person whose waste has been excluded from regulation under paragraph (a) above accumulates hazardous wastes in quantities greater than 600 kilograms or acutely hazardous wastes in quantities greater than set forth in paragraph (c) of this section, all of those accumulated wastes are subject to regulation under 38 M.R.S.A. §1301 et seq. and related rules (Chapters 850‑860 of the Department's rules).

 

(c)  If a person generates in a calendar month or accumulates at any time any of the following acutely hazardous wastes in quantities greater than set forth below, those wastes are subject to regulation under 38 M.R.S.A., §1301 et seq. and related rules. (Chapters 850‑857 of the Department's Rules).

 

                                                     (i)            A total of one kilogram of commercial chemical products and manufacturing chemical intermediates having the generic names listed in Section 4 C(4)(e) of this Chapter and off‑specification commercial chemical products and manufacturing chemical intermediates which, if they met specifications, would have the generic names listed in Section 4 (C)(4)(e) of this Chapter.

 

                                                   (ii)            A total of one kilogram of the following hazardous wastes listed in Section 4(C)(2)(a) of this rule: Industry and EPA hazardous waste Nos. F020, F021, F022, F023, F026, F027, and F028.

 

                                                 (iii)            Any containers identified in Section 4(C)(4)(c) of this Chapter that are larger than 20 liters in capacity;

 

                                                 (iv)            Ten (10) kilograms of inner liners from containers identified in Section 4 (C)(4)(c) of this Chapter;

 

                                                   (v)            A total of 100 kilograms of any residue or contaminated soil, water, or other debris resulting from the cleanup of a spill, into or on any land or water, of any commercial chemical products or manufacturing chemical intermediates having the generic names listed in Section 4(C)(4)(e) of this Chapter or any residue or contaminated soil, water, or other debris resulting from the cleanup of a spill, into or on any land or water, of any off‑specification commercial chemical products or manufacturing chemical intermediates which, if they met specifications, would have the generic names listed in Section 4(C)(4)(e) of this Chapter;

 

NOTE: Any person who exceeds the quantity requirements outlined in Sections 4(A)(5)(b) and 4(A)(5)(c) of this rule is subject to full regulation (i.e., regulation applicable to generators of greater than 100 kilograms per month of hazardous waste), including the requirements of Chapter 851, Section 8(B) that relate to accumulation times for hazardous waste. The time period in Section 8(B) of Chapter 851 begins when the accumulated wastes exceed the applicable exclusion limit.

 

(d) In order for hazardous waste to be excluded from regulation under this section, the generator must:

 

                                                     (i)            Determine whether the waste generated is hazardous in accordance with Section 5 of Chapter 851;

 

                                                   (ii)            Store the waste in a container no greater than 55 gallons in size, label and package the hazardous waste in accordance with Section 8(A) and 8(B)(3) of Chapter 851, and label the container with the date the container becomes full;

 

                                                 (iii)            Properly manifest the hazardous waste in accordance with Chapter 857;

 

                                                 (iv)            Utilize a licensed transporter in accordance with Section 7 of Chapter 851;

 

                                                   (v)            Transport, or offer for transport, such waste only to a waste facility for hazardous waste which is authorized to handle the waste under a state program, and if applicable, under the federal hazardous waste regulatory program; and

 

                                                 (vi)            Ship off site such waste within 180 days of the date the drum becomes full; and

 

                                               (vii)            If more than 55 gallons (approximately 200 kg) of a non-acutely hazardous waste is stored onsite, the generator must in addition:

 

a.   Manage the waste in accordance with Sections 8(B)(2), 11, 13(B)(1),(2), 13(C)(1), (3), (4) and 13(D)(1), and (2) of Chapter 851; and

 

b.   Have a generator identification number assigned to the generator by the United States Environmental Protection Agency if the generator will be operating under the provisions of 4(A)(5)(d)(vii) of this Chapter.

 

NOTE: To be eligible for the reduced requirements of this section, a small quantity generator must store its waste in containers.

 

(e)  Hazardous waste subject to the reduced requirements of paragraph (d) that is mixed with non‑hazardous waste remains subject to these reduced requirements as long as the resultant mixture does not exceed the quantity limitations identified in this section. If any person mixes a solid waste with a hazardous waste that exceeds a quantity exclusion level of this section, the mixture is subject to full regulation. Mixture of a characteristic hazardous waste with a non hazardous waste such that the mixture no longer exhibits a characteristic constitutes treatment which requires a license pursuant to Chapters 854 and 856.

 

(6)  Special requirements for hazardous waste which is beneficially used or reused

 

(a)  Activities that may be eligible for reduced licensing requirements because those activities involve hazardous waste which is beneficially used or reused are specified under Section 11 of Chapter 856, License by Rule.

 

(b)  Activities that involve recycling and reclamation of hazardous waste are considered forms of treatment and, as such, are subject to the requirements of Chapter 854 and 856 with respect to treatment of hazardous waste.

 

(7)  Residues of hazardous waste in empty containers. Any residue remaining in a container or an inner liner removed from a container that has held any hazardous waste other than hazardous waste identified as acute hazardous waste in Section 4(C)(2), 4(C)(3) or 4(C)(4)(e) is a hazardous waste unless the container is empty as defined below:

 

(a)  All wastes have been removed that can be removed using the practices commonly employed to remove materials from that type container and

 

(b)  No more than one inch of residue containing no free liquids remains on the bottom of the container or inner liner or

 

NOTE: Removing free liquids from a container may include: draining the emptied container for at least thirty (30) seconds after the steady flow of hazardous waste has ceased and individual droplets are clearly evident and then performing that procedure two more times.

 

(c)  The container or inner liner has been triple rinsed using a solvent capable of removing the waste, or

 

(d) If the container has held a hazardous waste that is a compressed gas, the pressure in the container is at atmospheric.

 

      Any residue remaining in a container or an inner liner removed from a container that has held an acute hazardous waste is empty if the container or inner liner has been triple rinsed using a solvent capable of removing the waste or, in the case of a container, the inner liner that prevented contact of the commercial chemical product or manufacturing chemical intermediate with the container, has been removed.

 

(8)  The use of material which is contaminated or mixed with dioxin or any other hazardous waste identified in Chapter 850, for dust suppression or road treatment is prohibited.

 

(9)  No fuel which contains any hazardous waste may be burned in any cement kiln unless licensed under Chapter 856.

 

(10) Persons who generate, transport, or collect non‑leaking spent lead acid batteries, or who store non‑leaking spent batteries but do not reclaim or intend to reclaim them are not required to obtain a license for such a facility.

 

(11) Owners or operators of facilities that store spent lead acid batteries before reclaiming them are required to obtain a license for such storage under Chapter 856.

 

 (12) Delistings: [RESERVED]

 

RESERVED SPACE

 

(13)      Special Requirements for Universal Wastes

 

(a)  All generators of universal wastes must comply with either the full Hazardous Waste Management Rules, Chapter 850 through 857, including all requirements in this Section, or the alternative standards of Chapter 858.

 

(b)  Universal Wastes are:

 

                                                     (i)            Architectural paint

 

                                                   (ii)            Cathode ray tubes;

 

                                                 (iii)            Lamps;

 

                                                 (iv)            Mercury Devices;

 

                                                   (v)            Mercury thermostats;

 

                                                 (vi)            Motor Vehicle Mercury Switches;

 

                                               (vii)            Totally enclosed, non leaking polychlorinated biphenyl (PCB) ballast;

 

NOTE: Only mercury-containing lamps or lamps otherwise hazardous are included as universal wastes.

 

NOTE: Batteries are managed as universal waste in accordance with Section (14).

 

(c) Generators, owners or operators of any central accumulation or consolidation facility, and transporters of universal wastes are prohibited from conducting the following activities:

 

(i)   Disposing, diluting or treating universal wastes.

 

NOTE: The intentional breaking of universal wastes including Cathode Ray Tubes is a form of treatment, and is therefore prohibited at locations other than the recycling facility.

 

(ii)  Sending a universal waste to any facility other than a central accumulation facility, a consolidation facility for universal waste, an approved recycling facility for universal wastes, or in the case of ballasts and the residues from mercury spill kits to an approved disposal or treatment facility.

 

NOTE: Generators that self-transport waste must comply with universal waste transporter requirements, as provided in Section 11 of Chapter 853.

 

NOTE: Chapters 854 and 856 apply to a universal waste recycling facility.

 

(c)    Household hazardous waste, which meets the description of universal waste in Section 4A(13)(b) but which is exempt under Section 4A(4)(a)(vii), when combined or mixed with universal wastes is no longer exempt and must be managed in accordance with the requirements of Chapter 850, 851, 853, 856, 857, and 858.

 

(e)  All generators of universal wastes must:

 

(i)         Determine whether the waste generated is hazardous in accordance with Section 5 of Chapter 851 and , pursuant to 38 M.R.S.A. § 1663 determine that all mercury containing lamps are a universal waste; and

 

(ii)  Determine whether the waste is a universal waste under section 13(b) above;

 

NOTE: If a hazardous waste is not eligible for regulation under the universal waste rules, then the full hazardous waste management rules apply.

 

(iii) Immediately contain and transfer all releases of waste and residues resulting from spills or leaks from broken or ruptured universal waste to a container that meets the requirements of the Maine Hazardous Waste Management Rules (Chapter 850 through 857), except that waste and residues from incidental breakage may still be managed as a universal waste;

 

(iv) Determine by testing, or handle as hazardous, clean up residues resulting from spills or leaks from events other than incidental breakage of lamps or CRTs in accordance with Maine Hazardous Waste Management Rules (Chapter 850 through 857) including generator accumulation time limit, storage and disposal standards, and count this waste toward the determination of hazardous waste generator status;


 

(14)   Special requirements for certain batteries

 

Batteries that are described in 40 CFR 273.2 revised as of July 1, 2001 must be managed in accordance with 40 CFR 273 revised as of July 1, 2001, except that references to 40 CFR Parts 260 through 272 shall mean 850 through 857 of the Maine Hazardous Waste Management Rules and except that 40 CFR 273.8(a)(2) is not adopted, and instead, batteries handled by federally conditionally exempt small quantity generators are regulated as small quantity handlers pursuant to 40 CFR 273 Subpart B. In addition, instead of 40 CFR 273.2(c), a battery becomes a waste on the date that it becomes useless, unwanted, or intended for disposal, and spent lead acid batteries described in 40 CFR 273.2(a)(2) and 273.2(b)(1) are regulated under 850 through 858 instead of 40 CFR part 266, subpart G.

 

B.   Identification of hazardous wastes by characteristics

 

(1)  General

 

(a)  A waste which is not excluded from regulation as a hazardous waste under Section 4(A)(4) of this rule is a hazardous waste if it exhibits any of the characteristics identified in this rule.

 

(b)  A hazardous waste which is identified by a characteristic in this section, but is not listed as a hazardous waste in Section 4(C), is assigned the EPA Hazardous Waste Number set forth in the respective characteristic. This number, alone or in combination with another number assigned by the Department as provided by rule, must be used in complying with regulatory requirements as provided by rule.

 

(c) For purposes of this Section 4(B) of this rule, the Department will consider a sample obtained using any of the applicable sampling methods specified in Appendix I of this rule to be a representative sample within the meaning of 40 CFR 260.10 of EPA regulations. Until the Appendix I sampling methods are formally adopted by EPA, a person who desires to employ an alternative sampling method must demonstrate the equivalency of his method under the procedures set forth in 40 CFR 260.20 and 260.2l.

 

(2)  Characteristic of ignitability

 

(a)  A waste exhibits the characteristic of ignitability if a representative sample of the waste has any of the following properties:

 

(i)                 It is a liquid, other than an aqueous solution containing less than 24 percent alcohol by volume, and has a flash point less than 60º C (l40º F) as determined by a Pensky-Martens Closed Cup Tester, using the test method specified in ASTM Standard D‑93‑79 or D‑93‑80, or a Setaflash Closed Cup Tester, using the test method specified in ASTM standard D‑3278‑78, or as determined by an equivalent test method approved by the EPA under the procedures set forth in 40 CFR 260.20 and 260.21.[1]

 

(ii)               It is not a liquid and is capable, under standard temperature and pressure, of causing fire through friction, absorption of moisture or spontaneous chemical changes and, when ignited, burns so vigorously and persistently that it creates a hazard.

 

(iii)             It is an ignitable compressed gas as defined in 49 CFR l73.300 and as determined by the test methods described in that regulation or equivalent test methods approved by EPA under 40 CFR 260.20 and 260.2l.

 

(iv)             It is an oxidizer as defined in 49 CFR l73.151.

 

(b)  A waste that exhibits the characteristic of ignitability, but is not listed as a hazardous waste in Section 4(C) of this rule, has the EPA Hazardous Waste Number of D001.

 

(3)  Characteristic of corrosivity

 

(a)  A waste exhibits the characteristic of corrosivity if a representative sample of the waste has either of the following properties:

 

(i)                 It is aqueous and has a pH less than or equal to 2 or greater than or equal to 12.5, as determined by a pH meter using either the test method specified in the "Test Methods for the Evaluation of Solid Waste, Physical/Chemical Methods"[2] (also described in "Methods for Analysis of Water and Wastes" EPA 600/4‑79‑020, March, 1979), or an equivalent test method approved by EPA under the procedures set forth in 40 CFR 260.20 and 260.21.

 

(ii)               It is a liquid and corrodes steel (SAE l020) at a rate greater than 6.35 mm (0.250 inch) per year at a test temperature of 55º C (130º F) as determined by the test method specified in NACE (National Association of Corrosion Engineers) Standard TM‑01‑69[3] as standardized in "Test Methods for the Evaluation of Solid Waste, Physical/Chemical Methods," or an equivalent test method approved by EPA under the procedures set forth in 40 CFR 260.20 and 260.2l.

 

(b)  A waste that exhibits the characteristic of corrosivity, but is not listed as a hazardous waste in Section 4(C) of this rule, has the EPA Hazardous Waste Number of D002.

 


 

(4)  Characteristic of reactivity

 

(a)  A waste exhibits the characteristic of reactivity if a representative sample of the waste has any of the following properties:

 

(i)                 It is normally unstable and readily undergoes violent change without detonating.

 

(ii)               It reacts violently with water.

 

(iii)             It forms potentially explosive mixtures with water.

 

(iv)             When mixed with water, it generates toxic gases, vapors or fumes in a quantity sufficient to present a danger to human health or the environment.

 

(v)               It is a cyanide or sulfide bearing waste which, when exposed to pH conditions between 2 and l2.5, can generate toxic gases, vapors or fumes in a quantity sufficient to present a danger to human health or the environment.

 

(vi)             It is capable of detonation or explosive reaction if it is subjected to a strong initiating source or if heated under confinement.

 

(vii)           It is readily capable of detonation or explosive decomposition or reaction at standard temperature and pressure.

 

(v)               It is a forbidden explosive as defined in 49 CFR l73.5l, or a Class A explosive as defined in 49 CFR l73.53 or a Class B explosive as defined in 49 CFR l73.88.

 

(b)  A waste that exhibits the characteristic of reactivity, but is not listed as a hazardous waste in Section 4(C) of this rule, has the EPA Hazardous Waste Number of D003.

 

(5)  Characteristic of toxicity

 

(a)  A waste exhibits the characteristic of toxicity if, using the test methods described in Appendix II or equivalent methods approved by EPA under the procedures set forth in 40 CFR 260.20 and 260.21, the extract from a representative sample of the waste contains any of the contaminants listed in Table I at the concentration equal to or greater than the respective value given in that Table. Where the waste contains less than 0.5 percent filterable solids, the waste itself, after filtering using the methodology outlined in Appendix II, is considered to be the extract for the purpose of this section.

 

(b)  A waste that exhibits the characteristic of toxicity has the EPA Hazardous Waste Number specified in Table I which corresponds to the toxic contaminant causing it to be hazardous.


 

 

Table I. Maximum Concentration of Contaminants for the Toxicity Characteristic

 

 

EPA

Hazardous

Waste No.

 

 

Contaminant

 

Regulatory

Level

(mg/L)

 

      D004.................................................. Arsenic............................................. 5.0

      D005.................................................. Barium......................................... 100.0

      D006.................................................. Cadmium.......................................... l.0

      D007.................................................. Chromium........................................ 5.0

      D016.................................................. 2,4‑D.............................................. 10.0

      D012.................................................. Endrin............................................ 0.02

      D008.................................................. Lead................................................. 5.0

      D013.................................................. Lindane............................................ 0.4

      D009.................................................. Mercury............................................ 0.2

      D014.................................................. Methoxychlor................................. 10.0

      D010.................................................. Selenium.......................................... 1.0

      D011.................................................. Silver................................................ 5.0

      D015.................................................. Toxaphene........................................ 0.5

      D017.................................................. 2,4,5‑TP (Silvex).............................. 1.0

 

C.  Identification of hazardous wastes by particular substance, by chemical class or as waste products of specific industrial activities

 

(1)  General

 

(a)  A waste is a hazardous waste if it is listed in Section 4(C) of this rule unless it has been excluded by EPA under 260.20 and 260.22 of EPA regulations and excluded subsequently by the Maine Board of Environmental Protection.

 

(b)  Each hazardous waste listed in this section is assigned an EPA Hazardous Waste Number and/or a number assigned by the Department as provided by rule. These numbers, alone or in combination, must be used in complying with regulatory requirements as provided by rule.

 

(c)  Certain of the hazardous waste listed in Section 4(C)(2) or 4(C)(3) have exclusion limits that refer to Section 4(A)(5)(c).

 

(2)  Hazardous wastes from non-specific sources. A waste is a hazardous waste if it is listed below:

 

Industry and EPA

Hazardous No.

 

 

Hazardous Waste

Hazardous

Waste Code[4]

 

Generic:

F001

 

 

The following waste halogenated solvents used in degreasing: tetrachloroethylene, trichloroethylene, methylene chloride, 1,1,1‑trichloroethane, carbon tetrachloride and chlorinated fluorocarbons; all waste solvent mixtures/blends used in degreasing containing, before use, a total of ten percent or more (by volume) of one or more of the above halogenated solvents or those solvents listed in F002, F004, and F005; and still bottoms from the recovery of these waste solvents and waste solvent mixtures.

 

(T)

 

F002

The following waste halogenated solvents: tetrachloroethylene, methylene chloride, trichloroethylene, 1,1,1‑trichloroethane, chlorobenzene, 1,1,2‑trichloro‑1,2,2‑trifluoroethane, ortho‑dichlorobenzene, trichlorofluoromethane and 1,1,2‑trichloroethane; all waste solvent mixtures/blends containing, before use, a total of ten percent or more (by volume) of one or more of the above halogenated solvents or those solvents listed in F001, F004, and F005; and still bottoms from the recovery of these waste solvents and waste solvent mixtures.

(T)

 

F003

The following waste non‑halogenated solvents: xylene, acetone, ethyl acetate, ethyl benzene, ethyl ether, methyl isobutyl ketone, n‑butyl alcohol, cyclohexanone, and methanol; all waste solvent mixtures/blends containing before use, only the above waste non‑halogenated solvents; and all waste solvent mixtures/blends containing, before use one or more of the above non‑halogenated solvents, and, a total of ten percent or more (by volume) of one or more of those solvents listed in F001, F002, F004, or F005; and still bottoms from the recovery of these waste solvents and waste solvent mixtures.

(I)[5]

 

F004

The following waste non‑halogenated solvents: cresols and cresylic acid and nitrobenzene; all waste solvent mixtures/blends containing, before use, a total of ten percent or more (by volume) of one or more of the above non‑halogenated solvents or those solvents listed in F001, F002, and F005; and still bottoms from the recovery of these waste solvents and waste solvent mixtures.

(T)

 

F005

The following waste non‑halogenated solvents: toluene, methyl ethyl ketone, carbon disulfide, isobutanol, pyridine, benzene, 2‑ethoxyethanol, and 2‑nitropropane; all waste solvent mixtures and blends containing before use, a total of ten percent or more (by volume) of one or more of the above non‑halogenated solvents or those solvents listed in F001, F002, or F004; and still bottoms from the recovery of these waste solvents and waste solvent mixtures.

 

(T, I)

 

For the purposes of administering and enforcing this Rule, the Department presumes that a discharge to any land or surface or ground waters is the result of a discharge of hazardous waste if such discharge contains the presence of any waste identified in F001‑F005. In order to overcome this presumption, a person must demonstrate to the satisfaction of the Commissioner through clear and convincing evidence that the waste was discharged prior to 1980 or that the waste, at the time of discharge, was not a hazardous waste as identified in F001‑F005 above.

 

F006

Wastewater treatment sludges from electroplating operations except from the following processes: (1) sulfuric acid anodizing of aluminum; (2) tin plating on carbon steel; (3) zinc plating (segregated basis) on carbon steel; (4) aluminum or zinc‑aluminum plating on carbon steel; (5) cleaning/stripping associated with tin, zinc and aluminum plating on carbon steel; and (6) chemical etching and milling of aluminum.

(T)

 

F007

Spent cyanide plating bath solutions from electroplating operations.

(R,T)

 

F008

Plating bath residues from the bottom of plating baths from electroplating operations where cyanides are used in the processes.

(R,T)

 

F009

Spent stripping and cleaning bath solutions from electroplating operations where cyanides are used in the process.

(R,T)

 

F010

Quenching bath residues from oil baths from metal heat treating operations where cyanides are used in the process.

(R,T)

 

F011

Spent cyanide solutions from salt bath pot cleaning from metal heat treating operations.

(R,T)

 

F012

Quenching wastewater treatment sludges from metal heat treating operations where cyanides are used in the process.

(T)

 

F019

Wastewater treatment sludges from the chemical conversion coating of aluminum.

(T)

 

F020

Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the production or manufacturing use [as a reactant, chemical intermediate or component in a formulating process] of tri‑ or tetrachlorophenol, or of intermediates used to produce their pesticide derivatives. (This listing does not include wastes from the production of Hexachlorophene from highly purified 2,4,5‑trichlorophenol.)

(H)

 

F021

Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the production or manufacturing use (as a reactant, chemical intermediate or component in a formulating process) of pentachlorophenol, or of intermediates used to produce its derivatives.

(H)

 

F022

Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the manufacturing use (as a reactant, chemical intermediate, or component in a formulating process) of tetra‑, penta‑, or hexachlorobenzenes under alkaline conditions.

(H)

 

F023

Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the production of material on equipment previously used for the production or manufacturing use (as a reactant, chemical intermediate, or component in a formulating process) of tri‑, and tetrachlorophenols. (This listing does not include wastes from equipment used only for the production or use of Hexachlorophene from highly purified 2,4,5‑trichlorophenol.)

(H)

 

F024

Wastes, including but not limited to distillation residues, heavy ends, tars and reactor clean‑out and reactor clean‑out wastes from the production of chlorinated aliphatic hydrocarbons, having carbon content from one to five, utilizing free radical catalyzed processes. (This listing does not include, wastewaters, wastewater treatment sludges, spent catalysts, and wastes listed in 40 CFR 261.31 or 261.32).

(T)

 

F025

Condensed light ends, spent filters, and filter aids, and spent dessicant wastes from the production of chlorinated aliphatic hydrocarbons, by free radicalized processes, having carbon chain lengths ranging from one to and including five, with varying amounts and portions of chlorine substitution.[6]

(T)

 

F026

Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the production of materials on equipment previously used for the manufacturing use (as a reactant, chemical intermediate, or component in a formulating process) of tetra‑, penta‑, or hexachlorobenzene under alkaline conditions.

(H)

 

F027

Discarded unused formulations containing tri‑, tetra‑, or pentachlorophenol or discarded unused formulations containing compounds derived from these chlorophenols. (This listing does not include formulations containing Hexachlorophene synthesized from prepurified 2,4,5‑trichlorophenol as the sole component.)

(H)

 

F028

Residues resulting from the incineration or thermal treatment of soil contaminated with EPA Hazardous Waste Nos. F020, F02l, F022, F023, F026, and F027.

(T)

 

F039

Leachate (liguids that have percolated through land disposed wastes) resulting from the disposal of more than one restricted waste classified as hazardous under this chapter. (Leachate resulting from the disposal of one or more of the following EPA Hazardous Wastes and no other Hazardous Wastes retains its EPA Hazardous Waste Number(s): F020, F021, F022, F026, F027, and/or F028).

(T)

 

 

(b)  Polychlorinated biphenyl (PCB) and polychlorinated biphenyls (PCBs), where PCB and PCBs means any chemical substance that is limited to the biphenyl molecule that has been chlorinated to varying degrees or any combination of substances which contains such substance.

 

(i)   Except as provided in (AA) below, any chemical substances or combination of substances that contain 50 parts per million (on a dry weight basis) or greater of PCBs are subject to these regulations. "PCB Item" as defined in 40 CFR Part 761.3 as it appeared on July 1, 1982 is also subject to these regulations.

 

      Substances that are regulated by this rule include, but are not limited to, dielectric fluids, contaminated solvents, oils, waste oils, heat transfer fluids, hydraulic fluids, paints, sludges, slurries, dredge spoils, soils, materials contaminated as a result of spills, and other chemical substances or combination of substances, including impurities and byproducts.

 

(AA) The use of waste oil that contains any detectable concentration of PCB as a sealant, coating, or dust control agent is prohibited. Prohibited uses include, but are not limited to, road oiling, general dust control, use as a pesticide or herbicide carrier, and use as a rust preventative on pipes.

 

NOTE: Road oiling with waste oil is a prohibited act under Chapter 860 of the Department's Rules.

 

(ii)  Any chemical substance or combinations of chemical substances that contain less than 50 parts per million (ppm) PCBs as the result of dilution shall be subject to these regulations unless otherwise specifically provided by 40 CFR 761, except that PCB contaminated media at an uncontrolled hazardous substance site managed, treated or disposed of in accordance with a Department approved removal or remedial action plan may be managed according to the concentrations detected in the media.

 

(iii) For the purposes of this rule, the following are considered hazardous waste and are subject to regulation under 38 M.R.S.A., §1301, et seq.:

 

(AA) PCB or PCBs that are useless, unwanted,discarded or intended to be discarded;

 

(BB) PCB or PCBs that are "discharged" as defined by 38 M.R.S.A., §1317;

 

NOTE: Any person to whom AA or BB. applies is considered a generator of hazardous waste.

 

(CC) PCB or PCBs generated from off site, where the generator and the satellite facility are owned and operated by the same entity, other than those contained in a totally enclosed manner in equipment such as electrical transformers, capacitors, and hydraulic systems that are not intended to be discarded, that are stored at a site which is used or capable of being used to store as follows:

 

(1)  greater than 165 gallons of PCBs for more than 10 working days is considered a storage facility for hazardous waste; or

 

(2)  less than 165 gallons of PCBs, for more than 10 working days, or greater than 165 gallons for less than 10 working days, is not considered to be a storage facility for hazardous waste, provided that the facility obtains an abbreviated license under Chapter 856, Section 11A(8); or

 

(3)  less than 165 gallons of PCBs for less than 10 working days are exempt from the hazardous waste storage facility licensing requirements.

 

DD. PCB or PCBs that are subjected to or intended to be subjected to treatment so as to reduce or otherwise alter the concentration of PCB or PCBs.

 

NOTE: Any person to whom Section DD applies is considered a treatment facility for hazardous waste.

 

(iv) Disposal of PCB and PCBs is excluded from regulation under Chapters 854, 855 and 856 of the Department's rules in so far as that disposal is in fact regulated under 40 CFR 761.

 

NOTE: Federal law currently prohibits a State from regulating the disposal of PCB and PCBs. This exclusion does not apply to PCB and PCBs while they are being handled before disposal.

 

(v)  PCB and PCBs are identified as toxic wastes (T) and are assigned the Hazardous Waste Number M002.

 

(vi) "Alteration" or "treatment" as used in the Department's rules shall not include the routine servicing of equipment where PCB or PCBs are contained in a totally enclosed manner.

 

(3)  Hazardous Wastes from specific sources. A waste is a hazardous waste if it is listed in the table below:

 

 

Industry and EPA

Hazardous No.

 

 

Hazardous Waste

 

Hazardous

Waste Code

 

 

Wood Preservation:

K001

 

Bottom sediment sludge from the treatment of waste waters from wood preserving processes that use creosote and/or pentachlorophenol.

 

(T)

 

Inorganic pigments:

K002

 

Wastewater treatment sludge from the production of chrome yellow and orange pigments.

 

(T)

 

K003

Wastewater treatment sludge from the production of molybdate orange pigments.

(T)

 

K004

Wastewater treatment sludge from the production of zinc yellow pigments.

(T)

 

K005

Wastewater treatment sludge from the production of chrome green pigments.

(T)

 

K006

Wastewater treatment sludge from the production of chrome oxide green pigments (anhydrous and hydrated).

(T)

 

K007

Wastewater treatment sludge from the production of iron

blue pigments.

(T)

 

K008

Oven residue from the production of chrome oxide green pigments.

(T)

 

Organic chemicals:

K009

 

Distillation bottoms from the production of acetaldehyde from ethylene.

 

(T)

 

K010

Distillation side cuts from the production of acetaldehyde from ethylene.

(T)

 

K011

Bottom stream from the wastewater stripper in the production of acrylonitrile.

(R,T)

 

K013

Bottom stream from the acetonitrile column in the production of acrylonitrile.

(R,T)

 

K014

Bottoms from the acetonitrile purification column in the production of acrylonitrile.

(T)

 

K015

Still bottoms from the distillation of benzyl chloride.

(T)

 

K016

Heavy ends or distillation residues from the production of carbon tetrachloride.

(T)

 

K017

Heavy ends (still bottoms) from the purification column in the production of epichlorohydrin.

(T)

 

K018

Heavy ends from the fractionation column in ethyl chloride production.

(T)

 

K019

Heavy ends from the distillation of ethylene dichloride in ethylene dichloride production.

(T)

 

K020

Heavy ends from the distillation of vinyl chloride in vinyl chloride monomer production.

(T)

 

K021

Aqueous spent antimony catalyst waste from fluoromethanes production.

(T)

 

K022

Distillation bottom tars from the production of phenol/acetone from cumene.

(T)

 

K023

Distillation light ends from the production of phthalic anhydride from naphthalene.

(T)

 

K024

Distillation bottoms from the production of phthalic anhydride from naphthalene.

(T)

 

K025

Distillation bottoms from the production of nitrobenzene by the nitration of benzene.

(T)

 

K026

Stripping still tails from the production of methyl ethyl pyridines.

(T)

 

K027

Centrifuge and distillation residues from toluene diisocyanate production.

(R,T)

 

K028

Spent catalyst from the hydrochlorinator reactor in the production of 1,1,1‑trichloroethane.

(T)

 

K029

Waste from the product steam stripper in the production of 1,1,1‑trichloroethane.

(T)

 

K030

Column bottoms or heavy ends from the combined production of trichloroethylene and perchloroethylene.

(T)

 

K083

Distillation bottoms from aniline production.

(T)

 

K085

Distillation or fractionation column bottoms from the production of chlorobenzenes.

(T)

 

K093

Distillation light ends from the production of phthalic anhydride from ortho‑xylene.

(T)

 

K094

Distillation bottoms from the production of phthalic anhydride from ortho‑xylene.

(T)

 

K095

Distillation bottoms from the production of l,l,l‑tri-chloroethane.

(T)

 

K096

Heavy ends from the heavy ends column from the production of l,l,l‑trichloroethane.

(T)

 

K103

Process residues from aniline extraction from the production of aniline.

(T)

 

K104

Combined wastewater streams generated from nitrobenzene/aniline production.

(T)

 

K105

Separated aqueous stream from the reactor product washing step in the production of chlorobenzene.

(T)

 

K107[7]

Column bottoms from product separation from the production of 1,1‑dimethylhydrazine (UDMH) from carboxylic acid hydrazides.

(C,T)

 

K1087

Condensed column overheads from product separation and condensed reactor vent gases from the production of l,l‑dimethylhydrazine (UDMH) from carboxylic acid hydrazides.

(I,T)

 

K109

Spent filter cartridges from product purification from the production of 1,1‑dimethylhydrazine (UDMH) from carboxylic acid hydrazides.

(T)

 

K110

Condensed column overheads from intermediate separation from the production of 1,1‑dimethylhydrazine (UDMH)      from carboxylic acid hydrazides.

(T)

 

K111

Product washwaters from the production of dinitrotoluene via nitration of toluene.

(C,T)

 

K112

Reaction by‑product water from the drying column in the production of toluenediamine via hydrogenation of dinitrotoluene.

(T)

 

K113

Condensed liquid light ends from the purification of toluenediamine in the production of toluenediamine via hydrogenation of dinitrotoluene.

(T)

 

K114

Vicinals from the purification of toluenediamine in the production of toluenediamine via hydrogenation of dinitrotoluene.

(T)

 

K115

Heavy ends from the purification of toluenediamine in the production of toluenediamine via hydrogenation of dinitrotoluene.

(T)

 

K116

Organic condensate from the solvent recovery column in the production of toluenedisocyanate via phosgenation of dinitrotoluene.

(T)

 

K117

Wastewater from the reactor vent gas scrubber in the production of ethylene dibromide via bromination of ethene.

(T)

 

K118

Spent adsorbent solids from the purification of ethylene dibromide in the production of ethylene dibromide via bromination of ethene.

(T)

 

K136

Still bottoms from the purification of ethylene dibromide in the production of ethylene dibromide via bromination of ethene.

(T)

 

K119[8]

Wastes from the decantor in the production of linuron.

(I,C,T)

 

K1208

Wastes from the spill control trap in production of linuron.

(I,T)

 

K1218

Wastewater from product filtration and water washing in the production of bromacil.

(T)

 

K123

Process wastewater (including supernates, filtrates, and washwaters) from the production of ethylenebisdithiocarbamic acid and its salts.

(T)

 

K124

Reactor vent scrubber water from the production of ethylenebisdithiocarbamic acid and its salts.

(C,T)

 

K125

Purification solids (including filtration, evaporation, and centrifugation solids) from the production of ethylenebisdithiocarbamic acid and its salts.

(T)

 

K126

Baghouse dust and floor sweepings in milling and packaging operations from the production or formulation of ethylenebisdithiocarbamic acid and its salts.

(T)

 

K131

Wastewater from the reactor and spent sulfuric acid from the acid drier from the production of methyl bromide.

(C,T)

 

K132

Spent adsorbent and wastewater separator solids from the production of methyl bromide.

(T)

 

Inorganic chemicals:

K071

 

Brine purification muds from the mercury cell process in chlorine production, where separately prepurified brine is not used.

(T)

 

K073

Chlorinated hydrocarbon waste from the purification step of the diaphragm cell process using graphite anodes in chlorine production.

(T)

 

K106

Wastewater treatment sludge from the mercury cell process in chlorine production.

(T)

 

Pesticides:

K031

 

By‑product salts generated in the production of MSMA and cacodylic acid.

(T)

 

K032

Wastewater treatment sludge from the production of chlordane.

(T)

 

K033

Wastewater and scrub water from the chlorination of cyclopentadiene in the production of chlordane.

(T)

K034

Filter solids from the filtration of hexachloro-cyclopentadiene in the production of chlordane.

(T)

K035

Wastewater treatment sludges generated in the production of creosote.

(T)

K036

Still bottoms from toluene reclamation distillation in the production of disulfoton.

(T)

K037

Wastewater treatment sludges from the production of disulfoton.

(T)

K038

Wastewater from the washing and stripping of phorate production.

(T)

K039

Filter cake from the filtration of diethylphosphoro-dithioic acid in the production of phorate.

(T)

 

K040

Wastewater treatment sludge from the production of phorate.

(T)

 

K041

Wastewater treatment sludge from the production of toxaphene.

(T)

 

K042

Heavy ends or distillation residues from the distillation of tetrachlorobenzene in the production of 2,4,5‑T.

(T)

 

K043

2,6‑Dichlorophenol waste from the production of 2,4‑D.

(T)

 

K097

Vacuum stripper discharge from the chlordane chlorinator in the production of chlordane.

(T)

 

K098

Untreated process wastewater from the production of toxaphene.

(T)

 

K099

Untreated wastewater from the production of 2,4‑D.

(T)

 

Explosives:

K044

 

Wastewater treatment sludges from the manufacturing and processing of explosives.

(R)

 

K045

Spent carbon from the treatment of wastewater containing explosives.

(R)

 

K046

Wastewater treatment sludges from the manufacturing, formulation and loading of lead‑based initiating compounds.

(T)

 

K047

Pink/red water from TNT operations.

(R)

 

Petroleum refining:

K048

 

Dissolved air flotation (DAF) float from the petroleum refining industry.

(T)

 

K049

Slop oil emulsion solids from the petroleum refining industry.

(T)

 

K050

Heat exchanger bundle cleaning sludge from the petroleum refining industry.

(T)

 

K051

API separator sludge from the petroleum refining industry.

(T)

 

K052

Tank bottoms (leaded) from the petroleum refining industry.

(T)

 

Iron and steel:

K061

 

Emission control dust/sludge from the primary production of steel in electric furnaces.

(T)

 

K062

Spent pickle liquor from steel finishing operations.

(C,T)

 

Primary copper:

K064

 

Acid plant blowdown slurry/sludge resulting from the thickening of blowdown slurry from primary copper production.

(T)

 

Primary lead:

K065

 

Surface impoundment solids contained in and dredged from surface impoundments at primary lead smelting facilities.

(T)

 

Primary zinc:

K066

 

Sludge from treatment of process wastewater and/or acid plant blowdown from primary zinc production.

(T)

 

Primary aluminum:

K088

 

Spent potliners from primary aluminum reduction.

(T)

 

Ferroalloys:

K090

 

Emission control dust or sludge from ferrochromiumsilicon production.

(T)

 

K091

Emission control dust or sludge from ferrochromium production.

(T)

 

Secondary lead:

K069

 

Emission control dust/sludge from secondary lead smelting.

(T)

 

K100

Waste leaching solution from acid leaching of emission control dust/sludge from secondary lead smelting.

(T)

 

Veterinary pharmaceuticals:

 

 

K084

Wastewater treatment sludges generated during the production of veterinary pharmaceuticals from arsenic or organo‑arsenic compounds.

(T)

 

K101

Distillation tar residues from the distillation of aniline‑based compounds in the production of veterinary pharmaceuticals from arsenic or organo‑arsenic compounds.

(T)

 

K102

Residue from the use of activated carbon for decolorization in the production of veterinary pharmaceuticals from arsenic or organo‑arsenic compounds.

(T)

 

Ink formulation:

K086

 

Solvent washes and sludges, caustic washes and sludges, or water washes and sludges from cleaning tubs and equipment used in the formulation of ink from pigments, driers, soaps, and stabilizers containing chromium and lead.

(T)

 

Coking:

K060

 

Ammonia still lime sludge from coking operations.

(T)

 

K087

Decanter tank tar sludge from coking operations.

(T)

 

 

(4)  Discarded commercial chemical products, off-specification species, container residues, and spill residues thereof. The following materials or items are hazardous wastes if and when they are discarded or intended to be discarded, when they are mixed with other material and applied to the land for dust supression or road treatment, when they are otherwise applied to the land in lieu of their original intended use or when they are contained in products that are applied to the land in lieu of their original intended use or when, in lieu of their original intended use, they are produced for use as (or as a component of) a fuel, distributed for use as a fuel, or burned as a fuel:

 

(a)  Any commercial chemical product, or manufacturing chemical intermediate having the generic name listed in paragraphs (e) or (f) of this section.

 

(b)  Any off‑specification commercial chemical product or manufacturing chemical intermediate which, if it met specifications, would have the generic name listed in paragraphs (e) or (f) of this section.

 

(c)  Any residue remaining in a container or an inner liner removed from a container that has held any commercial chemical product or manufacturing chemical intermediate having the generic name listed in paragraph (e) of this section, unless the container is empty as defined in Section 4(A)(7) of this Chapter. Containers which have contained medicinal nitroglycerin are considered empty if they meet the provisions of Section 4(A)(7)(a) and (b).

 

(d) Any residue or contaminated soil, water or other debris resulting from the cleanup of a spill into or on any land or water of any commmercial chemical product or manufacturing chemical intermediate having the generic name listed in paragraph (e) or (f) of this section, or any residue or contaminated soil, water or other debris resulting from the cleanup of a spill, into or on any land or water, of any off‑specification chemical product and manufacturing chemical intermediate which, if it met specifications, would have the generic name listed in paragraph (e) or (f) of this section.

 

NOTE: The phrase "commercial chemical product or manufacturing chemical intermediate having the generic name listed in . . ." refers to a chemical substance manufactured or formulated for commercial or manufacturing use which consists of: (1) the commercially pure grade of the chemical, (2) any technical grades of the chemical that are produced or marketed, (3) any formulations in which the P or U listed chemical is the sole active ingredient regardless of the percent composition, or (4) effective Janaury 1, 1995, any formulations in which the P listed chemical is an active ingredient of 10% or more. It does not refer to a material, such as a manufacturing process waste, that contains any of the substances listed in paragraphs (e) or (f). Where a manufacturing process waste is deemed to be a hazardous waste because it contains a substance listed in paragraphs (e) or (f), such waste will be listed in either Section 4(C)(2) or Section 4(C)(3) or will be identified as a hazardous waste by the characteristics set forth in Section 4(B) of this rule.

 

(e)  The commercial chemical products, manufacturing chemical intermediates or off‑specification commercial chemical products or manufacturing chemical intermediates referred to in paragraphs (a) through (d) of this section, are identified as acute hazardous wastes (H) and are subject to the small quantity exclusion defined in Section 4(A)(5)(c).

 

NOTE: For the convenience of the regulated community the primary hazardous properties of these materials have been indicated by the letters T* (Human Toxicity), and R (Reactivity). Absence of a letter indicates that the compound is listed on the basis of animal toxicity data.

 

      These wastes and their corresponding EPA Hazardous Waste Numbers are:

 

Hazardous

Waste

Number                       Substance

 

P023                            Acetaldehyde, chloro‑

P002                            Acetamide, N‑(aminothioxomethyl)‑

P057                            Acetamide, 2‑fluoro‑

P058                            Acetic acid, fluoro‑, sodium salt

P002                            1‑Acetyl‑2‑thiourea

P003                            Acrolein

P124                            Actinomycin D*

P070                            Aldicarb

P004                            Aldrin

P005                            Allyl alcohol

P006                            Aluminum phosphide (R,T)

P007                            5‑(Aminomethyl)‑3‑isoxazolol

P008                            4‑Aminopyridine

P009                            Ammonium picrate (R)

P119                            Ammonium vanadate

P125                            Antimony, when in the form of particles 100 microns or less*

P099                            Argentate(1‑), bis(cyano‑C)‑, potassium

P010                            Arsenic acid H3AsO4

P012                            Arsenic oxide As2O3

P011                            Arsenic oxide As2O5

P011                            Arsenic pentoxide

P012                            Arsenic trioxide

P038                            Arsine, diethyl

P036                            Arsonous dichloride, phenyl‑

P054                            Aziridine

P067                            Aziridine, 2‑methyl‑

P150                            Azinphos ethyl*

P151                            Azinphos methyl*

P013                            Barium cyanide

P024                            Benzenamine, 4‑chloro‑

P077                            Benzenamine, 4‑nitro‑

P028                            Benzene, (chloromethyl)‑

P042                            1,2‑Benzenediol, 4‑[1‑hydroxy‑2‑(methylamino)ethyl]‑,(R)‑

P046                            Benzeneethanamine, alpha, alpha‑dimethyl‑

P014                            Benzenethiol

P001                            2H‑1‑Benzopyran‑2‑one,4‑hydroxy‑3‑(3‑oxo‑1‑        phenylbutyl)‑, & salts, when present at concen‑greater than 0.3%

P028                            Benzyl chloride

P015                            Beryllium

P126                            4,4'‑Bipyridinium, 1,1'‑dimethyl,dichloride*

P017                            Bromoacetone

P018                            Brucine

P045                            2‑Butanone, 3,3‑dimethyl‑1‑(methylthio)‑,    O‑[methylamino)carbonyl] oxime

P021                            Calcium cyanide

P021                            Calcium cyanide Ca(CN)2

P127                            Carbamic acid, methyl‑2,3‑dihydro, 2,2‑dimethyl‑7‑benzofuranyl ester*

P128                            Carbamic acid, methyl, 4‑dimethylamino‑3, 5‑xylyl ester*

P127                            Carbofuran*

P022                            Carbon bisulfide (another name for carbon disulfide)

P022                            Carbon disulfide

P095                            Carbonic dichloride

P095                            Carbonyl chloride (alternative name for phosgene)

P023                            Chloroacetaldehyde

P024                            p‑Chloroaniline

P133                            Chloroethanol*

P143                            Chlorofenvinphos*

P128                            Chlorine*

P026                            1‑(o‑Chlorophenyl)thiourea

P027                            3‑Chloropropionitrile

P029                            Copper cyanide

P029                            Copper cyanide Cu(CN)

P130                            Coumaphos*

P131                            Coumarin,3‑chloro‑7 hydroxy‑4‑methyl,0‑ester with             0,0‑diethyl phosphorothioate*

P131                            Crotonic acid, 3‑hydroxy‑,methyl ester, dimethyl phosphate (E)*

P030                            Cyanides (soluble cyanide salts), not otherwise specified

P031                            Cyanogen

P033                            Cyanogen chloride

P033                            Cyanogen chloride (CN)Cl

P034                            2‑Cyclohexyl‑4,6‑dinitrophenol

P134                            Cycloheximide*

P155                            Demeton*

P144                            Dichlorvos*

P146                            Dicrotophos*

P016                            Dichloromethyl ether

P036                            Dichlorophenylarsine

P037                            Dieldrin

P132                            Diethylamine, 2,2'‑dichloro‑N‑methyl‑*

P039                            0,0‑Diethyl S‑[2‑(ethylthio)ethyl] phosphorodithioate* (another name for Disulfoton)

P038                            Diethylarsine

P041                            Diethyl‑p‑nitrophenyl phosphate

P040                            O,O‑Diethyl O‑pyrazinyl phosphorothioate

P043                            Diisopropylfluorophosphate (DFP)P004        1,4,5,8‑Dimethanonaphthalene, 1,2,3,4,10,10‑hexa‑chloro‑1,4,4a,5,8,8a,‑hexahydro‑, (1alpha,4alpha,4abeta,5alpha, 8alpha, 8abeta)‑

P060                            1,4,5,8‑Dimethanonaphthalene, 1,2,3,4,10,10‑hexa‑chloro‑1,4,4a,5,8,8a‑hexahydro‑, (1alpha,4alpha,4abeta,5beta,8beta,8abeta)‑

P037                            2,7:3,6‑Dimethanonaphth[2,3‑b]oxirene, 3,4,5,6,9,9‑hexachloro‑1a,2,2a,3,6,6a,7,7a‑octahydro‑,(1aalpha,2beta,2aalpha,3beta,6beta,6aalpha,7beta,7aalpha)‑

P051                            2,7:3,6‑Dimethanonaphth[2,3‑b]oxirene, 3,4,5,6,9,9‑hexachloro‑1a,2,2a,3,6,6a,7,7a‑octahydro‑,(1aalpha,2beta,2abeta,3alpha,6alpha,6abeta,7beta,7aalpha)‑, & metabolites

P044                            Dimethoate

P046                            alpha,alpha‑Dimethylphenethylamine

P047                            4,6‑Dinitro‑o‑cresol, & salts

P034                            4,6‑Dinitro‑o‑cyclohexylphenol (another name for 2-Cyclohexyl-4,6-dinitrophenol)

P048                            2,4‑Dinitrophenol

P020                            Dinoseb

P153                            Dioxathion*

P085                            Diphosphoramide, octamethyl‑

P111                            Diphosphoric acid, tetraethyl ester

P039                            Disulfoton

P049                            Dithiobiuret

P050                            Endosulfan

P088                            Endothall

P051                            Endrin

P051                            Endrin, & metabolites

P042                            Epinephrine

P141                            EPN*

P046                            Ethanamine, 1,1‑dimethyl‑2‑phenyl‑ (alternative name for alpha, alpha-Dimethylphenethylamine)

P031                            Ethanedinitrile

P066                            Ethanimidothioic acid, N‑[[methylamino) carbonyl]oxy]‑,methyl ester

P154                            Ethion*

P101                            Ethyl cyanide

P054                            Ethyleneimine

P097                            Famphur

P156                            Fensulfothion*

P056                            Fluorine

P057                            Fluoroacetamide

P058                            Fluoroacetic acid, sodium salt

P065                            Fulminic acid, mercury (2+) salt (R,T)

P134                            Glutarimide,3‑(2‑(3,5‑dimethyl‑2‑oxocyclohexyl)‑2 hydroxyethyl)*

P059                            Heptachlor

P062                            Hexaethyl tetraphosphate

P135                            Hydantoin, 5,5‑diphenyl‑*

P136                            Hydantoin, 5,5‑diphenyl‑monosodium salt*

P116                            Hydrazinecarbothioamide

P068                            Hydrazine, methyl‑

P063                            Hydrocyanic acid

P063                            Hydrogen cyanide

P096                            Hydrogen phosphide

P137                            Hydroquinone*

P060                            Isodrin

P138                            Isonicotinic acid hydrazide*

P007                            3(2H)‑Isoxazolone, 5‑(aminomethyl)‑

P140                            Leptophos*

P092                            Mercury, (acetato‑0)phenyl‑

P065                            Mercury fulminate (R,T)

P082                            Methanamine, N‑methyl‑N‑nitroso‑

P064                            Methane, isocyanato‑

P016                            Methane, oxybis[chloro‑

P112                            Methane, tetranitro‑ (R)

P118                            Methanethiol, trichloro‑

P050                            6,9‑Methano‑2,4,3‑benzodioxathiepin, 6,7,8,9,10,10‑ hexachloro‑ 1,5,5a,6,9,9a‑hexahydro‑, 3‑oxide

P059                            4,7‑Methano‑1H‑indene, 1,4,5,6,7,8,8‑heptachloro‑ 3a,4,7,7a‑tetrahydro‑

P066                            Methomyl

P068                            Methyl hydrazine

P064                            Methyl isocyanate

P069                            2‑Methyllactonitrile

P071                            Methyl parathion

P131                            Mevinphos*

P128                            Mexacarbate*

P147                            Monocrotophos*

P158                            Mustard gas

P072                            alpha‑Naphthylthiourea

P073                            Nickel carbonyl

P073                            Nichol carbonyl Ni(CO)4 (T‑4)‑

P074                            Nichol cyanide

P074                            Nickel cynaide Ni(CN)2

P075                            Nicotine, & salts

P076                            Nitric oxide

P077                            p‑Nitroaniline

P078                            Nitrogen dioxide

P132                            Nitrogen mustard*

P076                            Nitrogen oxide NO

P078                            Nitrogen oxide NO2

P081                            Nitroglycerine (R)(T*)

P082                            N‑Nitrosodimethylamine

P084                            N‑Nitrosomethylvinylamine

P085                            Octamethylpyrophosphoramide

P087                            Osmium oxide OsO4 (T‑4)‑

P087                            Osmium tetroxide

P088                            7‑Oxabicyclo[2.2.1]heptane‑2,3‑dicarboxylic acid

P157                            Oxydemeton‑Methyl*

P126                            Paraquat*

P089                            Parathion

P034                            Phenol,2‑cyclohexyl‑4,6‑dinitro‑

P048                            Phenol, 2,4‑dinitro‑

P047                            Phenol, 2‑methyl‑4,6‑dinitro‑, & salts

P020                            Phenol, 2‑(1‑methylpropyl)‑4,6‑dinitro‑

P009                            Phenol, 2,4,6‑trinitro‑, ammonium salt (R)

P092                            Phenylmercury acetate

P093                            Phenylthiourea

P135                            Phenytoin*

P136                            Phenytoin sodium*

P152                            Phosmet*

P094                            Phorate

P142                            Phosacetim*

P095                            Phosgene

P145                            Phosphamidon

P096                            Phosphine

P139                            Phosphonic acid, (2,2,2‑thrichloro‑1, hydroxyethyl)‑, dimethyl ester*

P140                            Phosphonothioic acid, phenyl‑0‑(4‑bromo‑2,5‑dichlorophenyl) 0‑methyl ester*

P141                            Phosphorothioic acid, phenyl‑,0‑ethyl 0‑(p‑nitrophenyl) ester*

P142                            Phosphoramidiothioic acid, acetimidoyl‑,0,0‑bis(p‑chlorophenyl) ester*

P143                            Phosphoric acid, 2‑chloro‑1‑(2,4‑dichlorophenyl) vinyl diethyl ester*

P144                            Phosphoric acid, 2,2‑dichlorovinyl dimethyl ester*

P041                            Phosphoric acid, diethyl 4‑nitrophenyl ester

P145                            Phosphoric acid, dimethyl ester, ester with 2‑chloro‑N,N‑diethyl‑3‑hydroxycrotonamide*

P146                            Phosphoric acid, dimethyl ester, ester with (E)‑3‑hydroxy‑N,N‑dimethylcrotonamide*

P147                            Phosphoric acid, dimethyl ester, ester with (E)‑3‑hydroxy‑N, methyl‑crotonamide*

P148                            Phosphorodithioic acid, S‑(((p‑chlorophenyl)thio)‑methyl) 0,0‑diethyl ester*

P039                            Phosphorodithioic acid, 0,0‑diethyl S‑[2‑(ethylthio)ethyl] ester

P094                            Phosphorodithioic acid, 0,0‑diethyl S‑[ethylthio)methyl]ester

P149                            Phosphorodithioic acid, 0,0‑diethyl‑S‑(((1,1‑dimethylethyl)thio) methyl)ester*

P154                            Phosphorodithioic acid, S,S'‑methylene 0,0,0',0'‑tetraethyl ester**

P150                            Phosphorodithioic acid, 0,0‑diethyl ester, S‑ester with 3‑(mercaptomethyl)‑1,2,3‑benzotriazin‑4(3H)‑one*

P151                            Phosphorodithioic acid, 0,0‑dimethyl ester, S‑ester with 3‑(mercaptomethyl)‑1,2,3‑benzotriazin‑4(3H)‑one*

P152                            Phosphorodithioic acid, 0,0‑dimethyl ester, S‑ester with N‑(mercaptomethyl) phthalimide*

P153                            Phosphorodithioic acid, S,S'‑p‑dioxane‑2,3‑diyl 0,0,0',0'‑tetra‑ethyl ester*

P155                            Phosphorothioic acid, 0,0‑diethyl 0‑(2‑(ethylthio)ethyl) ester, mixed with 0‑0‑diethyl S‑(2‑(ethylthio)ethyl) ester 7:3)*

P156                            Phosphorothioic acid, 0,0‑diethyl 0‑(p‑methyl sulfinyl)phenyl) ester*

P044                            Phosphorodithioic acid, 0,0‑dimethyl S‑[2‑methylamino)‑2‑oxoethyl] ester

P043                            Phosphorofluoridic acid, bis(1‑methylethyl) ester

P089                            Phosphorothioic acid, 0,0‑diethyl 0‑(4‑nitrophenyl) ester (T*)

P040                            Phosphorothioic acid, 0,0‑diethyl 0‑pyrazinyl ester

P157                            Phosphorothioic acid, S‑(2‑(ethyl‑sulfinyl)ethyl)0,0‑dimethyl ester*

P097                            Phosphorothioic acid, 0‑[4‑[(dimethylamino)sulfonyl]phenyl] 0,0‑dimethyl ester

P071                            Phosphorothioic acid, 0,0,‑dimethyl 0‑(4‑nitrophenyl) ester

P110                            Plumbane, tetraethyl‑

P098                            Potassium cyanide

P098                            Potassium cyanide K(CN)

P099                            Potassium silver cyanide

P070                            Propanal, 2‑methyl‑2‑(methylthio)‑,0‑[(methylamino)carbonyl]oxime

P101                            Propanenitrile

P027                            Propanenitrile, 3‑chloro‑

P069                            Propanenitrile, 2‑hydroxy‑2‑methyl‑

P081                            1,2,3‑Propanetriol, trinitrate (R) (T*)

P017                            2‑Propanone, 1‑bromo‑(T*)

P102                            Propargyl alcohol

P003                            2‑Propenal

P005                            2‑Propen‑1‑0l

P067                            1,2‑Propylenimine

P102                            2‑Propyn‑1‑0l

P008                            4‑Pyridinamine

P075                            Pyridine, 3‑(1‑methyl‑2‑pyrrolidinyl)‑,(S)‑, & salts (T*)

P114                            Selenious acid, dithallium(1+) salt

P103                            Selenourea

P104                            Silver cyanide

P104                            Silver cyanide Ag(Cn)

P105                            Sodium azide

P106                            Sodium cyanide

P106                            Sodium cyanide Na(CN)

P107                            Strontium sulfide (T*)

P107                            Strontium sulfide SrS

P108                            Strychnidin‑10‑one, & salts (T*)

P018                            Strychnidin‑10‑one, 2,3‑dimethoxy‑

P108                            Strychnine, & salts (T*)

P158                            Sulfide, bis (2‑chloro‑ethyl)‑*

P115                            Sulfuric acid, dithallium (1+) salt

P149                            Terbufos*

P109                            Tetraethyldithiopyrophosphate

P110                            Tetraethyl lead

P111                            Tetraethyl pyrophosphate

P112                            Tetranitromethane (R)

P062                            Tetraphosphoric acid, hexaethyl ester

P113                            Thallic oxide

P113                            Thallium oxide Tl203

P114                            Thallium(l) selenite

P115                            Thallium(l) sulfate

P109                            Thiodiphosphoric acid, tetraethyl ester

P045                            Thiofanox

P049                            Thioimidodicarbonic diamide [(H2N)C(S)]2NH

P014                            Thiophenol

P116                            Thiosemicarbazide

P026                            Thiourea, (2‑chlorophenyl)‑

P072                            Thiourea, 1‑naphthalenyl‑

P093                            Thiourea, phenyl‑

P123                            Toxaphene

P139                            Trichlorfon

P118                            Trichloromethanethiol

P119                            Vanadic acid, ammonium salt

P120                            Vanadium oxide V205

P120                            Vanadium pentoxide

P084                            Vinylamine, N‑methyl‑N‑nitroso‑

P001                            Warfarin, & salts, when present at concentrations greater than 0.3%

P121                            Zinc cyanide

P121                            Zinc cyanide Zn(CN)2

P122                            Zinc phosphide Zn3P2, when present at concentrations greater than 10% (R,T)

*49 FR 49792, December 21, 1984, Proposed Rule.

 

(f)  The commercial chemical products, manufacturing chemical intermediates, or off‑specification commercial chemical products referred to in paragraphs (a) through (d) of this section, are identified as toxic wastes (T) unless otherwise designated and are subject to the small quantity exclusion defined in Section 4(A)(5)(a) and 4(A)(5)(b).

 

NOTE: For the convenience of the regulated community, the primary hazardous properties of these materials have been indicated by the letters T (Toxicity), R (Reactivity), I (Ignitability) and C (Corrosivity). Absence of a letter indicates that the compound is only listed for toxicity.

 

      These wastes and their corresponding EPA Hazardous Waste Numbers are:

 

Hazardous

Waste

Number                       Substance

 

U001                           Acetaldehyde (I)

U034                           Acetaldehyde, trichloro‑

U187                           Acetamide, N‑(4‑ethoxyphenyl)‑

U005                           Acetamide, N‑9H‑fluoren‑2‑yl‑

U240                           Acetic acid, (2,4‑dichlorophenoxy)‑,salts & esters

U112                           Acetic acid ethyl ester (I)

U144                           Acetic acid, lead(2+)salt

U214                           Acetic acid, thallium (1+) salt

see F027                      Acetic acid, (2,4,5‑trichlorophenoxyl)‑

U002                           Acetone (I)

U003                           Acetonitrile (I,T)

U004                           Acetophenone

U005                           2‑Acetylaminofluorene

U006                           Acetyl chloride (C,R,T)

U007                           Acrylamide

U008                           Acrylic acid (I)

U009                           Acrylonitrile

U011                           Amitrole

U012                           Aniline (I,T)

U136                           Arsinic acid, dimethyl‑

U014                           Auramine


U015                           Azaserine

U010                           Azirino[2',3':3,4]pyrrolo[1,2‑a] indole‑4,7‑dione, 6‑amino‑8‑[[(aminocarbonyl) oxy]methyl]‑l,la,2,8,8a,8b- hexahydro‑8a‑methoxy‑5‑methyl‑,[1aS‑(1aalpha, 8beta,8aalpha,8balpha)]‑

U157                           Benz[j]aceanthrylene, l,2‑dihydro‑3‑methyl‑

U016                           Benz[c]acridine

U017                           Benzal chloride

U192                           Benzamide, 3,5‑dichloro‑N‑(1,1‑dimethyl‑2‑ propynyl)-

U018                           Benz[a]anthracene

U094                           Benz[a]amthracene, 7,12‑dimethyl‑

U012                           Benzenamine (I,T)

U014                           Benzenamine, 4,4'-carbonimidoylbis[N,N-dimethyl

U049                           Benzenamine, 4‑chloro‑2‑methyl‑, hydrochloride

U093                           Benzenamine, N,N‑dimethyl‑4‑(phenylazo)‑

U328                           Benzenamine, 2‑methyl‑

U353                           Benzenamine, 4‑methyl‑

U158                           Benzenamine, 4,4'‑methylenebis[2‑chloro‑

U222                           Benzenamine, 2‑methyl‑,hydrochloride

U181                           Benzenamine, 2‑methyl‑5‑nitro‑

U019                           Benzene (I,T)

U038                           Benzeneacetic acid, 4‑chloro‑alpha‑(4‑chlorophenyl)‑alpha‑hydroxy‑, ethyl ester

U030                           Benzene, 1‑bromo‑4‑phenoxy‑

U035                           Benzenebutanoic acid, 4‑[bis(2‑chloroethyl)amino]‑

U037                           Benzene, chloro‑

U221                           Benzenediamine, ar‑methyl‑

U028                           1,2‑Benzenedicarboxylic acid, bis(2‑ethylhexyl) ester

U069                           1,2‑Benzenedicarboxylic acid, dibutyl ester

U088                           1,2‑Benzenedicarboxylic acid, diethyl ester

U102                           1,2‑Benzenedicarboxylic acid, dimethyl ester

U107                           1,2‑Benzenedicarboxylic acid, dioctyl ester

U070                           Benzene, 1,2‑dichloro‑

U071                           Benzene, 1,3‑dichloro‑

U072                           Benzene, 1,4‑dichloro‑

U060                           Benzene, 1,1'‑(2,2‑dichloroethylidene)bis[4‑chloro

U017                           Benzene, (dichloromethyl)‑

U223                           Benzene, 1,3,‑diisocyanatomethyl‑(R,T)

U239                           Benzene, dimethyl‑(I,T)

U201                           1,3‑Benzenediol

U127                           Benzene, hexachloro‑

U056                           Benzene, hexahydro‑(I)

U220                           Benzene, methyl‑

U105                           Benzene, 1‑methyl‑2,4‑dinitro‑

U106                           Benzene, 2‑methyl‑1,3‑dinitro‑

U055                           Benzene, (l‑methylethyl)‑(I)

U169                           Benzene, nitro‑

U183                           Benzene, pentachloro‑

U185                           Benzene, pentachloronitro‑

U020                           Benzenesulfonic acid chloride (C,R)

U020                           Benzenesulfonyl chloride (C,R)

U207                           Benzene, l,2,4,5‑tetrachloro‑

U061                           Benzene,1,1'‑(2,2,2‑    trichloroethylidene)bis[4‑chloro

U247                           Benzene, 1,1'‑(2,2,2‑trichloroethylidene)bis[4‑methoxy‑

U023                           Benzene, (trichloromethyl)‑

U234                           Benzene, l,3,5‑trinitro‑

U021                           Benzidine

U202                           l,2‑Benzisothiazol‑3(2H)‑one, l,l‑dioxide, & salts

U203                           1,3‑Benzodioxole, 5‑(2‑propenyl)‑

U141                           1,3‑Benzodioxole, 5‑(1‑propenyl)‑

U090                           1,3‑Benzodioxole, 5‑(1‑propyl‑

U084                           Benzo[rst]pentaphene

U248                           2H‑1‑Benzopyran‑2‑one, 4‑hydroxy‑3‑(3‑oxo‑1‑       phenyl‑butyl)‑, & salts, when present at concentrations of 0.3% or less

U022                           Benzo(a)pyrene

U197                           p‑Benzoquinone

U023                           Benzotrichloride (C,R,T)

U085                           2,2'‑Bioxirane

U021                           (l,l'‑Biphenyl)‑4,4'‑diamine

U073                           (l,l'‑Biphenyl)‑4,4'‑diamine, 3,3'‑dichloro‑

U091                           (l,l'‑Biphenyl)‑4,4'‑diamine, 3,3'‑dimethoxy‑

U095                           (l,l'‑Biphenyl)‑4,4'‑ diamine, 3,3'‑dimethyl‑

U354                           Bromacil*

U354                           5‑Bromo‑3‑sec‑butyl‑6‑methyluracil*

U225                           Bromoform

U030                           4‑Bromophenyl phenyl ether

U128                           l,3‑Butadiene, 1,1,2,3,4, 4‑hexachloro‑

U172                           l‑Butanamine, N‑butyl‑N‑nitroso‑

U031                           1‑Butanol (I)

U150                           2‑Butanone (I,T)

U160                           2‑Butanone, peroxide (R,T)

U053                           2‑Butenal

U074                           2‑Butene, l,4‑dichloro‑ (I,T)

U143                           2‑Butenoic acid, 2‑methyl‑, 7‑[[2,3‑dihydroxy‑2‑(1‑methoxyethyl)‑3‑methyl‑1‑oxobutoxy][methyl]‑2,3,5,7a‑tetrahydro‑1H-pyrrolizin‑1‑yl ester,[1S‑[1 alpha(Z),7(2S*,3R*),7aalpha]]‑

U031                           n‑Butyl alcohol (I)

U136                           Cacodylic acid

U032                           Calcium chromate

U238                           Carbamic acid, ethyl ester

U178                           Carbamic acid, methylnitroso‑, ethyl ester

U097                           Carbamic chloride, dimethyl‑

U114                           Carbamodithioic acid, 1,2‑ethanediylbis‑, salts & esters

U062                           Carbamothioic acid, bis(1‑methylethyl)‑, S‑(2,3‑dichloro‑2‑propenyl) ester

U215                           Carbonic acid, dithallium (1+) salt

U033                           Carbonic difluoride

U156                           Carbonochloridic acid, methyl ester (I,T)

U033                           Carbon oxyfluoride (R,T)

U211                           Carbon tetrachloride

U034                           Chloral

U035                           Chlorambucil

U036                           Chlordane, alpha & gamma isomers

U026                           Chlornaphazin

U037                           Chlorobenzene

U038                           Chlorobenzilate

U039                           p‑Chloro‑m‑cresol

U042                           2‑Chloroethyl vinyl ether

U044                           Chloroform

U046                           Chloromethyl methyl ether

U047                           beta‑Chloronaphthalene

U048                           o‑Chlorophenol

U049                           4‑Chloro‑o‑toluidine, hydrochloride

U032                           Chromic acid H2CrO4, calcium salt

U050                           Chrysene

U051                           Creosote

U052                           Cresol(Cresylic acid)

U053                           Crotonaldehyde

U055                           Cumene (I)

U246                           Cyanogen bromide (CN)Br

U197                           2,5‑Cyclohexadiene‑1,4‑dione

U056                           Cyclohexane (I)

U129                           Cyclohexane, 1,2,3,4,5,6‑hexachloro‑,(1alpha,2alpha,3beta,4alpha,5alpha,6beta)‑

U057                           Cyclohexanone (I)

U130                           1,3‑Cyclopentadiene, 1,2,3,4,5,5‑hexachloro‑

U058                           Cyclophosphamide

U240                           2,4‑D, salts & esters

U059                           Daunomycin

U060                           DDD

U061                           DDT

U062                           Diallate

U063                           Dibenz[a,h]anthracene

U064                           Dibenzo[a,i]pyrene

U066                           1,2‑Dibromo‑3‑chloropropane

U069                           Dibutyl phthalate

U070                           o‑Dichlorobenzene

U071                           m‑Dichlorobenzene

U072                           p‑Dichlorobenzene

U073                           3,3'‑Dichlorobenzidine

U074                           l,4‑Dichloro‑2‑butene (I,T)

U075                           Dichlorodifluoromethane

U078                           l,l‑Dichloroethylene

U079                           l,2‑Dichloroethylene

U025                           Dichloroethyl ether

U027                           Dichloroisopropyl ether

U024                           Dichloromethoxy ethane

U081                           2,4‑Dichlorophenol

U082                           2,6‑Dichlorophenol

U355                           N'(3,4‑dichlorophenyl)‑N‑methoxy‑N‑methylurea*

U084                           1,3‑Dichloropropene

U085                           1,2:3,4‑Diepoxybutane (I,T)

U108                           1,4‑Diethyleneoxide (alternative name for 1,4-Diethylene dioxide)

U028                           Diethylhexyl phthalate

U086                           N,N‑Diethylhydrazine

 

U087                           O,O‑Diethyl‑S‑methyl‑ dithiophosphate

U088                           Diethyl phthalate

U089                           Diethylstilbesterol

U090                           Dihydrosafrole

U091                           3,3'‑Dimethoxybenzidine

U092                           Dimethylamine (I)

U093                           p‑Dimethylaminoazobenzene

U094                           7,12‑Dimethylbenz[a]anthracene

U095                           3,3'‑Dimethylbenzidine

U096                           alpha,alpha‑Dimethylbenzylhydroperoxide (R)

U097                           Dimethylcarbamoyl chloride

U098                           1,1‑Dimethylhydrazine

U099                           1,2‑Dimethylhydrazine

U101                           2,4‑Dimethylphenol

U102                           Dimethyl phthalate

U103                           Dimethyl sulfate

U105                           2,4‑Dinitrotoluene

U106                           2,6‑Dinitrotoluene

U107                           Di‑n‑octyl phthalate

U108                           1,4‑Dioxane

U109                           1,2‑Diphenylhydrazine

U110                           Dipropylamine (I)

U111                           Di‑N‑propylnitrosamine

U041                           Epichlorohydrin

U001                           Ethanal (I)

U174                           Ethanamine, N‑ethyl‑N‑nitroso‑

U155                           1,2‑Ethanediamine, N,N‑dimethyl‑N'‑2‑pyridinyl‑N'‑(2‑thienyl methyl)

U067                           Ethane, 1,2‑dibromo‑

U076                           Ethane, 1,1‑dichloro‑

U077                           Ethane, 1,2‑dichloro‑

U131                           Ethane, hexachloro‑

U024                           Ethane, 1,1'‑[methylenebis(oxy)]bis [2‑chloro‑

U117                           Ethane, 1,1'‑oxybis‑(I)

U025                           Ethane, 1,1'‑oxybis[2‑chloro‑]

U184                           Ethane, pentachloro‑

U208                           Ethane, 1,1,1,2‑tetrachloro‑

U209                           Ethane, 1,1,2,2‑tetrachloro‑

U218                           Ethanethioamide

U226                           Ethane, 1,1,1‑trichloro‑

U227                           Ethane, 1,1,2‑trichloro‑

U359                           Ethanol, 2‑ethoxy‑

U173                           Ethanol, 2,2'‑(nitrosoimino)bis‑

U004                           Ethanone, 1‑phenyl‑

U043                           Ethene, chloro‑

U042                           Ethene, 2‑chloroethoxy‑

U078                           Ethene, 1,1‑dichloro‑

U079                           Ethene, 1,2‑dichloro‑, (E)‑

U210                           Ethene, tetrachloro‑

U228                           Ethene, trichloro‑

U112                           Ethyl acetate (I)

U113                           Ethyl acrylate (I)

U238                           Ethyl carbamate (urethane)

U117                           Ethyl ether (I)

U114                           Ethylenebisdithiocarbamic acid, salts & esters

U067                           Ethylene dibromide

U077                           Ethylene dichloride

U359                           Ethylene glycol monoethyl ether

U115                           Ethylene oxide (I,T)

U116                           Ethylenethiourea

U076                           Ethylidene dichloride

U118                           Ethyl methacrylate

U119                           Ethyl methanesulfonate

U139                           Ferric dextran

U120                           Fluoranthene

U122                           Formaldehyde

U123                           Formic acid (C,T)

U124                           Furan (I)

U125                           2‑Furancarboxaldehyde (I)

U147                           2,5‑Furandione

U213                           Furan, tetrahydro‑(I)

U125                           Furfural (I)

U124                           Furfuran (I)

U206                           Glucopyranose, 2‑deoxy‑2- (3‑methyl‑3‑nitrosoureido)‑, D‑

U206                           D‑Glucose, 2‑deoxy‑2‑[[methylnitrosoamino)‑carbonyl]amino]-

U126                           Glycidylaldehyde

U163                           Guanidine, N‑methyl‑N'‑nitro‑N‑nitroso-

U127                           Hexachlorobenzene

U128                           Hexachlorobutadiene

U130                           Hexachlorocyclopentadiene

U131                           Hexachloroethane

U132                           Hexachlorophene

U243                           Hexachloropropene

U133                           Hydrazine (R,T)

U086                           Hydrazine, 1,2‑diethyl‑

U098                           Hydrazine, 1,1‑dimethyl‑

U099                           Hydrazine, 1,2‑dimethyl‑

U109                           Hydrazine, 1,2‑diphenyl‑

U134                           Hydrofluoric acid (C,T)

U134                           Hydrogen fluoride (C,T)

U135                           Hydrogen sulfide

U135                           Hydrogen sulfide H2S

U096                           Hydroperoxide, 1‑methyl‑ 1‑phenylethyl‑ (R)

U136                           Hydroxydimethylarsine oxide

U116                           2‑Imidazolidinethione

U137                           Ideno[1,2,3‑cd]pyrene

U139                           Iron dextran

U190                           1,3‑Isobenzofurandione

U140                           Isobutyl alcohol (I,T)

U141                           Isosafrole

U142                           Kepone

U143                           Lasiocarpine

U144                           Lead acetate

U146                           Lead,bis(acetato‑O)tetrahydroxy-tri‑

U145                           Lead phosphate

U146                           Lead subacetate

U129                           Lindane

U355                           Linuron*

U163                           MNNG

U147                           Maleic anhydride

U148                           Maleic hydrazide

U149                           Malononitrile

U150                           Melphalan

U151                           Mercury

U152                           Methacrylonitrile (I,T)

U092                           Methanamine, N‑methyl‑ (I)

U029                           Methane, bromo‑

U045                           Methane, chloro‑ (I, T)

U046                           Methane, chloromethoxy‑

U068                           Methane, dibromo‑

U080                           Methane, dichloro‑

U075                           Methane, dichlorodifluoro‑

U138                           Methane, iodo‑

U119                           Methanesulfonic acid, ethyl ester

U211                           Methane, tetrachloro‑

U153                           Methanethiol (I,T)

U225                           Methane, tribromo‑

U044                           Methane, trichloro‑

U121                           Methane, trichlorofluoro‑

U036                           4,7‑Methano‑1H‑indene,1,2,4,5,6,7,8,8‑octach‑loro‑2,3,3a,4,7,7a‑hexahydro‑

U154                           Methanol (I)

U155                           Methapyrilene

U142                           1,3,4‑Metheno‑2H‑cyclobuta[cd]pentalen‑2‑one,1a,3,3a,4,5,5,5a,5b,6-decachloro-octahydro‑

U247                           Methoxychlor

U154                           Methyl alcohol (I)

U029                           Methyl bromide

U186                           1‑Methylbutadiene (I)

U045                           Methyl chloride (I,T)

U156                           Methyl chlorocarbonate (I,T)

U226                           Methyl chloroform

U157                           3‑Methylcholanthrene

U158                           4,4'‑Methylenebis(2‑chloroaniline)

U068                           Methylene bromide

U080                           Methylene chloride

U159                           Methyl ethyl ketone (MEK)(I,T)

U160                           Methyl ethyl ketone peroxide (R T)

U138                           Methyl iodide

U161                           Methyl isobutyl ketone (I)

U162                           Methyl methacrylate (I,T)

U161                           4‑Methyl‑2‑pentanone (I)

U164                           Methylthiouracil

U010                           Mitomycin C

U059                           5,12‑Naphthacenedione, 8‑acetyl‑10‑[(3- amino‑2,3,6‑trideoxy)‑alpha‑L‑lyxo‑hexopyranosyl)oxy]‑7,8,9,10‑tetrahydro-6,8,11-tri- hydroxy-1-methoxy-, (8S-cis)-

U167                           1‑Naphthylamine

U168                           2‑Naphthylamine

U026                           Naphthylamine, N,N'‑bis(2‑chloroethyl)‑

U165                           Naphthalene

U047                           Naphthalene, 2‑chloro‑

U166                           l,4‑Naphthalenedione

U236                           2,7‑Naphthalenedisulfonic acid, 3,3'‑[3,3'‑dimethyl [1,1'‑biphenyl]‑4,4'‑diyl)] bis(azo)bis[5‑amino‑4‑ hydroxy]-,tetrasodium salt

U166                           1,4‑Naphthoquinone

U167                           alpha‑Naphthylamine

U168                           beta‑Naphthylamine

U217                           Nitric acid, thallium(1+) salt

U169                           Nitrobenzene (I,T)

U170                           p‑Nitrophenol

U171                           2‑Nitropropane (I,T)

U172                           N‑Nitrosodi‑n‑butylamine

U173                           N‑Nitrosodiethanolamine

U174                           N‑Nitrosodiethylamine

U176                           N‑Nitroso‑N‑ethylurea

U177                           N‑Nitroso‑N‑methylurea

U178                           N‑Nitroso‑N‑methylurethane

U179                           N‑Nitrosopiperidine

U180                           N‑Nitrosopyrrolidine

U181                           5‑Nitro‑o‑toluidine

U193                           1,2‑Oxathiolane, 2,2‑dioxide

U058                           2H,‑l,3,2‑Oxazaphosphorin‑ 2‑amine, N,N‑bis(2‑chloroethyl)tetrahydro‑,2‑oxide

U115                           Oxirane (I,T)

U126                           Oxiranecarboxyaldehyde

U041                           Oxirane, (chloromethyl)‑

U182                           Paraldehyde

U183                           Pentachlorobenzene

U184                           Pentachloroethane

U185                           Pentachloronitrobenzene(PCNB)

See

 F027, Pentachlorophenol

U161                           Pentanol,4‑methyl‑

U186                           1,3‑Pentadiene (I)

U187                           Phenacetin

U188                           Phenol

U048                           Phenol, 2‑chloro‑

U039                           Phenol, 4‑chloro‑3‑methyl‑

U081                           Phenol, 2,4‑dichloro‑

U082                           Phenol, 2,6‑dichloro‑

U089                           Phenol, 4,4'‑(1,2‑diethyl‑1,2‑ethenediyl)bis‑,(E)‑

U101                           Phenol, 2,4‑dimethyl‑


U052                           Phenol, methyl‑

U132                           Phenol, 2,2'‑methylenebis[3,4,6‑trichloro

U170                           Phenol, 4‑nitro‑

See

 FO27                          Phenol, pentachloro‑

See

 FO27                          Phenol, 2,3,4,6‑tetrachloro‑

See

 FO27                          Phenol, 2,4,5‑trichloro‑

See

 FO27                          Phenol, 2,4,6‑trichloro‑

U150                           L‑Phenylalanine, 4‑bis(2‑chloroethyl)amino]‑

U145                           Phosphoric acid, lead (2+) salt(2:3)

U087                           Phosphorodithioic acid, 0,0‑diethyl S‑methyl ester

U189                           Phosphorous sulfide (R)

U190                           Phthalic anhydride

U191                           2‑Picoline

U179                           Piperidine, 1‑nitroso‑

U192                           Pronamide

U194                           1‑Propanamine (I,T)

U111                           1‑Propanamine, N‑nitroso‑N‑propyl-

U110                           1‑Propanamine, N‑propyl‑ (I)

U066                           Propane, l,2‑dibromo‑3‑chloro‑

U083                           Propane, 1,2‑dichloro‑

U149                           Propanedinitrile

U171                           Propane, 2‑nitro‑ (I,T)

U027                           Propane, 2,2'oxybis[2‑chloro‑

U193                           l,3‑Propane sultone

See

 FO27                          Propanoic acid, 2‑(2,4,5‑trichlorophenoxy)‑

U235                           l‑Propanol, 2,3‑dibromo‑, phosphate (3:l)

U140                           1‑Propanol, 2‑methyl‑ (I,T)

U002                           2‑Propanone (I)

U007                           2‑Propenamide

U084                           1‑Propene, 1,3‑dichloro‑

U243                           1‑Propene, 1,1,2,3,3,3‑hexachloro‑

U009                           2‑Propenenitrile

U152                           2‑Propenenitrile, 2‑methyl‑ (I,T)

U008                           2‑Propenoic acid (I)

U113                           2‑Propenoic acid, ethyl ester (I)

U118                           2‑Propenoic acid, 2‑methyl‑, ethyl ester

U162                           2‑Propenoic acid, 2‑methyl‑,methyl ester (I,T)

U194                           n‑Propylamine (I,T)

U083                           Propylene dichloride

U148                           3,6‑Pyridazinedione, 1,2‑dihydro‑

U196                           Pyridine

U191                           Pyridine, 2‑methyl‑

U237                           2,4‑(1H,3H)‑Pyrimidinedione, 5‑[bis(2‑chloro‑ethyl)amino]‑

U164                           4(lH)‑Pyrimidinone, 2,3‑di hydro‑6‑methyl‑2‑thioxo‑

U180                           Pyrrolidine, 1‑nitroso‑

U200                           Reserpine

U201                           Resorcinol

U202                           Saccharin, and salts

U203                           Safrole

U204                           Selenious acid

U204                           Selenium dioxide

U205                           Selenium sulfide

U205                           Selenium sulfide SeS2 (R,T)

U015                           L‑Serine, diazoacetate (ester)

See

 FO27                          Silvex (2,4,5‑TP)

U206                           Streptozotocin

U103                           Sulfuric acid, dimethyl ester

U189                           Sulfur phosphide (R)

See

 FO27                          2,4,5‑T

U207                           l,2,4,5‑Tetrachlorobenzene

U208                           l,l,l,2‑Tetrachloroethane

U209                           1,1,2,2‑Tetrachloroethane

U210                           Tetrachloroethylene

See

 FO27                          2,3,4,6‑Tetrachlorophenol

U213                           Tetrahydrofuran (I)

U214                           Thallium acetate

U215                           Thallium carbonate

U216                           Thallium chloride

U216                           Thallium chloride TlCl

U217                           Thallium nitrate

U218                           Thioacetamide

U153                           Thiomethanol (I,T)

U244                           Thioperoxydicarbonic diamide [(H2N)C(S)]2S2,tetramethyl‑

U219                           Thiourea

U244                           Thiram

U220                           Toluene

U221                           Toluenediamine

U223                           Toluene diisocyanate (R,T)

U328                           o‑Toluidine

U353                           p‑Toluidine

U222                           o‑Toluidine hydrochloride

U011                           1H‑l,2,4‑Triazol‑3‑amine

U227                           l,l,2‑Trichloroethane

U228                           Trichloroethylene

U121                           Trichloromonofluoromethane

See

 F027                           2,4,5‑ Trichlorophenol

See

 F027                           2,4,6‑ Trichlorophenol

U234                           1,3,5‑Trinitrobenzene (R,T)

U182                           l,3,5‑Trioxane, 2,4,6‑Trimethyl‑

U235                           Tris(2,3‑dibromopropyl) phosphate

U236                           Trypan blue

U237                           Uracil mustard

U176                           Urea, N‑ethyl‑N‑nitroso‑

U177                           Urea, N‑methyl‑N‑nitroso‑

U043                           Vinyl chloride

U248                           Warfarin, & salts, when present at concentrations of 0.3% or less

U239                           Xylene (I)

U200                           Yohimban‑16‑carboxylic acid, 11,17‑dimethoxy‑18[(3,4,5‑trimethoxybenzoyl)oxy]- methyl ester(3beta,16beta,17alpha,18beta,20alpha)‑

U249                           Zinc phosphide Zn3P2, when present at concentrations of 10% or less

 

* 50 FR 18626, May 1, 1985 Proposed Rule

 

NOTE: all amendments to reference F027: 50 FR 2000, Jan. 14, 1985, Final Rule.

 

D.  Criteria for designation of hazardous waste as universal waste.

 

      In determining whether a waste may be designated a universal waste, the Maine Board of Environmental Protection must determine that:

 

(1)  the waste or category of the waste meets the definition of a hazardous waste;

 

(2)  the waste or category of the waste is a manufactured product that is not easily contaminated with other substances:

 

(3)  the waste or a category of the waste is not exclusive to a specific industry or group of industries, is commonly generated by a wide variety of types of establishments (including, for example, households, retail and commercial businesses, office complexes, small businesses, government organizations, as well as large industrial facilities);

 

(4)  the waste or category of waste is generated by a large number of generators (e.g., more than 1,000 nationally) and is frequently generated in relatively small quantities by each generator;

 

(5)  systems to be used for collecting the waste or category of waste including packaging, marking, labeling, storage, and tracking would ensure close stewardship of the waste;

 

(6)  the risk posed by the waste or category of waste during accumulation and transport is relatively low compared to other hazardous wastes, and specific management standards developed for the waste type would be protective of human health and the environment during accumulation and transport;

 

(7)  regulation of the waste or category of waste under the designation of universal waste will increase the likelihood that the waste will be diverted from non hazardous waste management systems to recycling, or where appropriate treatment or disposal, in compliance with the full hazardous waste regulations;

 

(8)  regulation of the waste or category of waste under the designation of universal waste will improve implementation of and compliance with the hazardous waste regulatory program; and

 

(9)  such other factors as may be appropriate.


 

APPENDIX I:

REPRESENTATIVE SAMPLING METHODS

 

(Appendix I of this rule corresponds to Appendix I of 40 CFR 261)

 

The methods and equipment used for sampling waste materials will vary with the form and consistency of the waste materials to be sampled. Samples collected using the sampling protocols listed below, for sampling waste with properties similar to the indicated materials, will be considered by the Agency [EPA] to be representative of the waste.

 

Extremely viscous liquid‑‑ASTM Standard D140‑70 Crushed or powdered material‑‑ASTM Standard D346‑75 Soil or rock‑like material‑‑ASTM Standard D420‑69 Soil‑like material‑‑ASTM Standard D1452‑65

 

Fly Ash‑like material‑‑ASTM Standard D2234‑76 [ASTM Standards are available from ASTM, 1916 Race St., Philadelphia, PA 19103]

 

Containerized liquid wastes‑‑"COLIWASA" described in "Test Methods for the Evaluation of Solid Waste, Physical/Chemical Methods,"1 U.S. Environmental Protection Agency, Office of Solid Waste, Washington, DC 20460. [Copies may be obtained from NTIS as specified in Appendix III.]

 

Liquid waste in pits, ponds, lagoons, and similar reservoirs.‑‑"Pond Sampler" described in "Test Methods for the Evaluation of Solid Waste, Physical/Chemical Methods."1

 

This manual also contains additional information on application of these protocols.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

1These methods are also described in "Samplers and Sampling Procedures for Hazardous Waste Streams," EPA 600/2‑80‑018, January, 1980.


 

 

APPENDIX II:

 

METHOD 1311

TOXICITY CHARACTERISTIC LEACHING PROCEDURE (TCLP)

 

See 40 CFR 261. Appendix II (July 1, 2003 Version) for specific procedure.

 

 

 

 

APPENDIX III: CHEMICAL ANALYSIS TEST METHODS

 

(Appendix III of this rule corresponds to Appendix III of 40 CFR 261.)

 

Tables 1, 2 and 3 specify the appropriate analytical procedures, described in "Test Methods for Evaluating Solid Waste, Physical/Chemical Methods"1, which shall be used in determining whether a sample contains a given Appendix VII or VIII toxic constituent. Table 1 identifies each Appendix VII or VIII organic constituent along with the approved measurement method. Table 2 identifies the corresponding methods for the inorganic species. Table 3 summarizes the contents of SW‑846 and supplies specific section and method numbers for sampling and analysis methods.

 

Prior to final sampling and analysis method selection, the analyst should consult the specific section or method described in SW‑846 for additional guidance on which of the approved methods should be employed for a specific sample analysis situation.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

1Copies of the Third Edition, and Updates I, II, and III may be obtained from the National Technical Information Service (NTIS), 5285 Port Royal Road, Springfield, VA 22161, (703)487‑4600, as document number PB‑87‑120‑291. The cost is $48.95 for paper and $13.50 for microfiche or is available at http://www.epa.gov/epaoswer/hazwaste/test/main.htm.


 

TABLE 1: ANALYSIS METHODS FOR ORGANIC CHEMICALS CONTAINED IN SW-846

 

 

Compounds                                                                                 Method                 Numbers+

 

Acetonitrile                                                                                   8030,                     8240

Acrolein                                                                                        8030,                     8240

Acrylamide                                                                                   8015,                     8240

Acrylonitrile                                                                                  8030,                     8240

2‑Amino‑l‑methylbenzene (o‑Toluidine)                                      8250

4‑Amino‑l‑methylbenzene (p‑Toluidine)                                      8250

Aniline                                                                                          8250

Benzene                                                                                        8020,                     8024

Benz(a)anthracene                                                                        8100,                     8250, 8310

Benzo(a)pyrene                                                                             8100,                     8250, 8310

Benzotrichloride                                                                           8120,                     8250

Benzyl chloride                                                                             8120,                     8250

Benzo(b)fluoanthene                                                                    8100,                     8250, 8310

Bis(2‑chloroethoxymethane)                                                         8010,                     8240

Bis(2‑chloroethyl)ether                                                                 8010,                     8240

Bis(2‑chloroisopropyl)ether                                                          8010,                     8240

Bromacil***                                                                                  8080,                     8250, 8270

Carbon disulfide                                                                           8015,                     8240

Carbon tetrachloride                                                                     8010,                     8240

Chlordane                                                                                     8080,                     8250

Chlorinated biphenyls                                                                   8080,                     8250

Chlorinated dibenzo‑p‑dioxins                                                     8280

Chlorinated dibenzofurans                                                           8280

Chloroacetaldehyde                                                                      8010,                     8240

Chlorobenzene                                                                              8020                      8240

Chloroform                                                                                   8010,                     8240

Chloromethane                                                                              8010,                     8240

2‑Chlorophenol                                                                             8040,                     8250

Chrysene                                                                                       8100,                     8250, 8310

Creosote1                                                                                      8100,                     8250

Cresol(s)                                                                                        8040,                     8250

Cresylic Acid(s)                                                                            8040,                     8250

Dichlorobenzene(s)                                                                       8010,                     8120,

Dichloroethane(s)                                                                          8010,                     8240

2,4‑Dimethylphenol                                                                      8040,                     8250

Dichloromethane                                                                           8010,                     8240

Dichlorophenoxyacetic acid                                                         8150,                     8250

Dichloropropanol                                                                          8120,                     8250, 8250

Dimethyl sulfate                                                                           8250                      8270

Dinitrobenzene                                                                              8090,                     8250

4,6‑Dinitro‑o‑cresol                                                                       8040,                     8250

2,4‑Dinitrotoluene                                                                         8090,                     8250

2,6‑Dinitrotoluene                                                                         8060,                     8250

Endrin                                                                                           8080,                     8250

2‑Ethoxyethanol                                                                           8030,                     8240

Ethylene dibromide                                                                      8010,                     8240

Ethylene thiourea                                                                          8250                      8330

Ethyl ether                                                                                    8015,                     8240

Formaldehyde                                                                               8015,                     8240

Formic acid                                                                                   8250

Heptachlor                                                                                    8080,                     8250

Hexachlorobenzene                                                                       8120,                     8250

Hexachlorobutadiene                                                                    8120,                     8250

Hexachloroethane                                                                         8010,                     8240

Hexachlorocyclopentadiene                                                          8120,                     8250

Lindane                                                                                         8080,                     8250

Linuron**                                                                                     8080,                     8250, 8270

Maleic anhydride                                                                          8250

Methanol                                                                                       8010,                     8240

Methomyl                                                                                      8250

Methyl bromide                                                                            8010                      8240, 8260

Methyl ethyl ketone                                                                      8240

Methyl isobutyl ketone                                                                 8015,                     8240

Napthalene                                                                                    8015,                     8240

Napthoquinone                                                                             8290,                     8250

Nitrobenzene                                                                                 8090,                     8250

4‑Nitrophenol                                                                                8040,                     8240

2‑Nitropropane                                                                              8030,                     8240

Paraldehyde (trimer of acetaldehyde)                                          8015,                     8240

Pentachlorophenol                                                                        8040,                     8250

Phenol                                                                                           8040,                     8250

Phorate                                                                                          8140

Phosphorodithioic acid esters                                                       8140

Phthalic anhydride                                                                        8090,                     8250

2‑Picoline                                                                                      8090,                     8250

Pyridine                                                                                         8090,                     8250

3,3',4,4'‑Tetrachloroazobenzene (TCAB)**                                 8080,                     8250, 8270

3,3',4,4'‑Tetrachloroazoxybenzene (TCAOB)**                          8080,                     8250, 8270

Tetrachlorobenzene(s)                                                                   8120,                     8250

Tetrachloroethane(s)                                                                     8010,                     8240

Tetrachloroethene                                                                         8010,                     8240

Tetrachlorophenol                                                                         8040,                     8250

Toluene                                                                                         8020,                     8024

Toluenediamine                                                                             8250

2,4‑Toluenediamine                                                                      8250

2,6‑Toluenediamine                                                                      8250

3,4‑Toluenediamine                                                                      8250

Toluene diisocyanate(s)                                                                8250

Toxaphene                                                                                     8080,                     8250

Trichloroethane                                                                             8010,                     8240

Trichloroethene(s)                                                                         8010,                     8240

Trichlorofluoromethane                                                                8010,                     8240

Trichlorophenol(s)                                                                         8040,                     8250

2,4,5‑Trichlorophenoxy propionic acid                                         8150,                     8250

Trichloropropane                                                                           8010,                     8240

Vinyl chloride                                                                               8010,                     8240

Vinylidene chloride                                                                      8010,                     8240

Xylene                                                                                           8020,                     8240

 

 

 

***50 FR 18626

 

1Analyze for phenanthrene and carbazole; if these are present in a ratio between 1.4:1 and 5:1 creosote should be considered present.

 

**50 FR 18626, 5/1/85, Proposed Rule

 


TABLE 2:   ANALYSIS METHODS FOR INORGANIC CHEMICALS AND MISCELLANEOUS GROUPS OF ANALYTES CONTAINED IN SW‑846*

 

 

Title                                                           Third Edition                        Second Edition

Compound                                                  Method(s)                               Method(s)

 

 

Aluminum                                                       6010

Antimony                                                        6010                                        7040,7041

Arsenic                                                            6010                                        7060,7061

Barium                                                            6010                                        7080,7081

Beryllium                                                        6010,7090,7091

Boron                                                              6010

Cadmium                                                        6010                                        7130,7131

Calcium                                                           6010

Chromium                                                       6010                                        7190,7191

Chromium, Hexavalent                                   7198                                        7195,7196,7197

Cobalt                                                             6010

Copper                                                            6010,7210,7211

Iron                                                                 6010,7380,7381

Lead                                                                6010                                        7420,7421

Magnesium                                                      6010

Manganese                                                      6010,7460,7461

Mercury                                                                                                           7470,7471

Molybdenum                                                   6010

Nickel                                                              6010                                        7520,7521

Osmium                                                           7550

Potassium                                                        6010

Selenium                                                         6010                                        7740,7741

Silicon                                                             6010

Silver                                                               6010                                        7760,7761

Sodium                                                            6010,7770

Thallium                                                          6010,7840,7841

Vanadium                                                       6010,7910,7911

Zinc                                                                 6010,7950,7951

Cyanides                                                                                                         9010

Total Organic Halides                                     9022                                        9020

Sulfides                                                                                                           9030

Sulfates                                                           9035,9036,9038

Total Organic Carbon                                     9060

Phenolics                                                         9065,9066**,9067

Oil and Grease                                                9070,9071

Total Coliform                                                9131,9132

Nitrate                                                             9200


Chlorides                                                         9250,9251,9252

Gross Alpha and Gross Beta                          9310

Alpha‑Emitting Radium Isotopes                   9315

Radium‑228                                                    9320

 

 

*The Third Edition and its Updates will supercede the Second Edition and its Updates 1 and II when it is adopted. Until the Third Edition is adopted, in a final rule, the Second Edition and its updates must be used for regulatory purposes. Therefore, reference to the Third Edition, in these tables, is provided for convenience. The Third Edition of SW‑846 and Update 1 are available from the Government Printing Office, Superintendent of Documents, Washington, D.C. 20402, (202) 738‑3238.

 

**When Method 9066 is used it must be preceded by the manual distillation specified in procedure 7.1 of Method 9065. Just prior to distillation in Method 9065, adjust the sulfuric acid‑preserved sample to pH 4 with 1+9 NaOH. After the manual distillation is completed, the autoanalyzer manifold is simplified by connecting the re‑sample line directly to the sampler.


Table 3:    SAMPLING AND ANALYSIS METHODS CONTAINED IN SW‑8461

 

 

        Title                                                  Third Edition                              Second Edition

                                                         Section No.    Method No.          Section No.    Method No.

 

 

Quality Control                                       1.0                                              10.0

   Introduction                                         1.1                                              10.1

   Quality Control                                    1.2

   Method Detection Limit                      1.3

   Data Reporting                                     1.4

   Quality Control Documentation           1.5

   References                                            1.6

Choosing the Correct Procedure             2.0

   Purpose                                                 2.1

   Required Information                           2.2

   Implementing the Guidance                 2.3

   Characteristics                                      2.4

   Ground Water                                      2.5

   References                                            2.6

Metallic Analytes                                    3.0

   Sampling Considerations                      3.1

   Sample Preparation Methods               3.2

      Acid Digestion of Waters for Total  3.2                  3005

      Recoverable or Dissolved Metals for

      Analysis by Flame AAS or ICP.

      Acid Digestion of Aqueous Samples                       3.2                        3010                4.1            3010

      Samples and Extracts for Total Metals

      for Analysis by Flame AAS or ICP.

      Acid Digestion of Aqueous Samples                       3.2                        3020                4.1            3020

      and Extracts for Total Metals for

      Analysis by Furnace AAS.

      Dissolution Procedure for Oils,         3.2                  3040                     4.1                   3040

      Greases, or Waxes.

      Acid Digestion of Sediments,           3.2                  3050                     4.1                   3050

      Sludges and Soils.

   Methods for the Determination of Metals                  3.3

      Inductively Coupled Plasma Atomic                       3.3                        *6010

      Emissions Spectroscopy

      Atomic Absorption Methods            3.3                  7000

      Aluminum, Flame AAS                     3.3                  7020

      Antimony, Flame AAS                     3.3                  7040                     7.0                   7040

      Antimony, Furnace AAS                  3.3                  7041                     7.0                   7041

      Arsenic, Furnace AAS                      3.3                  7060                     7.0                   7060

      Arsenic, Gaseous Hydride AAS       3.3                  7061                     7.0                   7061

      Barium, Flame AAS                          3.3                  7080                     7.0                   7080

      Barium, Furnace AAS                       3.3                  7081                     7.0                   7881

      Beryllium, Flame AAS                      3.3                  *7090

      Beryllium, Furnace AAS                   3.3                  *7091

      Cadmium, Flame AAS                      3.3                  7130                     7.0                   7130

      Cadmium, Furnace AAS                   3.3                  7131                     7.0                   7131

      Calcium, Flame AAS                        3.3                  7140

      Chromium, Flame AAS                     3.3                  7190                     7.0                   7190

      Chromium, Furnace AAS                  3.3                  7191                     7.0                   7191

      Chromium, Hexavalent, Coprecip.    3.3                  7195                     7.0                   7195

      Chromium, Hexavalent, Colorimetric    3.3             7196                     7.0                   7196

      Chromium, Hexavalent, Chelation/   3.3                  7197                     7.0                   7197

       Extraction

      Chromium, Hexavalent, Differential 3.3                  *7198

       Pulse Polarography

      Cobalt, Flame AAS                           3.3                  7200

      Cobalt, Furnace AAS                        3.3                  7201

      Copper, Flame AAS                          3.3                  *7210

      Copper, Furnace AAS                       3.3                  *7211

      Iron, Flame AAS                               3.3                  *7380

      Iron, Furnace AAS                            3.3                  *7381

      Lead, Flame AAS                             3.3                  7420                     7.0                   7470

      Lead, Furnace AAS                          3.3                  7421                     5.0                   7421

      Magnesium, Flame AAS                   3.3                  7450

      Manganese, Flame AAS                    3.3                  *7460

      Manganese, Furnace AAS                 3.3                  *7461

      Mercury in Liquid Waste, Manual    3.3                  7470                     7.0                   7470

       Cold Vapor Technique

      Mercury in Solid or Semisolid Waste,   3.3             7471                     7.0                   7471

       Manual Cold Vapor Technique

      Molybdenum, Flame AAS                3.3                  7480

      Molybdenum, Furnace AAS             3.3                  7481

      Nickel, Flame AAS                           3.3                  7520                     7.0                   7520

      Osmium, Flame AAS                        3.3                  *7550

      Potassium, Flame AAS                     3.3                  7610

      Selenium, Furnace AAS                    3.3                  7740                     7.0                   7740

      Selenium, Gaseous Hydride AAS     3.3                  7741                     7.0                   7741

      Silver, Flame AAS                            3.3                  7760                     7.0                   7760

      Silver, Furnace AAS                         3.3                  7761                     7.0                   7761

      Sodium, Flame AAS                         3.3                  *7770

      Thallium, Flame AAS                        3.3                  *7840

      Thallium, Furnace AAS                     3.3                  *7841

      Tin, Flame AAS                                3.3                  7870

      Vanadium, Flame AAS                     3.3                  *7910

      Vanadium, Furnace AAS                  3.3                  *7911

      Zinc, Flame AAS                              3.3                  *7950

      Zinc, Furnace AAS                           3.3                  *7951

Organic Analytes                                     4.0                                              8.0

   Sampling Considerations                      4.1

   Sample Preparation Methods               4.2

   Extractions and Preparations                4.2.1

   Organic Extraction and Sample           4.2.1               3500

    Preparation

   Separatory Funnel Liquid‑Liquid         4.2.1               3510                     4.2                   3510

    Extraction

   Continuous Liquid‑Liquid Extraction  4.2.1               3520                     4.2                   3520

   Soxhlet Extraction                                4.2.1               3540                     4.2                   3540

   Ultrasonic Extraction                           4.2.1               3550                     4.2                   3550

   Waste Dilution                                     4.2.1               3580

   Purge‑and‑Trap                                     4.2.1               5030                     5.0                   5030

   Protocol for Analysis of Sorbent          4.2.1               *5040

    Cartridges from VOST

   Cleanup                                                4.2.2

      Cleanup                                             4.2.2               3600

   Alumina Column Cleanup                    4.2.2               3610

      Alumina Column Cleanup and          4.2.2               *3611

      Separation of Petroleum Wastes

         Florisil Column Cleanup                 4.2.2               3620

         Silica Gel Cleanup                          4.2.2               3630

         Gel‑Permeation Cleanup                4.2.2               3640

         Acid‑Base Partition Cleanup          4.2.2               3650                     4.2                   3530

         Sulfur Cleanup                               4.2.2               3660

   Determination of Organic Analytes     4.3

      Gas Chromatographic Methods        4.3.1                                           8.1

         Gas Chromatography                     4.3.1               8000

         Halogenated Volatile Organics      4.3.1               8010                     8.1                   8010

         EDB and DBCP                             4.3.1               8011

         Nonhalogenated Volatile Organics                       4.3.1                     8015                8.1            8015

         Aromatic Volatile Organics            4.3.1               8020                     8.1                   8020

         Volatile Organic Compounds in     4.3.1               8021

          Water by Purge‑and‑Trap Capillary

          Column GC with PID and Electrolytic

          Conductivity Detector in Series

         Acrolein, Acrylonitrile, Acetonitrile   4.3.1          8030                     8.1                   8030

         Phenols                                           4.3.1               8040                     8.1                   8040

         Phthalate Esters                              4.3.1               8060                     8.1                   8060

         Nitrosamines                                   4.3.1               8070

         Organochlorine Pesticides and PCBs 4.3.1          8080                     8.1                   8080

          as Aroclors

         Nitroaromatics and Cyclic Ketones    4.3.1          8090                     8.1                   8090

         Polynuclear Aromatic Hydrocarbons  4.3.1          8100                     8.1                   8100

         Haloethers                                      4.3.1               8110

         Chlorinated Hydrocarbons             4.3.1               8120                     8.1                   8120

         Organophosphorus Pesticides        4.3.1               8140                     8.1                   8140

         Organophosphorus Pesticides:       4.3.1               8141

          Capillary Column

         Chlorinated Herbicides                  4.3.1               8150                     8.1                   8150

      Gas Chromatographic/Mass              4.3.2                                           8.2

      Spectroscopic Methods

      GC/MS Volatiles                               4.3.2               8240                     8.2                   8240

      GC/MS Semivolatiles, Packed Column                   4.3.2                     8250                8.2            8250

      GC/MS for Volatiles Capillary Column                  4.3.2                     8260

      GC/MS Semivolatiles, Capillary Col.    4.3.2          8270                     8.2                   8270

      Analysis of Chlorinated Dioxins and                      4.3.2                     8280

       Dibenzofurans

      High Performance Liquid                  4.3.3                                           8.3

       Chromatographic Methods (HPLC)

      Polynuclear Aromatic Hydrocarbons     4.3.3          8310                     8.3                   8310

   Miscellaneous Screening Methods       4.4

      Headspace                                         4.4                  3810                     5.0                   5020

      Hexadecane Extraction and Screening                    4.4                        3820

       of Purgeable Organics

Miscellaneous Test Methods                   5.0                                              9.0

   Total and Amenable Cyanide               5.0                  9010                     9.0                   9010

    (Colorimetric, Manual)

   Total and Amenable Cyanide               5.0                  9012

    (Colorimetric, Automated)

   Total Organic Halides (TOX)               5.0                  9020                     9.0                   9020

   Purgeable Organic Halides (POX)       5.0                  9021

   Total Organic Halides (TOX) by Neutron                  5.0                        *9022

    Activation Analysis

   Acid‑Soluble and Acid‑Insoluble        5.0                  9030                     9.0                   9030

    Sulfides

   Extractable Sulfides                             5.0                  9031

   Sulfate, (Colorimetric, Automated,      5.0                  *9035

    Chloranilate)

   Sulfate, (Colorimetric, Automated,      5.0                  *9036

    Methylthymol Blue, AA II)

   Sulfate, (Turbidimetric)                        5.0                  *9038

   Total Organic Carbon                           5.0                  *9060

   Phenolics, (Spectrophotometric,           5.0                  *9065

    Manual 4‑AAP)

   Phenolics, (Colorimetric, Automated   5.0                  *+9066

    4‑AAP

   Phenolics, (Spectrophotometric, MBTH)    5.0          *9067

   Total Recoverable Oil and Grease        5.0                  *9070

    (Gravimetric, Separatory Funnel Extraction)

   Oil and Grease Extraction Method for                       5.0                        *9071

    Sludge Samples

   Total Coliform: Multiple Tube             5.0                  *9131

    Fermentation

   Total Coliform: Membrane Filter         5.0                  *9132

   Nitrate                                                  5.0                  *9200

   Chloride (Colorimetric, Automated     5.0                  *9250

    Ferricyanide AAI)

   Chloride (Colorimetric, Automated     5.0                  *9251

    Ferricyanide AAII)

   Chloride (Titrimetric, Mercuric Nitrate)      5.0          *9252

Properties                                                 6.0

   Multiple Extraction Procedure             6.0                  *1320

   Extraction Procedure for Oily Wastes 6.0                  *1330

   pH Electrometric Measurement            6.0                  9040                     9.0                   9040

   pH Paper Method                                 6.0                  9041

   Soil pH                                                 6.0                  9045

   Specific Conductance                          6.0                  9050

   Cation‑Exchange Capacity of Soils     6.0                  *9080

    (Ammonium Acetate)

   Cation‑Exchange Capacity of Soils     6.0                  *9081

    (Sodium Acetate)

   Compatibility Test for Wastes and       6.0                  9090

    Membrane Liners

   Paint Filter Liquids Test                       6.0                  9095                     9.0                   9095

   Saturated Hydraulic Conductivity,      6.0                  *9100

    Saturated Leachate Conductivity, and

    Intrinsic Permeability

   Gross Alpha and Gross Beta                6.0                  *9310

   Alpha‑Emitting Radium Isotopes        6.0                  *9315

   Radium 228                                          6.0                  *9320

Introduction and Regulatory Definitions                      7.0                                                2.0

   Ignitability                                            7.1                                              2.1.1

   Corrosivity                                            7.2                                              2.1.2

   Reactivity                                             7.3                                              2.1.3

Test Method to Determine Hydrogen     7.3

    Cyanide Released from Wastes

Test Method to Determine Hydrogen     7.3

    Sulfide Released from Wastes

   Extraction Procedure Toxicity             7.4                                              2.1.4

Methods for Determining Characteristics       8.0                                       2.0

   Ignitability                                            8.1                                              2.1.1

      Pensky‑Martens Closed‑Cup Method   8.1             1010                     2.1.1                1010

      Setaflash Closed‑Cup Method          8.1                  1020                     2.1.1                1020

   Corrosivity                                            8.2                                              2.1.2

      Corrosivity Toward Steel                  8.2                  1110                     2.1.2                1110

   Reactivity                                             8.3                                              2.1.3

   Toxicity                                                8.4                                              2.1.4

      Extraction Procdure (EP) Toxicity Test    8.4          1310                     2.1.4                1310

       Method and Structural Integrity Test

Sampling Plan                                          9.0                                              1.0

      Design and Development                  9.1                                              1.0, 1.1

      Implementation                                 9.2                                              1.2, 1.3, 1.4

Sampling Methods                                  10.0

      Modified Method 5 Sampling Train,                       10.0                      *0010

       Appendix A and B

      Source Assessment Sampling System                      10.0                      *0020

       (SASS)

      Volatile Organic Sampling Train       10.0                *0030

Ground Water Monitoring                      11.0

   Background and Objectives                 11.1

   Relationship to the Regulations           11.2

    and to Other Documents

   Revisions and Additions                      11.3

   Acceptable Designs and Practices        11.4

   Unacceptable Designs and Practices    11.5

Land Treatment Monitoring                    12.0

   Background                                          12.1

   Treatment Zone                                    12.2

   Regulatory Definition                          12.3

   Monitoring and Sampling Strategy      12.4

   Analysis                                                12.5

   References and Bibilography               12.6

Incineration                                             13.0

   Introduction                                         13.1

   Regulatory Definition                          13.2

   Waste Characterization Strategy          13.3

   Stack‑Gas Effluent Characterization   13.4

    Strategy

   Additional Effluent Characterization  13.5

    Strategy

   Selection of Specific Sampling and     13.6

    Analysis Methods

   References                                            13.7

 

 

1The Third Edition and its Updates will supersede the Second Edition and its Updates I and II when it is adopted. Until the Third Edition is adopted, in a final rule, the Second Edition and its updates must be used for regulatory purposes. Therefore, reference to the Third Edition, in these tables, is provided for convenience. The Third Edition of SW‑846 and Update I are available from the Government Printing Office, Superintendent of Documents, Washington, DC 20402, (202)738‑3238, document number 955‑001‑00000‑1.

 

*This method may be used in conjunction with or in addition to the methods found in the Second Edition of SW‑846 as amended by Updates I and II.

 

+When Method 9066 is used it must be preceded by the manual distillation specified in procedure 7.1 of Method 9065. Just prior to distillation in Method 9065, adjust the sulfuric acid‑preserved sample to pH 4 with 1+9 NaOH. After the manual distillation is completed, the autoanalyzer manifold is simplified by connecting the re‑sample line directly to the sampler.


 

APPENDIX IV: RESERVED

 

 

APPENDIX V: RESERVED

 

 

APPENDIX VI: RESERVED

 

 

APPENDIX VII: BASIS FOR LISTING HAZARDOUS WASTES

 

 

Hazardous

Waste                          Hazardous constituents

Number                       for which listed

 

 

F001                            Tetrachloroethylene, methylene chloride, trichloroethylene, 1,1,1‑trichloroethane, carbon tetrachloride, chlorinated fluorocarbons.

F002                            Tetrachloroethylene, methylene chloride, trichloroethylene, 1,1,1‑trichloroethane, 1,1,2‑trichloroethane, chloro‑ benzene, 1,1,2‑trichloro‑1,2, 2‑trifluoroethane, ortho‑dichloro‑benzene, trichlorofluoromethane.

F003                            N.A.

F004                            Cresols and cresylic acid, nitrobenzene.

F005                            Toluene, methyl ethyl ketone, carbon disulfide, isobutanol, pyridine, 2‑ethoxyethanol, benzene, 2‑nitropropane

F006                            Cadmium, hexavalent chromium, nickel, cyanide (complexed)

F007                            Cyanide (salts)

F008                            Cyanide (salts)

F009                            Cyanide (salts)

F010                            Cyanide (salts)

F011                            Cyanide (salts)

F012                            Cyanide (complexed)

F019                            Hexavalent chromium, cyanide (complexed)

F020                            Tetra‑ and pentachloro dibenzo‑p‑dioxins; tetra and pentachlorodibenzofurans; tri‑ and tetrachlorophenols and their chlorophenoxy derivative acids, esters, ethers, amine and other salts.

F021                            Penta‑ and hexachlorodibenzo‑p‑dioxins; penta- and hexachlorodibenzofurans; pentachlorophenol and its derivatives

F022                            Tetra‑, penta‑, and hexa‑ chlorodibenzo‑p‑dioxins; tetra‑, penta, and hexachlorodibenzofurans

F023                            Tetra‑, and pentachlorodibenzo‑p‑dioxins; tetra‑ and pentachlorodibenzofurans; tri‑ and tetrachlorophenols and their chlorophenoxy de-rivative acids, esters, ethers, amine and other salts.

F024                            Chloromethane, dichloro‑ methane, trichloromethane, carbon tetrachloride, chloroethylene, l,l‑di‑ chloroethane, l,2‑dichloro‑ ethane, trans‑l‑2‑dichloro‑ ethylene, l,l‑dichloro- ethylene, l,l,l‑trichloro‑ ethane, l,l,2‑trichloro‑ ethane, trichloroethylene, l,l,l,2‑tetrachloroethane, 1,1,2,2‑tetrachloroethane, tetrachloroethylene, pentachloroethane, hexachloroethane, allyl chloride (3‑chloropropene), dichloropropane, dichloropropene, 2‑chloro‑l,3‑butadiene, hexachloro‑l,3‑butadiene, hexachlorocyclopentadiene, hexachlorocyclohexane, benzene, chlorobenzene, dichlorobenzenes, 1,2,4‑trichlorobenzene, tetrachlorobenzene, pentachlorobenzene, hexachlorobenzene, toluene, naphthalene.

F025*                          Chloromethane, dichloromethane, trichloromethane, carbon tetrachloride, chloroethylene, l,l‑dichloroethane, l,2‑dichloroethane, trans‑l,2‑dichloroethylene, l,l‑dichloroethylene, l,l,l‑trichloroethane, 1,1,2‑trichloroethane, trichloroethylene, l,l,l,2‑tetrachloroethane, l,l,2,2‑tetrachloroethane, tetrachloroethylene, pentachloroethane, hexachloroethane, allyl chloride (3‑chloropropene), dichloropropane, dichloropropene, 2‑chloro‑l, 3‑butadiene, hexachloro‑l, 3‑butadiene, hexachloro- cyclopentadiene, hexachlorocyclohexane, benzene, chlorobenzene, dichlorobenzenes, 1,2,4‑trichlorobenzene, tetrachlorobenzene, pentachlorobenzene, hexachlorobenzene, toluene, naphthalene

 

*49 FR 5315, 2/10/84, Proposed Rule

 

F026                            Tetra‑, penta‑, and hexachlorodibenzo‑p‑dioxins; tetra‑, penta‑, and hexa‑ chlorodibenzofurans

F027                            Tetra‑, penta‑, and hexachlorodibenzo‑p‑dioxins; tetra‑, penta‑, and hexachlorodibenzofurans; tri‑, tetra‑, and pentachlorophenols and their chlorophenoxy derivative acids, esters, ethers, amine, and other salts

F028                            Tetra‑, penta‑, and hexachlorodibenzo‑p- dioxins; tetra‑, penta‑, and hexachlorodibenzofurans; tri‑, tetra‑ and pentachloro- phenols and their chlorophenoxy derivative acids, esters, ethers, amine, and other salts

K001                           Pentachlorophenol, phenol, 2‑chlorophenol, p‑chloro‑ m‑cresol, 2,4‑dimethyl‑ phenol, 2,4‑dinitrophenol, trichlorophenols, tetra- chlorophenols, 2,4‑dinitro‑ phenol, creosote, chrysene, naphthalene, fluoranthene, benzo(b)fluoranthene, benzo(a)pyrene, indeno (1,2,3‑cd)pyrene, benz(a) anthracene, dibenz(a) anthracene, acenaphthalene.

K002                           Hexavalent chromium, lead

K003                           Hexavalent chromium, lead

K004                           Hexavalent chromium

K005                           Hexavalent chromium, lead

K006                           Hexavalent chromium

K007                           Cyanide (complexed), hexavalent chromium

K008                           Hexavalent chromium

K009                           Chloroform, formaldehyde, methylene chloride, methyl chloride, paraldehyde, formic acid

K010                           Chloroform, formaldehyde, methylene chloride, methyl chloride, paraldehyde, formic acid, chloro‑ acetaldehyde

K011                           Acrylonitrile, acetonitrile, hydrocyanic acid

K013                           Hydrocyanic acid, acrylonitrile, acetonitrile

K014                           Acetonitrile, acrylamide

K015                           Benzyl chloride, chlorobenzene, toluene, benzotrichloride

K016                           Hexachlorobenzene, hexachlorobutadiene, carbon tetrachloride, hexachloro‑ ethane, perchloroethylene

K017                           Epichlorohydrin, chloro ethers [bis (chloromethyl) ether and bis (2‑chloroethyl) ethers], trichloropropane, dichloropropanols

K018                           l,2‑dichloroethane, tri‑ chloroethylene, hexachloro‑ butadiene, hexachlorobenzene

K019                           Ethylene dichloride, l,l,l‑ trichloroethane, l,l,2‑ trichloroethane, tetra‑ chloroethanes (l,l,2,2‑tetra‑ chloroethane and l,l,l,2‑tetrachloroethane), trichloroethylene, tetra‑ chloroethylene, carbon tetrachloride, chloroform, vinyl chloride, vinylidene chloride

K020                           Ethylene dichloride, l,l,l‑trichloroethane, l,l,2‑trichloroethane, tetra‑ chloroethanes (l,l,2,2‑tetra‑ chloroethane and l,l,l,2‑tetrachloroethane), trichloroethylene, tetrachloroethylene, carbon tetrachloride, chloroform, vinyl chloride, vinylidene chloride

K021                           Antimony, carbon tetrachloride, chloroform

K022                           Phenol, tars (polycyclic aromatic hydrocarbons)

K023                           Phthalic anhydride, maleic anhydride

K024                           Phthalic anhydride, l,4‑naphthoquinone

K025                           Meta‑dinitrobenzene, 2,4‑dinitrotoluene

K026                           Paraldehyde, pyridines, 2‑picoline

K027                           Toluene diisocyanate, toluene‑2,4‑diamine

K028                           l,l,l‑trichloroethane, vinyl chlorideK029         l,2‑dichloroethane, l,l,l‑trichloroethane, vinyl chloride, vinylidene chloride, chloroform

K030                           Hexachlorobenzene, hexachlorobutadiene, hexachloroethane, l,l,l,2‑ tetrachloroethane, l,l,2,2‑tetrachloroethane, ethylene dichloride

K031                           Arsenic

K032                           Hexachlorocyclopentadiene

K033                           Hexachlorocyclopentadiene

K034                           Hexachlorocyclopentadiene

K035                           Creosote, chrysene, naphthalene, fluoranthene benzo(b)fluoranthene, benzo(a)pyrene, indeno (l,2,3‑cd) pyrene, benzo (a)anthracene, dibenzo(a) anthracene, acenaphthalene

K036                           Toluene, phosphorodithioic and phosphorothioic acid esters

K037                           Toluene, phosphorodithioic and phosphorothioic acid esters

K038                           Phorate, formaldehyde, phosphorodithioic and phosphorothioic acid esters

K039                           Phosphorodithioic and phosphorothioic acid esters

K040                           Phorate, formaldehyde, phosphorodithioic and phosphorothioic acid esters

K041                           Toxaphene

K042                           Hexachlorobenzene, ortho‑ dichlorobenzene

K043                           2,4‑dichlorophenol, 2,6‑dichlorophenol, 2,4,6‑trichlorophenol

K044                           N.A.

K045                           N.A.

K046                           Lead

K047                           N.A.

K048                           Hexavalent chromium, lead

K049                           Hexavalent chromium, lead

K050                           Hexavalent chromium

K051                           Hexavalent chromium, lead

K052                           Lead

K060                           Cyanide, napthalene, phenolic compounds, arsenic

K061                           Hexavalent chromium, lead, cadmium

K062                           Hexavalent chromium, lead

K064                           Lead, Cadmium

K065                           Lead, Cadmium

K066                           Lead, Cadmium

K068                           Cyanide (Complexes)

K069                           Hexavalent chromium, lead, cadmium

K071                           Mercury

K073                           Chloroform, carbon tetra‑ chloride, hexachloroethane, trichloroethane, tetra- chloroethylene, dichloro‑ ethylene, 1,1,2,2‑tetra‑ chloroethane

K083                           Aniline, diphenylamine, nitrobenzene, phenylenediamine

K084                           Arsenic

K085                           Benzene, dichlorobenzenes, trichlorobenzenes, tetra‑ chlorobenzene, pentachloro‑ benzene, hexachlorobenzene, benzyl chloride

K086                           Lead, hexavalent chromium

K087                           Phenol, naphthalene

K088                           Cyanide (complexes)

K090                           Chromium

K091                           Chromium

K093                           Phthalic anhydride, maleic anhydride

K094                           Phthalic anhydride

K095                           1,1,2‑trichloroethane, 1,1,1,2‑tetrachloroethane, 1,1,2,2‑tetrachloroethane

K096                           1,2‑dichloroethane, 1,1,1‑trichloroethane, 1,1,2‑trichloroethane

K097                           Chlordane, heptachlor

K098                           Toxaphene

K099                           2,4‑dichlorophenol, 2,4,6‑trichlorophenol

K100                           Hexavalent chromium, lead, cadmium

K101                           Arsenic

K102                           Arsenic

Kl03                            Aniline, nitrobenzene, phenylenediamine

K104                           Aniline, benzene, diphenylamine, nitrobenzene, phenylenediamine

K105                           Benzene, monochlorobenzene, dichlorobenzenes, 2,4,6‑trichlorophenol

K106                           Mercury

K107*                         1,1‑Dimethylhydrazine (UDMH)

K108*                         1,1‑Dimethylhydrazine (UDMH)

K109*                         1,1‑Dimethylhydrazine (UDMH)

K110*                         1,1‑Dimethylhydrazine (UDMH)

K111                           2,4‑Dinitrotoluene,

K112                           2,4‑Toluenediamine, o‑toluidine, p‑toluidine, aniline

K113                           2,4‑Toluenediamine, o‑toluidine, p‑toluidine, aniline

K114                           2,4‑Toluenediamine, o‑toluidine, p‑toluidine

K115                           2,4‑Toluenediamine,

K116                           Carbon tetrachloride, tetrachloroethylene, chloroform, phosgene

K117                           Ethylene dibromide

K118                           Ethylene dibromide

K119**                       Chlorobenzene, linuron

K120**                       Chlorobenzene, bromacil

K121**                       Bromacil

K123                           Ethylene thiourea

K124                           Ethylene thiourea

K125                           Ethylene thiourea

K126                           Ethylene thiourea

K131                           Methyl bromide, dimethylsulfate

K132                           Methyl bromide

K136                           Ethylene dibromide

 

*49 FR 49559, 12/20/84, Proposed Rule

**50 FR 18626, 5/1/85, Proposed Rule


APPENDIX VIII:

HAZARDOUS CONSTITUENTS

 

Common name                                                      Chemical abstracts name

 

Acenaphthene,5‑nitro**

Acetamide, N‑(4‑(5‑nitro‑2‑furyl)‑2‑thiazolyl)‑**

Acetonitrile                                                           Same

Acetophenone                                                       Ethanone, 1‑phenyl‑

2‑Acetylaminofluorene                                         Acetamide, N‑9H‑fluoren‑2‑yl‑

Acetyl chloride                                                     Same

1‑Acetyl‑2‑thiourea                                               Acetamide, N‑(aminothioxomethyl)‑

Acrolein                                                                2‑Propenal

Acrylamide                                                           2‑Propenamide

Acrylonitrile                                                          2‑Propenenitrile

Actinomycin D**

Aflatoxins                                                             Same

Aldicarb                                                                Propanal, 2‑methyl‑2‑(methylthio)‑,0‑[(methylamino)carbonyl]oxime

Aldrin                                                                    1,4,5,8‑Dimethanona

                                                                              phthalene, 1,2,3,4,10,10‑10‑hexachloro‑1,4,4a,5,

                                                                              8,8a‑hexahydro‑(1alpha,4alpha,4abeta,

                                                                              5alpha,8alpha,8abeta)‑,

Allyl alcohol                                                          2‑Propen‑1‑ol

Aluminum phosphide                                            Same

3‑Amino‑9‑ethyl carbazole**

p-aminoazobenzene                                               4‑(phenylazo) benzenamine‑**)

o‑Aminoazotoluene                                               o‑Toluidine, 4‑(o‑tolylazo)‑**

4‑Aminobiphenyl                                                  [1,1'‑Biphenyl]‑4 amine

5‑(Aminomethyl)‑3‑isoxazolol                              3(2H)‑Isoxazolone, 5‑(aminomethyl)‑

4‑Aminopyridine                                                   4‑Pyridinamine

Amitrole                                                                1H‑1,2,4‑Triazol‑

                                                                              3‑amine

Ammonium vanadate                                            Vanadic acid, ammonium salt

Anilazine                                                               S‑Triazine, 2,4‑dichloro‑6

                                                                              (o‑chloroanilino)‑**

Aniline                                                                  Benzenamine

Aniline, 4‑4'‑methylenebis‑(N‑N‑dimethyl‑)‑**

Aniline, 4‑4'‑methylenebis‑(2‑methyl‑)‑**

Aniline, 4,4'‑thiodi‑

Aniline, 2,4,5‑trimethyl‑**

0‑Anisidine**

0‑Anisidine hydrochloride**

0‑Anisidine, 5‑methyl‑**

0‑Anisidine, 5‑nitro‑**

Anthraquinone, 2‑amino‑**

Anthraquinone, 1‑amino‑2‑methyl‑**

Anthraquinone, 2‑methyl‑1‑nitro‑**

Antimony                                                              Same

Antimony compounds,N.O.S.1

Aramite                                                                 Sulfurous acid, 2‑chloroethyl‑2‑ [4‑(1,1‑dimethylethyl)-phenoxy]‑1‑methylethyl ester

Arsenic                                                                  Same

Arsenic compounds, N.O.S.1

Arsenic acid                                                          Arsenic acid H3AsO4

Arsenic pentoxide                                                 Arsenic oxide As2O5

Arsenic trioxide                                                    Arsenic oxide As2O3

Asbestos**

Auramine                                                              Benzenamine, 4,4'‑carbonimidoylbis [N,N‑dimethyl]‑, monohydrochloride

Azinphos ethyl                                                      Phosphorodithioic acid, O,O‑diethyl ester, S‑ester with 3‑(mercaptomethyl) ‑1,2,3‑benzotriazin‑4(3H)‑one**

Azinphos methyl                                                   Phosphorodithioic acid, O,O‑dimethyl ester, S‑ester with 3‑(mercaptomethyl)-1,2,3‑benzotriazine‑4(3H)‑one**

Azaserine                                                              L‑Serine, diazoacetate (ester)

Barban                                                                   Carbanilic acid, m‑chloro, 4‑chloro‑2‑butynyl ester*

Barbituric acid, 5‑ethyl‑5 phenyl‑**                     2,4,6 (1H,3H, 5H) - pyrimidinetrione

Barium                                                                  Same

Barium compounds, N.O.S.1

Barium cyanide                                                     Same

Bendiocarb                                                            Carbamic acid, methyl‑2,3‑(dimethyl- methylenediox)phenyl ester

Benz[c]acridine                                                     Same

Benz[a]anthracene                                                Same

Benzal chloride                                                     Benzene, (dichloromethyl)‑

Benzene                                                                Same

Benzenamine hydrochloride**

Benzenearsonic acid                                             Arsonic acid, phenyl‑

Benzidine                                                              [1,1'‑Biphenyl]‑4,4'‑diamine

Benzidine sulfate**

Benzimidazolecarbamic acid, 1‑(butyl‑carbamoyl)‑methyl ester

Benzo[b]fluoranthene                                           Benz[e] [acephenanthrylene

Benzo[j]fluoranthene                                            Same

Benzo[a]pyrene                                                     Same

p‑Benzoquinone                                                    2,5‑Cyclohexadiene‑1,4‑dione

Benzotrichloride                                                   Benzene, (trichloromethyl)‑

Benzyl chloride                                                     Benzene, (chloromethyl)‑

Beryllium                                                              Same

Beryllium compounds,N.O.S.1

Biphenyl, 4‑nitro‑**

Bromoacetone                                                       2‑Propanone, 1‑bromo‑

Bromacil                                                                Uracil, 6-methyl-, 5‑bromo‑3‑sec‑butyl

Bromoform                                                           Methane, tribromo‑

4‑Bromophenyl phenyl ether                                Benzene, 1‑bromo‑4‑phenoxy‑

Bromoxynil                                                           Benzonitrile, 3,5‑dibromo‑4-hydroxy*

Brucine                                                                  Strychnidin‑10‑one, 2,3‑dimethoxy-

1,3'‑Butadiene, 2‑chloro‑**

1‑Butanol, 4‑(butylnitrosamino)‑**

Butyl benzyl phthalate                                          1,2‑Benzene dicarboxylic acid, butyl phenylmethyl ester

Cacodylic acid                                                      Arsinic acid, dimethyl‑

Cadmium                                                              Same

Cadmium compounds, N.O.S.1

Calcium chromate                                                 Chromic acid H2CrO4,calcium salt

Calcium cyanide                                                   Calcium cyanide Ca(CN)2

Captafol                                                                4‑Cyclohexene‑1,2‑dicarboximide, N‑(1,1,2,2‑tetrachloroethyl)thio‑**

Captan                                                                   4‑Cyclohexene‑1,2‑dicarboximide, N‑(trichloromethyl)thio‑

Carbaryl                                                                Carbamic acid, methyl-, 1‑naphthyl ester*

Carbofuran                                                            Carbamic acid, methyl, 2,3‑dihydro‑

                                                                              2,2‑dimethyl‑7‑benzofuranyl ester**

Carbon disulfide                                                   Same

Carbon oxyfluoride                                               Carbonic difluoride

Carbon tetrachloride                                             Methane, tetrachloro

Carbophenothion                                                  Phosphorodithioic acid S‑(((p‑chlorophenyl)thio)methyl) O,O‑diethyl ester**

Chloral                                                                  Acetaldehyde, trichloro‑

Chlorambucil                                                         Benzenebutanoic acid, 4‑[bis(2‑chloroethyl)amino]‑

Chlordane                                                             4,7‑Methano‑1      H‑indene, 1,2,4,5,6,7,8,8‑octachloro‑2,3,3a, 4,7,7a‑hexahydro‑.

Chlordane(alpha and gamma isomers)

Chlorfenvinphos                                                   Phosphoric acid, 2‑chloro‑1‑(2,4‑dichlorophenyl)vinyl diethyl ester**

Chlorinated benzenes, N.O.S.1

Chlorinated ethane, N.O.S.1

Chlorinated fluorocarbons, N.O.S.1

Chlorinated napthalene, N.O.S.1

Chlorinated phenol, N.O.S.1

Chlorine**

Chlornaphazin                                                       2‑Naphthalenamine, N,N'‑bis(2‑chloroethyl)‑

Chloroacetaldehyde                                              Acetaldehyde, chloro‑

Chloroalkyl ethers, N.O.S.1

p‑Chloroaniline                                                     Benzenamine, (4‑chloro‑

Chlorobenzene                                                      Benzene, chloro‑

Chlorobenzilate                                                     Benzeneacetic acid, 4‑chloro‑alpha‑(4‑chloro‑phenyl)‑alpha‑hydroxy‑, ethyl ester

p‑Chloro‑m‑cresol                                                 Phenol, 4‑chloro‑3‑methyl‑

Chloroethanol                                                       Ethanol, 2‑chloro‑**

2‑Chloroethyl vinyl ether                                      Ethene, (2‑chloroethoxy)‑

Chloroform                                                           Methane, trichloro‑

Chloromethyl methyl ether                                   Methane, chloromethoxy‑

beta‑Chloronaphthalene                                        Naphthalene, 2‑chloro‑

o‑Chlorophenol                                                     Phenol,2‑chloro‑

1‑(o‑Chlorophenyl)thiourea                                  Thiourea, (2‑chlorophenyl)‑

Chloroprene                                                          1,3‑Butadiene, 2‑chloro‑

3‑Chloropropionitrile                                            Propanenitrile, 3‑chloro‑

Chlorpyrifos                                                          Phosphorothioic acid, O,O‑diethyl O‑(3,5,6‑trichloro‑2‑pyridyl) ester**

Chromium                                                             Same

Chromium compounds, N.O.S.1

Chrysene                                                               Same

Citrus red No. 2                                                    2‑Naphthalenol, 1‑(2,5‑dimethoxyphenyl)azo]‑

Clonitralid                                                             Salicylanilide, 2',5‑dichloro‑4'‑nitro‑, compound with 2‑aminoethanol (l:l)**

Coal tar creosote                                                   Same

Cobalt, when in the form of particles

 100 microns or less**

Cobalt (II) chloride**

Copper cyanide                                                     Copper cyanide CuCN

Coumaphos                                                           Phosphorothioic acid, 0‑(3‑chloro‑4‑methyl‑2‑oxo‑2H‑1‑benzopyran‑7‑yl)0,0‑diethyl ester (Coumarin, 3‑chloro‑7‑hydroxy‑4‑methyl,‑0‑ester with 0,0‑diethyl phosphorothioate)

Coumarin,                                                             3‑chloro‑7‑hydroxy‑4‑methyl‑0‑ester with 0,0‑diethylphosphorothioate**

Creosote                                                                Same

Cresol (Cresylic acid)                                            Phenol, methyl‑

Crotoxyphos                                                         2‑Butenoic acid, 3‑((dimethoxyphos‑phinyl)oxy)‑, 1‑phenylethyl ester (Crotonic acid, 3‑hydroxy‑, alpha‑methylbenzyl ester, dimethyl phosphate (E)‑)

Crotonaldehyde                                                    2‑Butenal

Cyanides (soluble salts and complexes

 N.O.S1

Cyanogen                                                              Ethanedinitrile

Cyanogen bromide                                                Cyanogen bromide (CN)Br

Cyanogen chloride                                                Cyanogen chloride (CN)Cl

Cycasin                                                                 beta‑D‑Glucopyranoside, (methyl‑ONN‑azoxy)methyl

2‑Cyclohexyl‑4,6‑dinitrophenol                            Phenol, 2‑cyclohexyl‑4,6‑dinitro‑

Cyclophosphamide                                               2H‑1,3,2‑Oxazaphosphorin‑2‑amine, N,N‑bis(2‑chloroethyl)tetrahydro‑,2‑oxide

2,4‑D                                                                     Acetic acid, (2,4‑dichlorophenoxy)‑

2,4‑D, salts, esters

Daunomycin                                                          5,12‑Naphtha cenedione, 8‑acetyl‑10[(3‑amino‑2,3,6‑trideoxy-alpha‑L‑lyxo‑hexopyranosyl)oxy]‑7,8,9,10‑tetrahydro‑6,8,11‑trihydroxy‑1‑methyoxy‑, (8S‑cis)‑

DDD                                                                     Benzene, 1,1'‑(2,2‑dichloroethylidene)bis(4‑chloro‑,

DDE                                                                      Benzene, 1,1'‑(dichloroethenylidene)bis(4‑chloro‑

DDT                                                                      Benzene, 1,1'‑(2,2,2‑trichloro‑ethylidene)bis(4‑chloro‑

Demeton                                                               Phosphorothioic acid, O,O‑diethyl 0‑(2‑(ethylthio)ethyl) ester, mixed with O,O‑diethyl S‑(2‑(ethylthio)ethyl) ester (7:3)**

Diallate                                                                  Carbamothioic acid, bis(1‑methyl‑ethyl)‑, S‑(2,3‑dichloro‑2‑propenyl) ester

Diazinon                                                                Phosphorothioic acid, O,O‑diethyl O‑(2‑isopropyl‑6‑methyl‑4‑pyrimidinyl) ester**

Dibenz[a,h]acridine                                               Same

Dibenz[a,j]acridine                                                Same

Dibenz[a,h]anthracene                                          Same

7H‑Dibenzo[c,g]carbazole                                    Same

Dibenzo[a,e]pyrene                                               Naphtho[1,2,3,4‑def] chrysene

Dibenzo[a,h]pyrene                                               Dibenzo[b,def] chrysene

Dibenzo[a,i]pyrene                                                Benzo[rst] pentaphene

1,2‑Dibromo‑3‑chloropropane                              Propane, 1,2‑dibromo‑3‑chloro‑

Dibutyl phthalate                                                  1,2‑Benzenedi carboxylic acid, dibutyl ester

Dichlone                                                                1,4‑Naphthalene dione, 2,3‑ dichloro‑**

o‑Dichlorobenzene                                                Benzene, 1,2‑dichloro‑

m‑Dichlorobenzene                                               Benzene, 1,3,‑dichloro‑

p‑Dichlorobenzene                                                Benzene, 1,4‑dichloro‑

Dichlorobenzene, N.O.S.1                                    Benzene, dichloro‑

3,3'‑Dichlorobenzidine                                          [1,1'‑Biphenyl] ‑4,4'‑diamine, 3,3'‑dichloro‑

1,4‑Dichloro‑2‑butene                                           2‑Butene,1,4‑dichloro‑

Dichlorodifluoromethane                                      Methane, dichlorodifluoro‑

Dichloroethylene, N.O.S.1                                   Dichloroethylene

1,1‑Dichloroethylene                                            Ethene, 1,1‑dichloro‑

1,2‑Dichloroethylene                                            Ethene, 1,2‑dichloro‑, (E)‑

Dichloroethyl ether                                               Ethane, 1,1'oxybis[2‑chloro‑

Dichloroisopropyl ether                                        Propane, 2,2'‑oxybis[2‑chloro‑

Dichloromethoxy ethane                                       Ethane, 1,1'‑[methylenebis(oxy)] bis[2‑chloro‑

Dichloromethyl ether                                            Methane, oxybis[chloro‑

2,4‑Dichlorophenol                                               Phenol, 2,4‑dichloro‑

2,6‑Dichlorophenol                                               Phenol, 2,6‑dichloro‑

Dichlorophenylarsine                                            Arsonous dichloride, phenyl‑

Dichloropropane, N.O.S.1                                    Propane, dichloro‑

Dichloropropanol, N.O.S.1                                   Propanol, dichloro‑

Dichloropropene, N.O.S.1                                    Propene, dichloro‑

1,3‑Dichloropropene                                             Propene, 1,3‑dichloro‑

Dichlorvos                                                             Phosphoric acid, 2,2‑dichlorovinyl           dimethyl ester**

Dieldrin                                                                 2,7:3,6‑Dimethanona phth[2,3‑b]oxirene, 3,4,5,6,9,9‑hexachloro‑1a,2,2a,3,6,6a,7,7a‑octahydro‑,(1aalpha,2beta,2aalpha,3beta,6beta,6aalpha,7beta,7aalpha)‑

1,2:3,4‑Diepoxybutane                                         2,2'‑Bioxirane

Diethylarsine                                                         Arsine, diethyl‑

1,4‑Diethyleneoxide                                             1,4‑Dioxane

Diethylhexyl phthalate                                          1,2‑Benzenedi-carboxylic acid, bis(2‑ethylhexyl) ester

N,N'‑Diethylhydrazine                                         Hydrazine, 1,2‑diethyl‑

O,O‑Diethyl S‑methyl dithiophosphate                Phosphorodithioic acid, O,O‑diethyl S‑methyl ester

Diethyl‑p‑nitrophenyl phosphate                          Phosphoric acid, diethyl 4‑nitro‑phenyl ester

Diethyl phthalate                                                  1,2‑Benzenedi-carboxylic acid, diethyl ester

O,O‑Diethyl O‑pyrazinyl phosphorothioate         Phosphorothioc acid, O,O‑diethyl O‑       pyrazinyl ester

Diethylstilbesterol                                                 Phenol, 4,4'‑(1,2‑diethyl‑1,2‑ethenediyl) bis‑(E)

Diethyl sulfate                                                      Sulfuric acid, diethyl ester**

Dihydrosafrole                                                      1,3‑Benzodioxole, 5‑propyl‑

Diisopropylfluorophosphate (DFP)                      Phosphorofluoridic acid, bis(1‑methylethyl) ester

Dimethoate                                                           Phosphorodithioic acid, O,O‑dimethyl S[2‑(methylamino)‑2‑oxoethyl] ester

3,3'‑Dimethoxybenzidine                                      [1,1'‑Biphenyl]‑4,-4'‑diamine, 3,3'‑           dimethoxy-

p‑Dimethylaminoazobenzene                                Benzenamine, N,N‑dimethyl‑4‑(phenylazo)‑

7,12‑Dimethylbenz[a]anthracene                          Benz[a]anthracene,-7,12‑dimethyl‑

3,3'‑Dimethylbenzidine                                         [1,1'‑Biphenyl]‑4,-4'‑diamine,3,3'‑dimethyl‑

Dimethylcarbamoyl chloride                                 Carbamic chloride, dimethyl-

1,1‑Dimethylhydrazine                                         Hydrazine, 1,1‑dimethyl‑

1,2‑Dimethylhydrazine                                         Hydrazine, 1,2‑dimethyl‑

alpha,alpha‑Dimethylphenethylamine                   Benzeneethanamine, alpha, alpha‑dimethyl‑

2,4‑Dimethylphenol                                              Phenol, 2,4‑dimethyl-

Dimethyl phthalate                                               1,2‑Benzenedi-carboxylic acid, dimethyl ester

Dimethyl sulfate                                                   Sulfuric acid, dimethyl ester

Dinitrobenzene, N.O.S.1                                      Benzene, dinitro-

4,6‑Dinitro‑o‑cresol                                               Phenol, 2‑methyl‑4,6‑dinitro-

4,6‑Dinitro‑o‑cresol salts

2,4‑Dinitrophenol                                                  Phenol, 2,4‑dinitro-

2,4‑Dinitoluene                                                     Benzene, 1‑methyl‑2,4‑dinitro-

2,6‑Dinitrotoluene                                                 Benzene, 2‑methyl‑1,3‑dinitro-

Dinocap                                                                 Crotonic acid, 2‑(1‑methylheptyl)‑4,6‑dinitrophenyl ester

Dinoseb                                                                 Phenol, 2‑(1‑methylpropyl)‑4,6-dinitro-

Di‑n‑octyl phthalate                                              1,2‑Benzenedi-carboxylic acid, dioctyl ester

Diphenylamine                                                      Benzenamine, N‑phenyl-

1,2‑Diphenylhydrazine                                         Hydrazine, 1,2‑diphenyl-

Di‑n‑propylnitrosamine                                         1‑Propanamine, N‑nitroso‑N‑propyl

Dioxathion                                                            Phosphorodithioic acid, S,S'‑p‑dioxane‑2,3‑diyl O,O,O',O'‑tetraethyl ester**

Disulfoton                                                             Phosphorodithioic acid, O,O‑diethyl S‑[2‑(ethylthio)ethyl] ester

Dithiobiuret                                                           Thioimidodicarbonic diamide [(H2N)C(S)]2NH

Endosulfan                                                            6,9‑Methano‑2,4,-3‑benzodioxa-thiepin,6,7,8,9,10,10‑hexachloro‑1,5,5a,6,9,9a‑hexahydro‑, 3‑oxide

Endothall                                                              7‑Oxabicyclo-[2.2.1]heptane‑2,-3‑dicarboxylic acid

Endrin                                                                   2,7:3,6‑Dimetha-nonaphth[2,3‑b]-oxirene, 3,4,5,6,9,9‑hexachloro‑1a,2,2a,3,6,6a,7,7a,octa‑hydro‑(1aalpha,2beta,2abeta,3alpha,6alpha,6abeta,7beta,7aalpha)‑

Endrin metabolites

Epichlorohydrin                                                    Oxirane, (chloromethyl)‑

Epinephrine                                                           1,2‑Benzenediol, 4‑[1‑hydroxy‑2‑(methylamino)ethyl]‑,(R)‑

EPN                                                                      Phosphonothioic acid, phenyl‑,O‑ethyl O‑(p‑nitrophenyl) ester**

Ether, 2,4‑dichlorophenyl p‑nitrophenyl**

Ethion                                                                   Phosphorodithioic acid, S,S'‑methylene O,O,O',O'‑tetraethyl ester**

Ethyl carbamate (urethane)                                   Carbamic acid, ethyl ester

Ethyl cyanide                                                        Propanenitrile

Ethylenebisdithiocarbamic acid                            Carbamodithioic acid, 1,2‑ethanediylbis‑

Ethylenebisdithiocarbamic acid, salts and esters.

Ethylene dibromide                                              Ethane, 1,2‑dibromo‑

Ethylene dichloride                                               Ethane, 1,2‑dichloro‑

Ethylene glycol monoethyl ether                          Ethanol, 2‑ethoxy‑

Ethyleneimine                                                       Aziridine

Ethylene oxide                                                      Oxirane

Ethylenethiourea                                                   2‑Imidazolid-        inethione

Ethylidene dichloride                                           Ethane, 1,1‑dichloro‑

Ethyl methacrylate                                                2‑Propenoic acid, 2‑methyl‑,ethyl ester

Ethyl methanesulfonate                                        Methanesulfonic acid, ethyl ester

Famphur                                                                Phosphorothioic acid, O‑[4‑[(dimethylamino)sulfonyl]phenyl]O,O‑dimethyl ester

Fensulfothion                                                        Phosphorothioic acid, O,O‑diethyl O‑(p‑(methylsulfinyl)phenyl) ester**

Fenthion                                                                Phosphorothioic acid, O,O‑dimethyl‑, O‑(4‑methylthio)‑m‑tolyl) ester**

Fluchloralin                                                           p‑Toluidine, N‑(2‑chloroethyl)‑2,6‑dinitro‑N‑propyl‑alpha,alpha,alpha‑trifluoro‑**

Fluoranthene                                                         Same

Fluorine                                                                 Same

Fluoroacetamide                                                   Acetamide, 2‑fluoro‑

Fluoroacetic acid, sodium salt                              Acetic acid, fluoro‑, sodium salt

Formaldehyde                                                       Same

Formic acid                                                           Same

Glutarimide, 3‑(2‑(3,5‑dimethyl‑2‑oxocyclohexyl)‑2‑hydroxyethyl)‑**

Glycidylaldehyde                                                 Oxirane carboxyaldehyde

Halomethanes, N.O.S.1

Heptachlor                                                            4,7‑Methano‑1H‑indene, 1,4,5,6,7,8,8‑heptachloro‑3a,4,7,7a- tetrahydro‑

Heptachlor epoxide                                               2,5‑Methano‑2H‑indeno[1,2‑b]oxirene 2,3,4,5,6,7,7‑heptachloro‑1a,1b,5,5a,6,6a-hexahydro-, 1aalpha,1bbeta,2alpha,5alpha,5abeta, 6beta,6aalpha)‑Heptachlor epoxide (alpha,beta,and gamma isomers).

Hexachlorobenzene                                               Benzene, hexachloro‑

Hexachlorobutadiene                                            1,3‑Butadiene, 1,1,2,3,4,4‑hexachloro‑

Hexachlorocyclopentadiene                                  1,3‑Cyclo pentadiene, 1,2,3,4,5,5‑hexachloro‑

Hexachlorodibenzo‑p‑dioxins

Hexachlorodibenzofurans

Hexachloroethane                                                 Ethane, hexachloro‑

Hexachlorophene                                                  Phenol, 2,2'‑methylenebis[3,4,6‑trichloro-

Hexachloropropene                                               1‑Propene,1,1,2,3,3,3‑hexachloro‑

Hexaethyl tetraphosphate                                     Tetraphosphoric acid, hexaethyl ester

Hexamethyl phosphoramide                                 Phosphoric triamide, hexamethyl‑**

Hydantoin, 5,5‑diphenyl‑**                                 2,4‑Imidazo lidinedione, 5,5‑diphenyl‑

Hydantoin, 5,5‑diphenyl‑, monosodium salt**

Hydrazine                                                             Same

Hydrogen cyanide                                                Hydrocyanic acid

Hydrogen fluoride                                                Hydrofluoric acid

Hydrogen sulfide                                                  Hydrogen sulfide H2S

Hydroquinone**

Hydroxylamine, N‑nitroso‑N‑phenyl‑, ammonium salt**

Hypochlorous acid, calcium salt**

Hypochlorous acid, sodium salt**

Indeno[1,2,3‑cd]pyrene                                        Same

Iron dextran                                                          Same

Isobutyl alcohol                                                    1-Propanol, 2‑methyl‑

Isodrin                                                                   1,4,5,8‑Dimethanonaphthalene, 1,2,3,4,10,10‑hexachloro‑1,4,4a,5,8,8a,hexahydro‑,(1alpha,4alpha,4abeta,5beta,8beta,8abeta)‑

Isonicotinic acid hydrazide**

Isosafrole                                                              1,3‑Benzo-dioxole,5‑(1‑propenyl)‑

Kepone                                                                  1,3,4‑Metheno‑2H‑cyclobuta[cd] pentalen‑2‑one, 1,1a,3,3a,4,5,5,5a,5b,6‑decachlorooctahydro‑

Ketene**

Lasiocarpine                                                          2‑Butenoic acid, 2‑methyl‑,7‑[[2,3‑dihydroxy‑2‑(1‑methoxyethyl)‑3‑methyl‑1‑oxobutoxy]methyl]2,3,5,7a‑tetrahydro‑1H‑pyrrolizin‑1‑yl ester,[1S‑[1alpha(Z),7(2S*,3R*),7aalphal]]‑

Lead                                                                      Same

Lead compounds, N.O.S.1

Lead acetate                                                          Acetic acid, lead(2+)salt

Lead phosphate                                                     Phosphoric acid, lead(2+)salt(2:3)

Lead subacetate                                                    Lead,bis‑(acetato‑O)tetrahydroxytri‑

Leptophos                                                             Phosphonothioic acid, phenyl‑,0‑(4‑bromo‑2,5‑dichlorophenyl) O‑methyl ester**

Lindane                                                                 Cyclohexane, 1,2,3,4,5,6‑hexachloro‑, (1alpha,2alpha,3beta,4alpha,5alpha,6beta)‑

Linuron                                                                 (Urea, N'‑(3,4‑dichlorophenyl)‑N‑methoxy‑N‑methyl‑*

Lithium**

Malachite green                                                     Ammonium, (4‑(p‑(dimethylamino)‑alpha‑phenylbenzylidene)‑2,5‑cyclohexadien‑1‑ylidene)‑dimethyl‑, chloride**

Malathion                                                              Succinic acid, mercapto‑, diethyl ester, S‑ester with O,O‑dimethyl phosphorodithioate**

Maleic anhydride                                                  2,5‑Furandione

Maleic hydrazide                                                  3,6‑Pyri     dazinedione, 1,2‑dihydro‑

Malononitrile                                                         Propanedinitrile

Melphalan                                                             L‑Phenylalanine, 4‑[bis(2‑chloro‑ethyl)aminol]‑

Mercury                                                                 Same

Mercury compounds, N.O.S.1

Mercury fulminate                                                Fulminic acid, mercury(2+)salt

Mestranol                                                              17‑alpha‑19‑Norpregna‑1,3,5(10)‑trien‑20‑yn‑17‑ol, 3‑methoxy‑**

Methacrylonitrile                                                   2‑Propenenitrile, 2‑methyl-

Methapyrilene                                                       1,2‑Ethanediamine, N,N‑dimethyl‑N'‑2‑pyridinyl‑N'‑(2‑thienylmethyl‑

Methomyl                                                              Ethanimidothioic acid, N‑[[(methylamino)carbonyl]oxy]‑,methyl ester

Methoxychlor                                                        Benzene, 1,1'‑(2,2,2‑trichloro‑ethylidene)bis[4‑methoxy‑

Methyl bromide                                                    Methane, bromo‑

Methyl chloride                                                     Methane, chloro‑

Methyl chlorocarbonate                                        Carbonochloridic acid, methyl ester

Methyl chloroform                                                Ethane, 1,1,1‑trichloro‑

3‑Methylcholanthrene                                           Benz[j]acean-thrylene, 1,2‑dihydro‑3‑methyl‑

4,4'‑Methylenebis(2‑chloroaniline)                       Benzenamine, 4,4'‑methylenebis[2‑chloro‑

Methylene bromide                                               Methane, dibromo‑

Methylene chloride                                               Methane, dichloro‑

Methyl ethyl ketone (MEK)                                 2‑Butanone

Methyl ethyl ketone peroxide                               2‑Butanone, peroxide

Methyl hydrazine                                                  Hydrazine, methyl‑

Methyl iodide                                                       Methane, iodo‑

Methyl isocyanate                                                 Methane, isocyanato

2‑Methyllactonitrile                                              Propanenitrile, 2‑hydroxy‑2‑methyl‑

Methyl methacrylate                                             2‑Propenoic acid, 2‑methyl‑,methyl ester

Methyl methanesulfonate                                     Methanesulfonic acid, methyl ester

Methyl parathion                                                   Phosphorothioic acid, O‑O‑dimethyl O‑(4‑nitrophenyl)ester

Methylthiouracil                                                    4(1H)‑Pyrimidinone,2,3‑dihydro‑6‑methyl‑2‑thioxo‑

Mevinphos                                                            2‑Butenoic acid, 3‑((dimethoxyphos‑phinyl)oxy)‑, methyl ester (Crotonic acid, 3‑hydroxy‑, methyl ester, dimethyl phosphate, (E)‑)

Mexacarbate                                                          Carbamic acid, methyl,4‑dimethylamino‑3,5‑xylyl ester**

Mirex                                                                     1,3‑Metheno‑1H‑cyclobuta-[cd]pentalene, 1,1a,2,2,3,3a,4,5,5,5a,5b,6‑dodecachlorooctahydro**

Mitomycin C                                                         Azirino[2',3':3,4]pyrrolo[1,2‑a]indole‑4,7‑dione, 6‑amino‑8[[amino‑carbonyl)oxy]methyl]‑1,1a,2,8,8a,8b‑hexahydro‑8a‑methoxy‑5‑methyl‑,[1aS‑(1aalpha,8beta,8aalpha,8balpha)]-

MNNG                                                                  Guanidine, N‑methyl‑N'‑nitro‑N‑nitroso‑

Monocrotophos                                                     Phosphoric acid, dimethyl ester, ester with (E)‑3‑hydroxy‑N‑methylcrotonamide

Mustard Gas                                                         Ethane, 1,1'‑thiobis[2‑chloro‑

Naled                                                                    Phosphoric acid, 1,2‑dibromo‑2,2‑dichloroethyl‑dimethyl ester**

Naphthalene                                                          Same

1,5‑Naphthalenediamine**

1,4‑Naphthoquinone                                             1,4‑Naphthalene-dione

alpha‑Naphthylamine                                            1‑Naphthalenamine

beta‑Naphthylamine                                              2‑Naphthalenamine

alpha‑Naphthylthiourea                                        Thiourea, 1‑naphthalenyl‑

Nickel                                                                    Same

Nickel compounds, N.O.S.1

Nickel carbonyl                                                     Nickel carbonyl Ni(CO)4 (T‑4)‑

Nickel cyanide                                                      Nickel cyanide (Ni(CN)2

Nicotine                                                                Pyridine, 3‑(1‑methyl‑2‑pyrrolidinyl)‑, (S)‑

Nicotine salts

Nithiazide                                                             Urea, 1‑ethyl‑3(5‑nitro‑2‑thiazolyl)**

Nitric oxide                                                           Nitrogen oxide NO

Nitridazole                                                            2‑Imidazolidinone, 1‑(5‑nitro‑2‑thiazolyl‑**

p‑Nitroaniline                                                        Benzenamine, 4‑nitro‑

Nitrobenzene                                                         Benzene, nitro-

Nitrogen dioxide                                                   Nitrogen oxide NO2

Nitrogen mustard                                                  Ethanamine, 2‑chloro‑N‑(2‑chloroethyl)‑N‑methyl‑

Nitrogen mustard, hydrochloride salt

Nitrogen mustard N‑oxide                                    Ethanamine, 2‑chloro‑N‑(2‑chloro‑ethyl)‑N‑methyl‑ ,N‑oxide

Nitrogen mustard, N‑oxide, hydrochloride salt

Nitroglycerin                                                         1,2,3‑Propanetriol, trinitrate

p‑Nitrophenol                                                        Phenol, 4‑nitro-

2‑Nitropropane                                                      Propane, 2‑nitro-

Nitrosamines, N.O.S.1

N‑Nitrosodi‑n‑butylamine                                    1‑Butanamine, N‑butyl‑N‑nitroso-

N‑Nitrosodiethanolamine                                     Ethanol,2,2'‑(Nitrosoimino)bis‑

N‑Nitrosodiethylamine                                         Ethanamine, N‑ethyl‑N‑Nitroso-

N‑Nitrosodimethylamine                                      Methanamine, N‑methyl‑N‑nitroso-

p‑Nitrosodiphenylamine                                       Diphenyl‑amine, 4‑nitroso‑**

N‑Nitroso‑N‑ethylurea                                          Urea, N‑ethyl‑N‑nitroso-

N‑Nitrosomethylethylamine                                 Ethanamine, N‑methyl‑N‑nitroso-

N‑Nitroso‑N‑methylurea                                       Urea, N‑methyl‑N‑nitroso-

N‑Nitroso‑N‑methylurethane                                Carbamic acid, methylnitroso‑,ethyl ester

N‑Nitrosomethylvinylamine                                 Vinylamine, N‑methyl‑N‑nitroso-

N‑Nitrosomorpholine                                            Morpholine, 4‑nitroso-

N‑Nitrosonornicotine                                            Pyridine, 3‑(1‑nitroso‑2‑py‑rrolidinyl)‑, (S)‑

N‑Nitrosopiperidine                                              Piperidine, 1‑nitroso‑

N‑Nitrosopyrrolidine                                            Pyrrolidine, 1‑nitroso‑

N‑Nitrososarcosine                                               Glycine, N‑methyl‑N‑nitroso‑

5‑Nitro‑o‑toluidine                                                Benzenamine, 2‑methyl‑5‑nitro‑

Octamethylpyrophosphoramide                            Diphosphoramide, octamethyl‑

Osmium tetroxide                                                 Osmium oxide OsO4 (T‑4)‑

2‑Oxetanone**

Oxydemeton‑Methyl                                            Phosphorothioic acid, S‑(2‑(ethyl‑sulfinyl)ethyl) O,O‑dimethyl ester**

4,4'‑Oxydianiline

Paraldehyde                                                          1,3,5,‑Trioxane, 2,4,6‑tri‑methyl‑

Paraquat                                                                4,4'‑Bipyridinium, 1,1'‑dimethyl‑,dichloride**

Parathion                                                               Phosphorothioic acid, O,O‑diethyl O‑(4‑nitrophenyl)ester

Pentachlorobenzene                                              Benzene, pentachloro‑

Pentachlorodibenzo‑p‑dioxins

Pentachlorodibenzofurans

Pentachloroethane                                                 Ethane, pentachloro‑

Pentachloronitrobenzene (PCNB)                        Benzene, pentachloronitro‑

Pentachlorophenol                                                Phenol, pentachloro‑

Peroxyacetic acid**

Phenacetin                                                             Acetamide, N‑(4‑ethoxyphenyl)‑

Phenestrine                                                            Acetic acid,(4‑(bis(2‑chloroethyl)amino)phenyl),cholesteryl ester**

Phenol                                                                   Same

m‑Phenylenediamine, 4‑chloro‑**

o‑Phenylenediamine, 4‑chloro‑**

Phenylenediamine                                                 Benzenediamine

Phenylmercury acetate                                          Mercury, (acetato‑O)phenyl‑

Phenylthiourea                                                      Thiourea, phenyl‑

Phorate                                                                  Phosphorodithioic acid,O,O‑diethylS‑[(ethylthio)methyl] ester

Phosacetim                                                            Phosphoramidothioic acid, acetimidoyl‑0,0‑bis(p‑chlorophenyl ester*

Phosgene                                                               Carbonic dichloride

Phosmet                                                                Phosphorodithioic acid, O,O‑dimethyl ester, S‑ester with N‑(mercaptomethyl)phthalimide**

Phosphamidon                                                      Phosphoric acid, dimethyl ester, ester with 2‑chloro‑N,N‑diethyl‑3‑hydroxy‑crotonamide**

Phosphine                                                              Same

Phthalic acid esters, N.O.S.1

Phthalic anhydride                                                1,3‑Isobenzofurandione

2‑Picoline                                                              Pyridine, 2‑methyl‑

Piperonyl sulfoxide                                               Benzene, 1,2‑(methylenedioxy)‑   4‑(2‑octylsulfinyl) propyl**

Polybrominated biphenyls**

Polychlorinated biphenyls, N.O.S.1

Potassium cyanide                                                Potassium cyanide K(CN)

Potassium silver cyanide                                       Argentate(1‑),bis(cyano‑C)‑, potassium

Pronamide                                                             Benzamide, 3,5‑dichloro‑N‑(1,1‑dimethyl‑2‑ propynyl)-

1,3‑Propane sulfone                                              1,2‑Oxathiolane, 2,2‑dioxide

Propargyl alcohol                                                  2‑Propyn‑1‑ol

Propene, 3‑chloro‑**

Propionitrile, 2‑hydroxy‑**

n‑Propylamine                                                       1‑Propanamine

Propylthiouracil                                                     Uracil, 6‑propyl‑2‑thio**

Propylene dichloride                                             Propane, 1,2‑dichloro‑

1,2‑Propylenimine                                                 Azinidine, 2‑methyl‑

Propylthiouracil                                                     4(1H)‑Pyrimidinone, 2,3‑dihydro‑6‑propyl‑2‑thioxo‑

Pyridine                                                                 Same

Pyridine, 3‑chloromethyl‑, hydrochloride**         Pyridine,2,6‑diamino‑3‑(phenylazo)‑, monohydrochloride**

Monocrotaline                                                       (2,3,4‑gh)Pyrrolizine‑2,6(3H)‑dione, (4,5,8,10,12,13,13a,13b‑octahydro‑4,5‑dihy‑droxy‑3,4,5‑trimethyl‑2H‑(1,6)dioxacycloundecino‑**

Reserpine                                                              Yohimban‑16‑carboxylic acid, 11,17‑dimethoxy‑18‑[(3,4,5‑trimethoxybenzoyl)oxy]‑methylester, (3beta,16beta,17alpha,18beta,20alpha)‑

Resorcinol                                                             1,3‑Benzenediol

Rotenone                                                               (1)Benzopyrano (3,4‑b)furo(2,3‑h)(1)benzopyran‑6(6aH)‑one, 1,2,12,12a‑tetrahydro‑2‑alpha‑isopropenyl‑8,9‑dimethoxy‑**

Saccharin                                                               1,2‑Benzisothiazol‑3(2H)‑one, 1,1‑dioxide

Saccharin salts

Safrole                                                                   1,3‑Benzodioxole, 5‑(2‑propenyl)‑

Selenium                                                               Same

Selenium compounds, N.O.S.1

Selenium dioxide                                                  Selenious acid

Selenium sulfide                                                   Selenium sulfide SeS2

Selenourea                                                             Same

Semicarbazide**

Silver                                                                     Same

Silver compounds, N.O.S.1

Silver cyanide                                                       Silver cyanide Ag(CN)

Silvex (2,4,5‑TP)                                                   Propanoic acid, 2‑(2,4,5‑tri‑chlorolorophenoxy)‑

Sodium cyanide                                                    Sodium cyanide Na(CN)

Streptozotocin                                                       D‑Glucose, 2‑deoxy‑2‑[[(methyl‑nitrosoamino)carbonyl]amino]‑

Strontium sulfide                                                  Strontium sulfide SrS

Strychnine                                                             Strychnidin‑10‑one

Strychnine salts

Styrene**

Sulfallate                                                               Carbamic acid, diethyldithio‑, 2‑chloroallyl ester**

TCDD                                                                   Dibenzo[b,e]-[1,4]dioxin, 2,3,7,8‑tetrachloro‑

Terbufos                                                                Phosphorodithioic acid, O‑O‑diethyl‑S‑ (((1,1‑dimethylethyl)thio)methyl)‑ester**

3,3',4,4'‑Tetrachloroazobenzene*                          bis(3,4‑dichloro-phenyl)diazene

3,3',4,4'‑Tetrachloroazoxybenzene*                      bis (3,4,‑dichlorophenyl)diazene‑l‑oxide

1,2,4,5‑Tetrachlorobenzene                                   Benzene, 1,2,4,5‑tetrachloro

Tetrachlorodibenzo‑p‑dioxins

Tetrachlorodibenzofurans

Tetrachloroethane, N.O.S.1                                  Ethane, tetrachloro‑N.O.S.1

1,1,1,2‑Tetrachloroethane                                     Ethane, 1,1,1,2‑tetrachloro

1,1,2,2‑Tetrachloroethane                                     Ethane, 1,1,2,2‑tetrachloro

Tetrachloroethylene                                              Ethene, tetrachloro‑

2,3,4,6‑Tetrachlorophenol                                     Phenol, 2,3,4,6‑tetrachloro

Tetrachlorvinphos                                                 Phosphoric acid, 2‑chloro‑1‑

                                                                              (2,4,5‑trichlorophenyl)vinyl dimethyl ester**

Tetraethyldithiopyrophosphate                             Thiodiphosphoric acid, tetraethyl ester

Tetraethyl lead                                                      Plumbane, tetraethyl-

Tetraethyl pyrophosphate                                     Diphosphoric acid, tetraethyl ester

Tetranitromethane                                                 Methane, tetranitro‑

Thallium                                                                Same

Thallium compounds, N.O.S.1

Thallium (III) oxide                                              Thallium (III) oxide Tl2O3

Thallium(I) acetate                                                Acetic acid, thallium(1+)salt

Thallium(I) carbonate                                            Carbonic acid, dithallium(1+)salt

Thallium(I) chloride                                              Thallium chloride TlCl

Thallium(I) nitrate                                                 Nitric acid, thallium(1+)salt

Thallium selenite                                                   Selenious acid, dithallium(1+)salt

Thallium(I)sulfate                                                 Sulfuric acid, dithallium(1+)salt

Thioacetamide                                                       Ethanethioamide

Thiofanox                                                              2‑Butanone, 3,3‑dimethyl‑1‑(methyl‑thio)‑,0‑[(methylamino)carbonyl] oxime

Thiomethanol                                                        Methanethiol

Thiophenol                                                            Benzenethiol

Thiosemicarbazide                                                Hydrazine-carbothioamide

Thiourea                                                                Same

Thiram                                                                   Thioperoxy-dicarbonic diamide [(H2N)C(S)]2S2, tetramethyl‑

Toluene                                                                 Benzene, methyl

Toluene, 2,4‑diamino**                                        1,3‑Benzenediamine, 4‑methyl-

Toluenediamine                                                     Benzenediamine, ar‑methyl‑

Toluene‑2,4‑diamine                                             1,3‑Benzenediamine, 4‑methyl

Toluene‑2,6‑diamine                                             1,3‑Benzenediamine, 2‑methyl‑

Toluene‑3,4‑diamine                                             1,2‑Benzenediamine, 4‑methyl‑

Toluene diisocyanate                                            Benzene, 1,3‑diisocyanatomethyl‑

o‑Toluidine                                                            Benzeneamine, 2‑methyl‑

o‑Toluidine, 5‑chloro**

o‑Toluidine hydrochloride                                    Benzenamine, 2‑methyl‑,hydrochloride

p‑Toluidine                                                            Benzenamine, 4‑methyl‑

Toxaphene                                                             Same

Trichlorfon                                                            Phosphonic acid, (2,2,2‑trichloro‑1‑hydroxyethyl)‑,dimethyl ester**

Triazene, 3,3'dimethyl‑1‑(p‑chlorophenyl)‑**

1,2,4‑Trichlorobenzene                                         Benzene, 1,2,4‑trichloro‑

1,1,2‑Trichloroethane                                            Ethane, 1,1,2‑trichloro‑

Trichloroethylene                                                  Ethene, trichloro‑

Trichloromethanethiol                                           Methanethiol, trichloro‑

Trichloromonofluoromethane                               Methane, trichlorofluoro‑

2,4,5‑Trichlorophenol                                            Phenol, 2,4,5‑trichloro‑

2,4,6‑Trichlorophenol                                            Phenol, 2,4,6‑trichloro‑

2,4,5‑T                                                                   Acetic acid, (2,4,5‑trichloro- phenoxy)

Trichloropropane, N.O.S.

1,2,3‑Trichloropropane                                          Propane, 1,2,3‑trichloro‑

Tricresyl phosphate                                               Phosphoric acid, tri‑o‑tolyl ester**

O,O,O‑Triethyl phosphorothioate                         Phosphorothioic acid, O,O,O‑triethyl ester

Trifluralin                                                              p‑Toluidine, alpha,alpha,alpha-trifluor‑2,6‑dinitro‑N,N‑dipropyl**

Trimethyl phosphate                                             Phosphoric acid, trimethyl ester**

1,3,5‑Trinitrobenzene                                            Benzene, 1,3,5‑trinitro‑

Tris(1‑aziridinyl)phosphine sulfide                       Aziridine, 1,1',1"‑phosphinothioy‑lidynetris‑

Tris(2,3‑dibromopropyl) phosphate                      1‑Propanol, 2,3‑dibromo‑, phosphate(3:1)

Trypan blue                                                           2,7‑Naphthal-enedisulfonic acid, 3,3'‑[(3,3'‑dimethyl[1,1'‑biphenyl]‑4,4'‑diyl)bis(azo)]‑bis[5‑amino‑4‑hydroxy‑, tetrasodium salt

Uracil mustard                                                      2,4‑(1H,3H)‑Pyrimidinedione, 5‑[bis‑(2‑chloroethyl)amino]‑

Vanadium pentoxide                                            Vanadium oxide, V2O5

Vinyl chloride                                                       Ethene, chloro‑

Warfarin                                                                2H‑1‑Benzopyran‑2‑one, 4‑hydroxy‑3- (3‑oxo‑1‑phenylbutyl)‑, when present at concentrations less than 0.3%

Warfarin                                                                2H‑1‑Benzopyran‑ 2‑one, 4‑hydroxy‑3- (3‑oxo‑1‑phenylbutyl)‑, when present at concentrations greater than 0.3%

Warfarin salts, when present at

 concentrations less than 0.3%

Warfarin salts, when present at

 concentrations greater than 0.3%

Zinc cyanide                                                         Zinc cyanide Zn(CN)2

Zinc phosphide                                                     Zinc phosphide Zn3P2, when present at concentrations greater than 10%.

Zinc phosphide                                                     Zinc phosphide Zn3P2, when present at concentrations of 10% or less.

Ziram                                                                     Zinc, bis(dimethyldithiocarbamato)‑**

 

 

 

1The abbreviation N.O.S. (not otherwise specified) signifies those members of the general class not specifically listed by name in this appendix.

 

*50 FR 18626, 5/1/85, Proposed Rule

 

**49 FR 49793, 12/21/84, Proposed Rule

 


APPENDIX IX: Reserved

 

APPENDIX X:

METHOD OF ANALYSIS FOR CHLORINATED

DIBENZO‑p‑DIOXINS AND DIBENZOFURANSl,2,3,4

 

This method is the same as that listed in Appendix X to 40 CFR Part 261.

 

Method 8280

 

1.   Scope and Application.

 

1.1 This method measures the concentration of chlorinated dibenzo‑p‑dioxins and chlorinated dibenzofurans in chemical wastes including still bottoms, filter aids, sludges, spent carbon, and reactor residues, and in soils.

 

1.2 The sensitivity of this method is dependent upon the level of interferences.

 

1.3 This method is recommended for use only by analysts experienced with residue analysis and skilled in mass spectral analytical techniques.

 

1.4 Because of the extreme toxicity of these compounds, the analyst must take necessary precautions to prevent exposure to himself, or to others, of materials known or believed to contain CDDs or CDFs.

 

 

1This method is appropriate for the analysis of tetra‑, penta‑, and hexa‑ chlorinated dibenzo‑p‑dioxins and ‑di‑ benzofurans.

 

2Analytical protocol for determination of TCDDs in phenolic chemical wastes and soil samples obtained from the proximity of chemical dumps. T.O. Tiernan and M. Taylor, Berhm Laboratory, Wright State University, Dayton, Ohio 45435.

 

3Analytical protocol for determination of chlorinated dibenzo‑p- dioxins and chlorinated dibenzofurans in river water. T.O. Tiernan and M. Taylor, Berhm Laboratory, Wright State University, Dayton, Ohio 45435.

 

4In general, the techniques that should be used to handle these materials are those which are followed for radioactive or infectious laboratory materials. Assistance in evaluating laboratory practices may be obtained from industrial hygienists and persons specializing in safe laboratory practices. Typical infectious waste incinerators are probably not satisfactory devices for disposal of materials highly contaminated with CDDs and CDFs. Safety instructions are outlined in EPA Test Method 613(4.0)

 

See also: 1) "Program for monitoring potential contamination in the laboratory following the handling and analyses of chlorinated dibenzo‑p‑ dioxins and dibenzofurans" by F.D. Hileman et al., In: Human and Environmental Risks of Chlorinated Dioxins and Related Compounds, R.E. Tucker, et al., eds., Plenum Publishing Corp., 1983. 2) Safety procedures outlined in EPA Method 613, Federal Register Volume 44, No. 233, December 3, 1979.

 

2.   Summary of the Method

 

2.1 This method is an analytical extraction cleanup procedure, and capillary column gas chromatograph‑low resolution mass spectrometry method, using capillary column GC/MS conditions and internal standard techniques, which allow for the measurement of PCDDs and PCDFs in the extract.

 

2.2 If interferences are encountered, the method provides selected general purpose cleanup procedures to aid the analyst in their elimination.

 

3.   Interferences

 

3.1 Solvents, reagents, glassware, and other sample processing hardware may yield discrete artifacts and/or elevated baselines causing misinterpretation of gas chromatograms. All of these materials must be demonstrated to be free from interferences under the conditions of the analysis by running method blanks. Specific selection of reagents and purification of solvents by distillation in all‑glass systems may be required.

 

3.2 Interferences co‑extracted from the samples will vary considerably from source to source, depending upon the diversity of the industry being sampled. PCDD is often associated with other interfering chlorinated compounds such as PCB's which may be at concentrations several orders of magnitude higher than that of PCDD. While general cleanup techniques are provided as part of this method, unique samples may require additional cleanup approaches to achieve the sensitivity stated in Table 1.

 

3.3 The other isomers of tetrachlorodibenzo‑p‑dioxin may interfere with the measurement of 2,3,7,8‑TCDD. Capillary column gas chromatography is required to resolve those isomers that yield virtually identical mass fragmentation patterns.

 

4.   Apparatus and Material

 

4.1 Sampling equipment for discrete or composite sampling.

 

4.1.1    Grab sample bottle ‑ amber glass, l liter or l quart volume. French or Boston Round design is recommended. The container must be washed and solvent rinsed before use to minimize interferences.

 

4.1.2    Bottle caps ‑ threaded to screw on to the sample bottles. Caps must be lined with Teflon. Solvent washed foil, used with the shiny side towards the sample, may be substituted for the Teflon if sample is not corrosive.

 

4.1.3    Compositing equipment ‑ automatic or manual composing system. No tygon or rubber tubing may be used, and the system must incorporate glass sample containers for the collection of a minimum of 250 ml. Sample containers must be kept refrigerated after sampling.

 

4.2 Water bath ‑ heated, with concentric ring cover, capable of temperature control (+2º C). The bath should be used in a hood.

 

4.3 Gas chromatograph/mass spectrometer data system.

 

4.3.1    Gas chromatograph: An analytical system with a temperature‑programmable gas chromatograph and all required accessories including syringes, analytical columns, and gases.

 

4.3.2    Column: SP‑2250 coated on a 30 m long X 0.25 mm I.D. glass column (Supelco No. 2‑3714 or equivalent). Glass capillary column conditions: Helium carrier gas at 30 cm/sec linear velocity run splitless. Column temperature is 210o C.

 

4.3.3    Mass spectrometer: Capable of scanning from 35 to 450 amu every l sec or less, utilizing 70 volts (nominal) electron energy in the electron impact ionization mode and producing a mass spectrum which meets all the criteria in Table 2 when 40 ng of decafluorotriphenyl‑ phosphine (DFTPP) is injected through the GC inlet. The system must also be capable of selected ion monitoring (SIM) for at least 4 ions simultaneously, with a cycle time of 1 sec or less. Minimum integration time for SIM is l00 ms. Selected ion monitoring is verified by injecting .015 ng of TCDD Cl37 to give a minimum signal to noise ratio of 5 to l at mass 328.

 

4.3.4    GC/MS interface: Any GC‑to‑MS interface that gives acceptable calibration points at 50 ng per injection for each compound of interest and achieves acceptable tuning performance criteria (see Section 6.1‑6.3) may be used. GC‑to‑MS interfaces constructed of all glass or glass‑lined materials are recommended. Glass can be deactivated by silanizing with dichlorodi- methylsilane. The interface must be capable of interest from GC to the MS.

 

4.3.5    Data system: A computer system must be interfaced to the mass spectrometer. The system must allow the continuous acquisition and storage on machine‑readable media of all mass spectra obtained throughout the duration of the chromato‑graphic program. The computer must have software that can search any GC/MS data file for ions of a specific mass and that can plot such ion abundance versus time or scan number. This type of plot is defined as an Extracted Ion Current Profile (EICP). Software must also be able to integrate the abundance, in any EICP, between specified time or scan number limits.

 

4.4 Pipettes‑Disposable, Pasteur, 150 mm long X 5 ID (Fisher Scientific Co., No. 13‑678‑6A or equivalent).

 

4.5 Flint glass bottle (Teflon‑lined screw cap).

 

4.6 Reacti‑vial (silanized) (Pierce Chemical Co.).

 

5.   Reagents

 

5.1 Potassium hydroxide‑(ACS), 2% in distilled water.

 

5.2 Sulfuric acid‑(ACS), concentrated.

 

5.3 Methylene chloride, hexane, benzene, petroleum ether, methanol, tetradecane‑pesticide quality or equivalent

 

5.4 Prepare stock standard solutions of TCDD and 37Cl‑TCDD (molecular weight 328) in a glove box. The stock solutions are stored in a glovebox, and checked frequently for signs of degradation or evaporation, especially just prior to the preparation of working standards.

 

5.5 Alumina‑basic, Woelm: 80/200 mesh. Before use activate overnight at 600oC, cool to room temperature in a dessicator.

 

5.6 Prepurified nitrogen gas.

 

6.0 Calibration

 

6.1 Before using any cleanup procedure, the analyst must process a series of calibration standards through the procedure to validate elution patterns and the absence of interferences from reagents.

 

6.2 Prepare GC/MS calibration standards for the internal standard technique that will allow for measurement of relative response factors of at least three CDD/37CDD ratios. Thus, for TCDDs at least three TCDD/37cl‑TCDD and TCDF/37Cl‑TCDF must be determined.5

 

5 37Cl‑labelled 2,3,7,8‑TCDD and 2,3,7,8‑ TCDF are available from K.O.R. Isotopes and Cambridge Isotopes, Inc., Cambridge, MA. Proper standardization requires the use of a specific labelled isomer for each congener to be determined. However, the only labelled isomers readily available are 37Cl‑2,3,7,8‑TCDD and Cl‑2,3,7,8‑TCDF. This method therefore uses these isomers as surrogates for the CDDs and CDFs. When other labelled CDDs and CDFs are available, their use will be required.

 

The 37Cl‑TCDD/F concentration in the standard should be fixed and selected to yield a reproducible response at the most sensitive setting of the mass spectrometer. Response factors for PCDD and HxCDD may be determined by measuring the response of the tetrachloro‑ labelled compounds relative to that of the unlabelled 1,2,3,4‑ or 2,3,7,8‑TCDD, 1,2,3,4,7‑ PCDD or 1,2,3,4,7,8‑HxCDD, which are commercially available.6

 

6.3 Assemble the necessary GC/MS apparatus and establish operating parameters equivalent to those indicated in Section 11.1 of this method. Calibrate the GC/MS system according to Eichelbarger, et al. (1975) by the use of decafluorotriphenyl phosphine (DFTPP). By injecting calibration standards, establish the response factors for CDDs vs. 37Cl‑TCDD, and for CDFs vs. 37Cl‑TCDF. The detection limit provided in Table 1 should be verified by injecting .015 ng of 37Cl‑TCDD which should give a minimum signal to noise ratio of 5 to 1 at mass 328.

 

7.   Quality Control

 

7.1 Before processing any samples, the analyst should demonstrate through the analysis of a distilled water method blank, that all glassware and reagents are interference‑free. Each time a set of samples is extracted, or there is a change in reagents, a method blank should be processed as a safeguard against laboratory contamination.

 

7.2 Standard quality assurance practices must be used with this method. Field replicates must be collected to measure the precision ofthe sampling technique. Laboratory replicates must be analyzed to establish the precision of the analysis. Fortified samples must be analyzed to establish the accuracy of the analysis.

 

8.   Sample Collection, Preservation, and Handling

 

8.1 Grab and composite samples must be collected in glass containers. Conventional sampling practices should be followed, except that the bottle must not be prewashed with sample before collection. Composite samples should be collected in glass containers in accordance with the requirements of the RCRA program. Sampling equipment must be free of tygon and other potential sources of contamination.

 

8.2 The samples must be iced or refrigerated from the time of collection until extraction. Chemical preservatives should not be used in the field unless more than 24 hours will elapse before delivery to the laboratory. If an aqueous sample is taken and the sample will not be extracted within 48 hours of collection, the sample should be adjusted to a pH range of 6.0‑8.0 with sodium hydroxide or sulfuric acid.

 

8.3 All samples must be extracted within 7 days and completely analyzed within 30 days of collection.

 

6This procedure is adopted because standards are not available for most of the CDDs and CDFs and assumes that all the cogeners will show the same response as the unlabelled cogener used as a standard. Although this assumption may not be true in all cases, the error will be small.

 

9.   Extraction and Cleanup Procedures

 

9.1 Use an aliquot of 1‑10 g sample of the chemical waste or soil to be analyzed. Soils should be dried using a stream or prepurified nitrogen and pulverized in a ball‑mill or similar device. Perform this operation in a clear are a with proper hood space. Transfer the sample to a tared 125 ml flint glass bottle (Teflon‑lined screw cap) and determine the weight of the sample. Add an appropriate quantity of 37Cl‑ labelled 2,3,7,8‑TCDD (adjust the quantity according to the required minimum detectable concentration), which is employed as an internal standard.

 

9.2 Extraction

 

9.2.1    Extract chemical waste samples by adding 10 ml methanol, 40 ml petroleum ether, 50 ml doubly distilled water, and then shaking the mixture for 2 minutes. Tars should be completely dissolved in any of the recommended neat solvents. Activated carbon samples must be extracted with benzene using method 3540 in SW‑ 846 (Test Methods for Evaluating Solid Waste‑ Physical/Chemical Methods, available from G.P.O. Stock #055‑022‑81001‑2). Quantitatively transfer the organic extract or dissolved sample toa clean 250 ml flint doubly distilled water and shake for 2 minutes. Discard the aqueous layer and proceed with Step 9.3.

 

9.2.2    Extract soil samples by adding 40 ml of petroleum ether to the sample, and then shaking for 20 minutes. Quantitatively transfer the organic extract to a clean 250 ml flint glass bottle (Teflon‑lined screw cap), add 50 ml doubly distilled water and shake for 20 minutes. Discard the aqueous layer and proceed with step 9.3.

 

9.3 Wash the organic layer with 50 ml of 20% aquoid potassium hydroxide by shaking for 10 minutes and then remove and discard the aqueous layer.

 

9.4 Wash the organic layer with 50 ml of doubly distilled water by shaking for 2 minutes, and discard the aqueous layer.

 

9.5 Cautiously add 50 ml concentrated sulfuric acid and shake for 10 minutes. Allow the mixture to stand until layers separate (approximately 10 minutes) and remove and discard the acid layer. Repeat acid washing until no color is visible in the acid layer.

 

9.6 Add 50 ml doubly distilled water to the organic extract and shake for 2 minutes. Remove and discard the aqueous layer and dry the organic layer by adding 10g of anhydrous sodium sulfate.

 

9.7 Concentrate the extract to incipient dryness by heating in a 55º C water bath and simultaneously flowing a stream of prepurified nitrogen over the extract. Quantitively transfer the residue to an alumina microcolumn fabricated as follows:

 

9.7.1 Cut off the top section of a 10 ml disposable Pyrex pipette at the 4.0 ml mark and insert a plug of silanized glass wool into the tip of the lower portion of the pipette.

 

9.7.2 Add 2.8g of Woelm basic alumina (previously activiated at 600º C overnight and then cooled to room temperature in a dessicator just prior to use).

 

9.7.3 Transfer sample extract with a small volume of methylene chloride.

 

9.8 Elute the microcolumn with 10 ml of 3% methylene chloride‑in‑hexane and discard these effluents. Elute the column with 15 ml of 50% methylene chloride‑in‑hexane and concentrate this effluent (55º C water bath, stream of prepurified nitrogen) to about 0.3‑0.5 ml.

 

9.9 Quantitatively transfer the residue (using methylene chloride to rinse the container) to a silanized Reacti‑Vial (Pierce Chemical Co.). Evaporate, using a stream of prepurified nitrogen, almost to dryness, rinse the walls of the vessel with approximately 0.5 ml methylene chloride, evaporate just to dryness, and tightly cap the vial. Store the vial at 5º C until analysis, at which time the sample is reconstituted by the addition of tridecane.

 

9.10  Approximately 1 hour before the GC/MA (HRGC‑LRMS) analysis, dilute the residue in the micro‑reaction vessel with an appropriate quantity of tridecane. Gently swirl the tridecane on the lower portion of the vessel to ensure dissolution of the CDDs and CDFs. Analyze a sample by GC/EC to provide insight into the complexity of the problem, and to determine the manner in which the mass spectrometer should be used. Inject an appropriate aliquot of the sample into the GC/MS instrument, using a syringe.

 

9.11  If, upon preliminary GC/MS analysis, the sample appears to contain interfering substances which obscure the analyses for CDDs and CFDs, high performance liquid chromatograph (HPLC) cleanup of the extract is accomplished, prior to further GC‑MS analysis.

 

10. HPLC Cleanup Procedure7

 

10.1 Place approximately 2 ml of hexane in a 50 ml flint glass sample bottle fitted with a Teflon‑lined cap.

 

10.2 At the appropriate retention time, position sample bottle to collect the required fraction.

 

10.3 Add 2 ml of 5% (w/v) sodium carbonate to the sample fraction collected and shake for one minute.

 

10.4 Quantitatively remove the hexane layer (top layer) and transfer to a micro‑reaction vessel.

 

10.5 Concentrate the fraction to dryness and retain for further analysis.

 

11. GC/MS Analysis

 

11.1 The following column conditions are recommended: Glass capillary column conditions: SP‑2250 coated on a 30 m long x 0.25 mm I.D. glass column (Supelco No. 2‑3714, or equivalent) with helium carrier gas at 30 cm/sec linear velocity, run splitless. Column temperature is 210oC. Under these conditions the retention time for TCDDs is about 9.5 minutes. Calibrate the system daily with a minimum three injections of standard mixtures.

 

11.2 Calculate response factors for standards relative to 37Cl‑TCDD/F (see Section 12).

 

11.3 Analyze samples with selected ion monitoring of at least two ions form Table 3. Proof of the presence of CDD or CDF exists if the following conditions are met:

 

11.3.1 The retention time of the peak in the sample must match that in the standard, within the performance specifications of the analytical system.

 

11.3.2 The ratio of ions must agree within 10% with that of the standard.

 

11.3.3 The retention time of the peak maximum for the ions of interest must exactly match that of the peak.

 

11.4 Quantitate the CDD and CDF peaks from the response relative to the 37CL-TCSS/F internal standards. Recovery of the internal standard should be greater than 50 percent.

 

7For cleanup see also method #8320 or #8330, SW‑846, Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (1982).

 

11.5 If a response is obtained for the appropriate set of ions, but is outside the expected ratio, a co‑eluting impurity may be suspected. In this case, another set of ions characteristic of CDD/CDF molecules should be analyzed. For TCDD a good choice of ions is m/e 259. For TCDF a good choice of ions is m/e 241 and 243. These ions are useful in charterizing the molecular structure to TCDD or TCDF. For analysis of TCDD good analytical technique would require using all four ions, m/e 257, 320, 322, and 328, to verify detection and signal to noise ratio of 5 to 1. Suspected impurities such as DDE, DDD or PCB residues can be confirmed cy checking for their major fragments. These materials can be removed by the cleanup columns. Failure to meet criteria should be explained in the report, or the sample reanalyzed.

 

11.6 If broad background interference restricts the sensitivity of the GC/MS analysis, the analyst should employ cleanup procedures and reanalyze by GC/MS. See Section 10.0.

 

11.7 In those circumstances where these procedures do not yield a definitive conclusion, the use of high resolution mass spectrometry is suggested.

 

12. Calculations

 

12.1 Determine the concentration of individual compounds according to the formula:

 

                                         A x As

Concentration, ug/gm = _____________

                                      G x Ais Rf

 

where:

A=ug of internal standard added to the sample8.

G=gm of sample extracted.

As=area of characteristic ion of the compound being quantified.

Ais=area of characteristic ion of the internal standard.

Rf=response factor9.

 

8The proper amount of standard to be used is determined from the calibration curve (See Section 6.0).

 

9If standards for PCDDs/Fs and HxCDDs/Fs are not available, response factors for ions derived from these congeners are calculated relative to 37CL‑TCDD/F. The analyst may use response factors for 1,2,3,4‑ or 2,3,7,8‑TCDD, 1,2,3,4,7‑PeCDD, or 1,2,3,4,7,8‑HxCDDs/Fs, respectively. Implicit in this requirement is the assumption that the same response is obtained from PCDDs/Fs containing the same numbers of chlorine atoms.

 

Response factors are calculated using data obtained from the analysis of standards according to the formula:

 

             As x Cis

RF = _____________

             Ais x Cs

 

where:

Cis=concentration of the internal standard.

Cs=concentration of the standard compound.

 

12.2 Report results in micrograms per gram without correction for recovery data. When duplicate and spiked samples are analyzed, all data obtained should be reported.

 

12.3 Accuracy and Precision. No data available at this time.

 


 

TABLE 1: GAS CHROMATOGRAPHY OF TCDD

 

 

                                        Retention        Detection

                                            Time                Limit

Column                               (min.)              (ug/kg)1

 

 

Glass capilary                       9.5                 0.003

 

 

1Detection limit for liquid samples is 0.003 ug/l. This is calculated from the minimum detectable GC response being equal to five times the GC background noise assuming a l ml effective final volume of the 1 liter sample extract, and a GC injection of 5 microliters. Detection levels apply to both electron capture and GC/MS detection. For further details see 44 FR 69526 (December 3, 1979).

 

 

TABLE 2: DFTPP KEY IONS AND ION ABUNDANCE CRITERIA1

 

 

        Mass        Ion abundance criteria

 

           51         30‑60% of mass 198.

           68         Less than 2% of mass 69.

           70         Less than 2% of mass 69.

         127         40‑60% of mass l98.

         197         Less than 1% of mass 198.

         198         Base peak, 100% relative abundance.

         199         5‑9% of mass 198.

         275         10‑30% of mass 198.

         365         Greater than 1% of mass 198.

         441         Present but less than mass 443.

         442         Greater than 40% of mass 198.

         443         17‑23% of mass 442.

 

 

1J.W. Eichelberger, L.E. Harris, and W.L. Budde, 1975. Reference compound to calibrate ion abundance measurement in gas chromatography‑mass spectrometry. Analytical Chemistry 47:995.

 


TABLE 3:   LIST OF ACCURATE MASSES MONITORED USING GC SELECTED‑ION MONITORING, LOW RESOLUTION, MASS SPECTROMETRY FOR SIMULTANEOUS DETERMINATION OF TETRA‑,PENTA‑, AND HEXACHLORINATED DIBENZO‑p‑DIOXINS AND DIBENZOFURANS

 

 

 

Class of chlorinated dibenzodioxin or dibenzofuran

 

Number of chlorine substituents (x)

 

 

Monitored m/z for dibenzodioxins C12H8‑x O2Clx

 

Monitored m/z for dibenzofurans C12H8‑x OCL2

Approximate theoretical ratio expected on basis of isotopic abundance

 

Tetra

4

1319.897

321.984

2327.885

3256.933

3258.930

1303.902

305.903

2311.894

 

 

0.74

1.00

 

0.21

0.21

Penta

5

1353.858

355.855

1337.863

339.860

0.57

1.00

Hexa

6

389.816

391.813

 

373.821

375.818

1.00

0.87

 

1Molecular ion peak.

2Cl4‑‑labelled standard peaks.

3Ions which can be monitored in TCDD analyses for confirmation purposes.

 

 

APPENDIX XI: PAINT FILTER TEST

 

"Test Methods for Evaluating Solid Waste, Physical/Chemical Methods," EPA Publication SW‑846 [Third Edition, August 31, 1993 as amended up to Update V (August 12, 2016)]. See Appendix III for instructions on how to obtain copies of this publication.

 

_____________________________________________________________________


 

STATUTORY AUTHORITY:     38 M.R.S.A. §1301, et seq.

EFFECTIVE DATE:                    July 1, 1980

AMENDED:                                 March 23, 1983

                                                      June 20, 1983

                                                      February 10, 1985

                                                      November 30, 1986

                                                      March 16, 1994

EFFECTIVE DATE

(ELECTRONIC CONVERSION):   May 4, 1996

AMENDED:                                 January 23, 2001

MINOR CORRECTIONS:          March 5, 2001

AMENDED:                                 November 3, 2002

                                                      July 20, 2004 - filing 2004-272

                                                      February 8, 2012 – filing 2012-12

                                                      March 11, 2015 – filing 2015-030

                                                      April 26, 2017 – filing 2017-063

 



[1]ASTM Standards are available from ASTM, 1916 Race Street, Philadelphia, PA 19103.

[2]This document is available from NTIS as specified in Appendix III.

[3]The NACE Standard is available from the National Association of Corrosion Engineers, P.O. Box 986, Katy, Texas 77450.

[4]Hazard Codes:

Ignitable Waste........................... (I)

Corrosive Waste......................... (C)

Reactive Waste........................... (R)

EP Toxic Waste.......................... (E)

Acute Hazardous Waste........... (H)

Toxic Waste................................ (T)

 

[5](I,T) should be used to specify mixtures containing ignitable and toxic constituents.

 

[6]49 FR 5315, Feb. 10, 1984, Proposed Rule

 

[7]49 FR 49559, December 20, 1984, Proposed Rule

[8]50 FR 18626, 5/1/85, Proposed Rule